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32results about How to "Moderate acid strength" patented technology

Method for synthesizing polyoxymethylene dimethyl ethers

The invention relates to a method for synthesizing polyoxymethylene dimethyl ethers, comprising the following steps: step one, generating hemiacetal by methanol and excessive methanal or paraformaldehyde with low polymerization degree under the existence of a modified alumina catalyst, reacting the hemiacetal with methanal to generate hemiacetal with one more carbon, and successively continuing the above steps to generate poly-hemiacetal with more carbon atoms; and step two, generating the polyoxymethylene dimethyl ethers by the poly-hemiacetal mixture under the existence of methanol and an organic strong acid bonded phase solid catalyst. The invention can achieve the technical targets of improving raw material conversion rate, product selectivity, target product yield and economical efficiency by the two steps of reaction process, adjusts the space velocity by a fixed bed continuous reactor and combines with a catalyst to control the polymerization degree. The synthesis method in the invention has mild reaction conditions and easy control.
Owner:DONGFANG HONGSHENG NEW ENERGY APPL TECH RES INST +1

Preparation method of styrenated hindered phenol or styrenated phenol antioxidant product

The invention discloses a preparation method of a styrenated hindered phenol or styrenated phenol antioxidant product, belonging to the field of preparation process methods of polymer antioxidant products. The preparation method is characterized in that: o-tert-butyl phenol or phenol, p-cresol, o-cresol and m-cresol are used as raw materials, styrene is used as an alkylation reagent, an organic acid compound is used as a catalyst, a small amount of polymerization inhibitor is added, and the styrenated hindered phenol product or styrenated phenol product is prepared through catalytic alkylation reaction; a neutralizing and decolorizing agent is added to the styrenated product to deactivate the acidic catalyst and remove the coloring source material, thus obtaining a white-like or light yellow viscous liquid namely the styrenated phenol antioxidant product which has clear and transparent appearance, pH value of 6.5-7.5, storage stability and high use efficiency; and the styrenated phenol antioxidant product is free of water-soluble pollutants such as free phenol or methyl phenol, thereby solving the problem of environmental pollution caused by the use of the product in styrene butadiene rubber latex.
Owner:CHANGZHOU UNIV

Method for preparing ethylene glycol ether

The invention relates to a glycol ether preparation method, mainly solving the problems of the original technique that the target product, glycol ether, has low selectivity, high alcohol / epoxy ethane ratio (alcohol / alkyl ratio) and no concern on catalyst stability. The invention uses epoxy ethane and lower fatty alcohol as raw materials, adopts niobium oxide as a main activated component, and chooses at least one of elements or compounds of V, Mo, Sn, Pb, La, Pr, Nd as auxiliary agent to form catalyst, so as to prepare glycol ether under the reaction temperature of 100 to 300 DEG C, reaction pressure of 0.1 to 3.0MPa, alcohol / alkyl ratio of 1-5: 1, and reaction time of 30 minutes to 8.0 hours. The technical proposal can well solve the problem and can be used for the industrial production of the glycol ether.
Owner:CHINA PETROLEUM & CHEM CORP +1

Catalyst for preparing dimethyl ether from methanol

The present invention relates to a catalyst for preparing dimethyl ether by using methyl alcohol dehydration. Said catalyst is made up by using niobium oxide as main active component and selecting at least one kind of phosphorus or sulfur as adjuvant through a certain preparation process. Said catalyst not only has good activity, but also possesses good stability.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation method of isobutyl ketone synthesis catalyst

The invention relates to a preparation method of an isobutyl ketone synthesis catalyst. The catalyst is prepared by loading bimetallic nickel and copper on alkaline-earth metallic oxide / aluminum oxide composite carrier. The preparation method of the catalyst comprises the three steps of: firstly adopting a sol-gel method to prepare the alkaline-earth metallic oxide / aluminum oxide composite carrier; then introducing active metal nickel and copper by an immersion method; and finally carrying out water hydrothermal treatment to prepare the catalyst. The preparation method has the advantages of simplicity, high activity and selectivity, integration of three catalysis functions such as condensation, dehydration and hydrogenation of acetone, and simple reaction process flow.
Owner:CHINA NAT OFFSHORE OIL CORP +1

Eutectic nano molecular sieve, preparation method and applications thereof

The invention belongs to the field of molecular sieves, particularly relates to a low-silicon AEI / CHA eutectic nano molecular sieve, a preparation method and applications thereof. A purpose of the invention is mainly to solve the problems of low AEI content, complex preparation process, high template agent price, high template agent dosage, high production cost and the like in the AEI / CHA eutecticmolecular sieve prepared by the conventional synthesis method. The preparation method of the molecular sieve specifically comprises the following steps: adding an aluminum source, a phosphorus source, a template agent and the like into distilled water, uniformly stirring and dispersing, and then adding a seed crystal to obtain a mixed solution; and crystallizing, separating, washing, drying and roasting the obtained mixed solution to obtain the eutectic nano molecular sieve formed by AEI and CHA symbiosis. The molecular sieve obtained in the invention has the advantages of high proportion ofAEI structural units and uniform dispersion of silicon species, and further has high CO conversion rate and low carbon olefin selectivity in a reaction for preparing low carbon olefins through directconversion of catalytic synthesis gas.
Owner:CHINA PETROLEUM & CHEM CORP +1

New method for hydrogenation saturation of aromatic hydrocarbons

The present invention relates to a new method for hydrogenation saturation of aromatic hydrocarbons. The main steps comprise: under mild operation conditions (the pressure is less than 3 MPa, and thetemperature is less than 80 DEG C), mixing an oil product containing an aromatic hydrocarbon and M / Al2O3, introducing hydrogen to achieve a certain pressure, carrying out a reaction at a certain temperature, reducing to a room temperature from the reaction temperature after the aromatic hydrocarbon is subjected to complete hydrogenation saturation, and recovering the separated catalyst, wherein Min the catalyst M / Al2O3 is one selected from Ru, Rh, Pd, Pt, Ir and other noble metals or a combination comprising two materials selected from Ru, Rh, Pd, Pt, Ir and other noble metals, and Al2O3 hasan ordered mesoporous structure. According to the present invention, the reaction conditions are mild, and the catalyst shows high aromatic hydrocarbon hydrogenation activity and high stability.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Method for preparing dimethyl ether

The present invention relates to process of preparing dimethyl ether, and aims at providing technological scheme of preparing dimethyl ether in lowered reaction temperature, high catalyst efficiency, long service life of catalyst and other merits. The process of preparing dimethyl ether adopts methanol as main material and catalyst with niobium oxide as the main active component and P and / or S as the co-catalyst, and has reaction temperature of 100-350 deg.c and catalyst efficiency of 1-20 ml methanol / hr.g. The present invention may be applied in industrial production of dimethyl ether.
Owner:CHINA PETROLEUM & CHEM CORP +1

Catalyst for preparing styrene by phenylethanol dehydration as well as preparation and application methods of catalyst

The invention discloses a ZrAl catalyst. The catalyst is composed of ZrO2-Al2O3, and the weight percentage of the catalyst is 20-50%. The catalyst is prepared by a following method: reacting a mixed solution of aluminum and zirconium precursors with urea to form gel; and drying the gel and roasting the gel to obtain the catalyst. The preparation method is simple, easy to operate and high in repeatability. The invention also discloses a use method of the catalyst for catalyzing alpha-phenylethanol dehydration to prepare styrene. The catalyst has high activity, produces less carbon deposit and has good catalytic stability.
Owner:HEBEI UNIV OF TECH

Preparation method of catalyst for coproducing isopropanol and methyl isobutyl ketone by acetone hydrogenation

The invention relates to a preparation method of a catalyst for coproducing isopropanol and methyl isobutyl ketone by acetone hydrogenation. The catalyst comprises an alumina carrier and Ni and Mg loaded on the gamma-Al2O3 carrier, and particularly comprises, by total weight, 10-18% of the Ni, 3-8% of the Mg and the balance alumina; and the BET specific surface area of the catalyst ranges from 100m<2> / g to 180m<2> / g, and the pore volume of the catalyst ranges from 0.35mL / g to 0.55mL / g. The preparation method includes steps of (1), preparing the carrier by details of weighing pseudo-boehmite powder, adding binders and extrusion assistants into the pseudo-boehmite powder, forming by strip extrusion or granulating by rotation, drying and calcining, cooling to reduce temperature so as to obtain the stripped or spherical carrier; (2), impregnating the carrier into magnesium nitrate by details of loading a magnesium additive onto the carrier by means of saturated impregnation, drying and then calcining for 2-6 hours at the temperature ranging from 400 DEG C to 500 DEG C; (3), loading the actively metallic nickel by details of impregnating for 10-24 hours and calcining for 2-6 hours at the temperature ranging from 350 DEG C to 480 DEG C; and (4), loading the actively metallic nickel again by details of drying a semi-finished product, impregnating the dried semi-finished product into impregnation liquid of nickel nitrate again, repeating the step (3) once, and calcining the semi-finished product for 2-4 hours at the temperature ranging from 400 DEG C to 450 DEG C so as to obtain the finished catalyst.
Owner:CHINA NAT OFFSHORE OIL CORP +1

Method for catalytic synthesis of cyclohexanone ethylene ketal from titanium phosphotungstate and ammonium phosphotungstate composite salt

The invention relates to a method for catalytic synthesis of cyclohexanone ethylene ketal from titanium phosphotungstate and ammonium phosphotungstate composite salt. The titanium phosphotungstate andammonium phosphotungstate composite salt is taken as a catalyst, cyclohexanone ethylene ketal is generated from cyclohexanone and ethylene glycol through a condensation reaction, and the condensed structural formula of the titanium phosphotungstate and ammonium phosphotungstate composite salt is (NH4)xTiyH(3-x-4y)PW12O40, wherein x=0.4-0.6, and y=0.4-0.6. The titanium phosphotungstate and ammonium phosphotungstate composite salt as the catalyst has larger specific surface area, higher surface acid density and proper acid strength, so that the catalyst has excellent catalytic performance, andproduct yield is high. Besides, raw materials of the catalyst are easily available, the preparation process is simple, the catalyst and the product are easy to separate, and the catalyst is recyclable.
Owner:SHAOYANG UNIV

Method for producing isopropylbenzene through transalkylation

The invention relates to a method for producing isopropylbenzene through transalkylation. Transalkylation catalyst is obtained by mixing Hbeta / HMCM-49 composite molecular sieve powder, assistant, binding agent, pore-forming agent and lubricant evenly in proportion. The transalkylation catalyst is grinded, granulated, squeezed in strip mode, dried, roasted and cooled to obtain the assistant styrene (SB) powder or one of the SB powder, phosphoric acid, ammonium phosphate and boric acid. The binding agent is sesbania powder, the pore-forming agent is one of methylcellulose, citric acid and oxalic acid, the lubricant is one or two of nitric acid with the concentration of 0.5-15% and phosphoric acid with the concentration of 0.5-15%, and a raw material is diisopropylbenzene or / and triisopropylbenzene and benzene. The transalkylation catalyst is good in activity, high in selectivity and long in service life, and yield of the isopropylbenzene can reach 72.1%-94.1%.
Owner:PETROCHINA CO LTD

High-fluorine-containing C9 resin hydrogenation catalyst and preparation method and application thereof

The invention relates to a high-fluorine-containing C9 resin hydrogenation catalyst, which is composed of an active component M1, an auxiliary agent component M2 and a carrier component M3. Based on 100% of the total weight of the catalyst, the content of the M1 component is 37%-54%, the content of the M2 component is 4%-6%, and the balance is the M3 component. The component M1 contains Ni, Mo, Cu and Al, the component M2 contains Sm and Na, and the component M3 is amorphous silicon-aluminum MgAl2O4 composite oxide. The invention also discloses a preparation method and application of the catalyst. The catalyst provided by the invention is used for hydrogenation removal of fluorine and sulfur in C9 resin, and can effectively delay fluorine and sulfur poisoning of a rear-stage hydrogenation catalyst.
Owner:WUHAN KELIN FINE CHEM

Synthesis method of (3,4-dimethoxyphenyl)(4-p henyl fluoride) ketone

The invention relates to a synthesis method of (3,4-dimethoxyphenyl)(4-p henyl fluoride) ketone, and solves the problem that in the prior art, the synthesis method brings large amout of pollution and the cost is high. According to the method, acidic ionic liquid is applied as the catalyst which is polymerized by an ionic liquid precursor containing positive electricity and metal halides with negative electricity, wherein, the ionic liquid precursor is [Bmim] C1 or [Bmim] Br, the metal halide is AlCl3, FeC13, ZnCl2 or CuCl2. The synthesis method of (3,4-dimethoxyphenyl)(4-p henyl fluoride) ketone has the advantages of largely reducing the use amout of catalysts, lowering the emission of the waste water, saving the neutralization process of sulfuric acid, eliminating the waste water generated in the step, avoiding the corrosion caused by strong acid. Compared with the original reaction, the emission of slag is omitted. The reaction product is easy to be separated. The post-treatment is simpler. The reaction temperature is low. The energy cost is low. The product yield rate can reach as high as 97% or higher.
Owner:BEIJING UNIV OF CHEM TECH

Preparation method of SBA-15/ZSM-5 composite molecular sieve, catalyst and application in double branched chain isomerization

The invention relates to the field of petroleum processing, discloses a preparation method of an SBA-15 / ZSM-5 composite molecular sieve material and application in double branched chain isomerization, and in particular relates to a low-cost green preparation method of an SBA-15 / ZSM-5 composite molecular sieve material with proper acidity and a stepped pore channel structure and a sulfur-tolerant double-branched-chain isomerization catalyst prepared by loading non-noble metals on the SBA-15 / ZSM-5 composite molecular sieve material. The catalyst is applied to a catalytic cracking (FCC) gasoline hydroisomerization reaction. According to the invention, a ZSM-5 molecular sieve nanocrystalline precursor solution is greenly synthesized by taking natural minerals as raw materials without a template agent, and then the SBA-15 / ZSM-5 composite molecular sieve carrier is prepared through in-situ assembly by adopting a low-acidity prehydrolysis method, so that the production cost is greatly reduced, the equipment corrosion is relieved, and the pollutant emission is reduced. Therefore, the method provided by the invention has good economic and environmental benefits, and provides technical support for promoting the industrialization process.
Owner:PETROCHINA CO LTD +1

Method for preparing ethylene glycol by ethylene one-step method

The invention relates to a method for preparing ethylene glycol by an ethylene one-step method. The method comprises the following steps: preparing ethylene glycol: under an acidic reaction condition, contacting ethylene, hydrogen peroxide and a titanium silicalite molecular sieve in water, and carrying out an oxidation hydration reaction to obtain the ethylene glycol. The acidic reaction condition is provided by a non-zeolite molecular sieve; the non-zeolite molecular sieve includes a homogeneous liquid acid and / or a heterogeneous solid acid. The method is high in effective utilization rate of hydrogen peroxide, and the target product ethylene glycol is high in selectivity and high in concentration.
Owner:BEIJING UNIV OF CHEM TECH

A kind of hydrogenation saturation method of aromatics

The invention relates to a new method for hydrogenation saturation of aromatic hydrocarbons. The main steps are: under mild operating conditions (pressure lower than 3MPa, temperature lower than 80°C), oil containing aromatics and M / Al 2 o 3 Mix, pass hydrogen to a certain pressure, and react at a certain temperature. After the aromatics are completely hydrogenated and saturated, the reaction temperature will be room temperature, and the separated catalyst will be recovered. Catalyst M / Al 2 o 3 M in refers to one or any combination of noble metals such as Ru, Rh, Pd, Pt, Ir, and Al 2 o 3 It is an ordered mesoporous structure. The reaction condition of the invention is mild, and the catalyst exhibits high aromatic hydrogenation activity and stability.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Preparation method of catalyst for co-generating of isopropanol and diisobutyl ketone through acetone hydrogenation and application

The invention provides a preparation method of a catalyst for co-generating of isopropanol and diisobutyl ketone through acetone hydrogenation and an application. The preparation method is characterized in that the catalyst comprises an alumina carrier as well as Ni and Mg loaded on the gamma-Al2O3 carrier; in terms of total weight of the catalyst, the catalyst comprises 20-25% of Ni and 8-12% of Mg; the preparation method comprises the following procedures of 1) carrier preparation: taking a pseudo-boehmite powder body; adding a certain quantity of adhesives and extrusion assisting agents to the pseudo-boehmite powder body; extruding a mixture into strips or rotationally granulating the mixture; and drying and roasting the mixture so as to obtain the carrier; 2) impregnation of magnesium nitrate and nickel nitrate: impregnating the carrier in the magnesium nitrate and the nickel nitrate for 10-24 hours at room temperature; taking out the carrier after filtering the carrier; drying and roasting the carrier; and then naturally cooling the carrier; and 3) repeating of the step 2): using a magnesium nitrate and nickel nitrate impregnation liquor obtained in the step 2); impregnating a semi-finished product obtained in the step 2) in the impregnation liquor; and repeating the impregnating, drying and roasting process for at least three times according to the step 2) so as to obtain a catalyst finished product. The invention further relates to a catalytic application of the catalyst, which is prepared by the preparation method, used for co-generating the isopropanol and the diisobutyl ketone through acetone hydrogenation.
Owner:CHINA NAT OFFSHORE OIL CORP +1

Ga-ZSM-5 catalyst as well as preparation method and application thereof

The invention provides a Ga-ZSM-5 catalyst as well as a preparation method and application thereof. The catalyst is of a crisscross sheet structure; and the thickness of the b axis of the Ga-ZSM-5 catalyst is 50 to 500 nm. According to the invention, the structure of the Ga-ZSM-5 molecular sieve is controlled by controlling conditions in the preparation process of the Ga-ZSM-5 catalyst, so the diffusion rate of reactants and products is increased, and the performance of the catalyst is further improved. Moreover, the Ga-ZSM-5 synthesized by the method is of the crisscross sheet structure, and has stable conversion rate, selectivity and longer service life when being used for preparing ethylbenzene through benzene alkylation; and the preparation method provided by the invention also has the advantages of simple process and low cost, and has good industrial prospects.
Owner:CHINA NAT OFFSHORE OIL CORP +4

A kind of method for catalyzing synthesis of furfural ethylene glycol acetal by aluminum ammonium phosphotungstate composite salt

The invention relates to a method for catalyzing the synthesis of furfural glycol acetal by an aluminum ammonium phosphotungstate composite salt. The aluminum ammonium phosphotungstate composite salt is used as a catalyst to generate furfural glycol acetal through a condensation reaction between furfural and ethylene glycol. , the structural simplified formula of the aluminum ammonium phosphotungstate composite salt is: (NH 4 ) x Al y H (3‑x‑3y) PW 12 O 40 , among which, x=0.4~0.6, y=0.6~0.8. The aluminum ammonium phosphotungstate composite salt catalyst involved in the present invention has a high specific surface area and surface acid density, and has appropriate acid strength, resulting in excellent catalytic performance and high product yield. In addition, the raw materials required for the catalyst are easy to obtain, the preparation process is simple, and the catalyst and product are easy to separate and can be reused.
Owner:SHAOYANG UNIV
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