The invention provides a method for recycling and regenerating PCB (
Printed Circuit Board) acidic and
alkaline etching waste liquid. The method comprises the following steps: feeding acidic and
alkaline etching waste liquid and an alkaline extracting agent into a centrifugal extraction
system under the driving of power in a ratio of 1:4, and mixing, agitating and separating, wherein
copper ions of the separated
etching liquid are reduced to be lower than 50g / L and thus the acidic and
alkaline etching waste liquid is regenerated; blending the regenerated acidic and alkaline
etching waste liquid and returning back to a
production line for cyclic utilization; after separating, feeding the extracting agent into a centrifuging
water washing groove; after washing with water, feeding the extracting agent into a centrifugal
backwashing groove, mixing with 190g / L dilute
sulfuric acid and stirring so that the extracted
copper ions are converted into
copper sulfate; conveying the
copper sulfate into a centrifugal
electrolysis system, and producing a
pipe type
electrolysis copper
pipe under the effect of
direct current, wherein the copper content of the copper
pipe is 99.95%; and after
backwashing, conveying the extracting agent into an extracting agent chamber for cyclic utilization. With the adoption of the method, the problems in the prior art that the extracting agent is easy to lose,
sulfate ions easily enter regenerated liquid, an electrolytic bath is likely to generate
short circuit in the operation process, the occupied area of equipment is large can be solved.