The invention belongs to the technical field of automobile coating and specially relates to water-based high temperature plain colored paint capable of being used for a wet-on-wet middle-coating-freesystem and a preparation method thereof. The water-based high temperature plain colored paint capable of being used for the wet-on-wet middle-coating-free system includes an A component and a B component, wherein the A component includes aqueous acrylic acid polyol dispersion, aqueous polyurethane dispersion, ultrafine talc powder, ultrafine barium sulfate, aluminum triphosphate, titanium dioxide,carbon black, an aqueous dispersant, methylated amino resin and pure water; and the B component includes the aqueous acrylic acid polyol dispersion, the aqueous polyurethane dispersion, an amine neutralizer, ethylene glycol butyl ether, titanium dioxide, a dispersant, methylated amino resin, a thickening agent and pure water. The water-based high temperature plain colored paint capable of being used for the wet-on-wet middle-coating-free system has excellent properties, strong paint film adhesion, high paint film hardness, and good water resistance, acid resistance, alkali resistance, weatherresistance and stone-chipping resistance, and environmental protection.