The invention discloses a preparing method for a modified
graphene oxide-
piezoelectric polymer energy-storing thin-film device. According to the preparing method, at first, a thin-
film material is prepared, perfluoro nitrine
benzoic acid and
graphene oxide are subjected to a covalent reaction through heating so that micro-molecular modifying agents can be connected to the surface of modified
graphene oxide, then the modified graphene oxide is washed cleanly through ethyl
alcohol, frozen, dried, and then dispersed in N, N-
dimethylformamide in an ultrasonic mode, a certain quantity of
polyvinylidene fluoride-
hexafluoropropylene copolymers is added, the mixture is heated and stirred, a tape-
casting method is used for preparing a composite thin film, after heating is carried out to remove
solvent, the thin film is cooled and recrystallized, then the thin film and a substrate are soaked in water, and the thin film is taken down; finally, the prepared thin film is prepared into the device, two pieces of
copper foil are connected to the upper face and the
lower face of the thin film respectively to serve as current collectors, wires are led out of the
copper foil, or the
copper foil can be directly connected with a test instrument for testing, and namely the flexible thin-film device integrating an
electricity generation ability and an
electricity storage ability is prepared.