The invention discloses a bulk phase deep
hydrodesulfurization catalyst and a preparation method thereof. The components of the catalyst comprise a
composite oxide (NixWyO2), MoO3, aluminum
oxide and beta
zeolite. The method comprises: adding a proper amount of
water soluble nitrogen compound in a
precipitation process of Ni, W and Al, gelatinizing, adding beta
zeolite size, aging, pulping with MoO3, forming and activating. The method improves the porous structure of the catalyst, makes more
metal active spots exposed from the surface of the catalyst, improves the
utilization rate of active metals, and makes beta
zeolite and
metal having hydrogenation activity uniformly and fully contacted and better cooperated to realize ultradeep
hydrodesulfurization of diesel. In addition, the increase in the aperture and pore volume of the catalyst allows a Ni-W
active center to be fully utilized and molecules with complex large structures to contact the
active center more easily, and the effect is more obvious particularly when distillate with high-
macromolecule content.