The invention discloses a decyl imidazole blue-light emission organic light-emitting material and a preparation method thereof .N-decyl is introduced into an imidazole structure unit, a phenanthroimidazole compound obtained through triphenylphosphine oxide functionalization is formed, the solid light-emitting characteristics, flame retardance, compatibility and machinability of the material are achieved while the solubility of the material is improved, and meanwhile the blue-light emitting characteristics of the material are kept .The preparation method is easy to implement and environmentally friendly, synthesis is convenient, the adopted solvents can be recycled and reduced, the obtained product is easy to purify and can be used as the blue-light conversion material for agricultural film production, the light quality of agricultural films is improved, the material can also be used as the blue-light emitting material for the fields of light-emitting devices, anti-fake materials, fluorescent sensing and the like, and the material can be used through solvent dissolution processing and can also be used as a solid material to be directly used, so that use is quite convenient .