The invention discloses a method for superplastic forming of a TC11 titanium alloy ring with complex cross-section. The steps are as follows: heating the TC11 titanium alloy to 1030-1050°C, elongating in one direction, with a total deformation of 20%-40%, and air cooling ; Reheat to 950-980°C, repeatedly upsetting and elongating, the total deformation is 40%-65%, air cooling; then keep at 950°C for 1.5 hours, air-cooling; keep at 530°C for 6 hours, air-cooling; get fine crystal TC11 titanium alloy blank; reheated to forging temperature, through upsetting, punching, and flat height, to obtain the alloy ring blank; at a temperature of 880-900°C, rolling at a maximum feed speed of 2.0mm / s Forming to obtain TC11 titanium alloy complex section ring. The method enables the TC11 titanium alloy to be in a superplastic state during the forming process, thereby obtaining a TC11 titanium alloy complex cross-section annular part that meets requirements in performance and size. The ring is mainly used as a connecting ring, a bearing ring, etc., and is widely used in mechanical equipment in aviation, aerospace and other industrial fields.