The invention discloses carbazole group-containing azafluorene orange-light ionic-type iridium (III) complexes including hexafluorophosphoric acid-[di(2-phenylpyridine)]-[9,9-di(9-ethyl carbazole-3-yl)-4,5-diazafluorene] iridium (III) (Ir1), hexafluorophosphoric acid-[di(2-phenylpyridine)]-[9,9-di(9-ethyl hexyl carbazole-3-yl)-4,5-diazafluorene] iridium (III) (Ir2), and hexafluorophosphoric acid-[di(2-phenylpyridine)]-[9,9-di(9-phenylcarbazole-3-yl)-4,5-diazafluorene] iridium (III) (Ir3). When doping concentration of the complex Ir1 is 10%, maximum illumination brightness 907cd / m2 and current efficiency 8.35cd / A are achieved, the maximum peak of an electroluminescence spectrum is observed at 568nm, color coordinates (CIE) x=0.45, and y=0.53, orange light is emitted, and relatively weak efficiency roll off of parts is observed. Electroluminescence devices made from the complex Ir2 and Ir3 possess similar performance.