The invention discloses a method for preparing a
reaction type transparent
halogen-free
flame retardation
unsaturated polyester. A program
temperature control melting
polycondensation reaction method is adopted; C2-6 dihydric
alcohol, C3-8 saturated
binary acid or anhydride, C4 unsaturated
binary acid or anhydride, and a difunctional reactivity phosphatic
flame retardant are used to synthesize an
unsaturated polyester oligomer;
styrene is taken as a crosslinking agent to prepare the
unsaturated polyester which can be solidified at
room temperature with transparent appearance, moderate
viscosity and lower cost. After solidification, no added dissociated
flame retardant component is contained in the cross linked network of the unsaturated
polyester. The
mechanical property, the flame retardation property and the
electricity property of the product can be stable in a long period, the
oxygen index of the product can be increased from 19 to 29 percent, and the product can pass the vertical firing UL94-V0 level. The
reaction type transparent
halogen-free flame retardation unsaturated
polyester can be applied to the field of electronic and electric appliance insulating materials with higher performance requirements, construction flame retardation
coating, ship-
building material, flame retardation
fiber glass reinforced plastics, and the like.