The present invention relates to bacterium resisting type high water absorption resin and a preparation method thereof. The resin is a functional polymer material prepared by redox initiation system water solution polymerization method, the resin has a long chain containing allyl structures, a side chain containing carboxylic acid groups and carboxylic acid sodium, and an inner-crosslinking porous network structure, and the internal or external of particles contains a solubilizing quaternary ammonium salt positive ion monomer, an oxidizing agent is sodium persulfate and ammonium persulfate, a reducing agent is sodium sulfite or sodium bisulfite, and a crosslinking agent is N, N '-methylene bis acrylamide or polyethylene glycol diacrylate. The prepared high water absorbent resin has excellent water absorption and water retention properties, high liquid passing performance and high liquid absorption speed, most prominently has good antibacterial properties, and is applicable to the production of adult diapers, sanitary napkins, baby diapers and other water absorption hygiene materials.