The invention relates to an
ultrasonic atomization atmospheric-pressure glow-
discharge ionization apparatus. The apparatus comprises an
ultrasonic atomization apparatus, an atmospheric-pressure glow-
discharge apparatus, a high-
voltage power supply and a sample inlet interface, wherein the
ultrasonic atomization apparatus comprises a sample inlet
pipe, a sample container, a liquid inlet pump, an
ultrasonic atomizer and a spraying
nozzle; the sample inlet
pipe is connected with the sample container and the liquid inlet pump; the liquid inlet pump is used for extracting a
water sample of a liquid sample; the liquid outlet end of the liquid inlet pump is connected with the
ultrasonic atomizer; and the atmospheric-pressure glow-
discharge apparatus comprises a discharging needle, a high-
voltage glow
reaction chamber and a sample inlet conical opening. By virtue of ultrasonic atomization, the liquid sample, which is not suitable for volatilization, can be directly sampled, without requiring complex pretreatment, so that sensitive and rapid
mass spectrometry can be realize; and therefore, the ultrasonic atomization atmospheric-pressure glow-discharge
ionization apparatus is wide in application prospect in rapid
mass spectrometry of food, pesticides, environment and the like.