The invention provides a polycarbonate combination and a preparation method thereof. In terms of 100 parts of polycarbonate materials by weight, the polycarbonate combination comprises the following components in parts by weight: 100 parts of polycarbonate, 1-10 parts of copolyester, 0.01-0.5 part of aromatic sulphosalts fire retardant, 0.05-0.35 part of organic silicon fire retardant, 0.05-5 parts of anti-dripping agent, 1-15 parts of photodiffusion agent master batches and 0.05-5 parts of antioxidant. The preparation method of the polycarbonate combination comprises the following steps: adding the components of the polycarbonate combination as required into a blender mixer, and evenly stirring and mixing; and carrying out melt mixing, extrusion and granulation on the evenly mixed raw materials in eight temperature areas of a double-screw extruder. The polycarbonate combination provided by the invention has excellent photodiffusion performance, high light transmittance, excellent flame retardant property, safety, environmental protection, favorable heat resistance, easy molding and reduced crystal point defect.