The invention discloses a complex reverse osmosis membrane which comprises a non-woven fabric layer and a polysulfone supporting layer, wherein a crosslinked polyamide layer which uses polyamine and an organic solution containing an acyl halide compound for interfacial synthesis is arranged on the polysulfone supporting layer. In the invention, the polyamine and the organic solution containing the acyl halide are adopted on the polysulfone supporting layer of the prior reverse osmosis membrane to obtain the polyamide layer with a three-dimensional crosslinked structure through interfacial condensation, thus the performance of the complex reverse osmosis membrane is further improved, and the membrane molecules have better compactness and stronger rigidness, wherein the improved compactness can improve the salt rejection rate of the membrane, and the improved rigidness can enable the membrane to have excellent anti-densification performance, thus the rate of decay of the performance of the membrane can be reduced, and the service life of the membrane can be prolonged. Therefore, the complex reverse osmosis membrane has the advantages of high salt rejection rate, large water flux, long service life and obvious reduction of engineering investment and production cost, and can be widely applied to the fields of electricity, metallurgy, petroleum and petrochemical industry, medicine, food, municipal engineering, seawater desalination, and the like.