The invention discloses a hierarchical structure
glass fiber and
lithium metal compound and a preparation method thereof, and relates to the technical field of battery cathodes. The hierarchical structure
glass fiber and
lithium metal compound comprises a
lithium layer, a
glass fiber layer is arranged in the lithium layer, and the bottom end of the glass
fiber layer is completely wrapped in the lithium layer. The top end of the glass
fiber layer is exposed outside the lithium layer, conductive
layers are arranged on the middle and lower surfaces of glass fibers, and the upper ends of the glassfibers are exposed. The conductive
layers have lithium affinity and
electronic conductivity, and the exposed top end of the glass
fiber layer has no electronic or
ionic conductivity. The deposited lithium ions can only obtain the electrons on the glass fiber with a modification layer on the surface of a
composite electrode, and cannot obtain the electrons at the topmost end of the glass fibers, so that the lithium dendrites and dead lithium exceeding the thickness of the glass fiber on the surface cannot be formed, the overall thickness of the
electrode is controllable, and the battery safetyis high. The surface of the topmost end of the glass fiber is electronically insulated, and battery
short circuit cannot be caused after a diaphragm is attached in the battery. The
metal lithium at the
lower half part of the glass fiber is responsible for supplementing a lithium source, so that the battery cycle performance is guaranteed.