The invention discloses a
crystalline silicon solar cell and a preparation method thereof, and the
crystalline silicon solar cell comprises a pn plus junction
silicon substrate, wherein a first amorphous
alumina layer and an
amorphous silicon nitride layer are arranged on the surface of an n plus emitter, a
silver electrode penetrates the
amorphous silicon nitride layer and the first amorphous
alumina layer and is connected with the n plus emitter, a composite
passivation medium layer is arranged on the surface of a p type substrate, the p type substrate comprises a
silicon oxide layer and a second amorphous
alumina layer, and a p type substrate is in contact with a back
electrode. The preparation method comprises the special preparation of the composite
passivation medium layer,
nitric acid and
hydrogen peroxide solution are adopted for
processing the surface of the p type substrate, the
sol-gel process is adopted for preparing the second amorphous alumina layer, and the composite
passivation medium layer (4) is formed after annealing. The
crystalline silicon solar cell has the advantages of simple process, low equipment investment, good passivation and anti-reflection performances of the front surface, excellent passivation effect of the composite passivation medium layer on the back surface, capability of improving the utilization efficiency of long
waves, and the like.