The invention discloses a method for segregation and purification of high-purity aluminum. The method comprises the following steps that a segregation furnace is started up for preheating, a non-stickaluminum
coating is sprayed on the inner wall of a
crucible, and then the inner wall of the
crucible is preheated, the preheated
crucible is put unit the segregation furnace,
metal molten aluminum orrefined electrolytic aluminum liquid is poured into the crucible, the cooling water on the outer wall of the crucible is opened, when the temperature of the aluminum liquid is reduced to a set value,the upper cover of the segregation furnace is closed, and a heating device, a stirring device and a vacuumizing device of the segregation furnace are opened; during the solidification and growth of an aluminum
crystal, the temperature of an aluminum melt is controlled through a temperature measuring device, a purification
heat conducting layer is subjected to forced cooling through a cooling device, a
temperature gradient of the
solid-
liquid interface of the aluminum melt in the crucible is controlled between 5 DEG C and 20 DEG C, the growth rate is monitored in real time, and the
heating temperature and the cooling
water flow of the segregation furnace are adjusted and corrected in real time according to the growth rate. According to the method, the
solid-
liquid interface can be accurately controlled to maintain a stable
temperature gradient, the concentration of impurities in the melt at the
front edge of the
solid-
liquid interface is reduced, thus the solidification process is controlled, and high purification efficiency and quality is maintained.