475results about How to "Good viscosity increasing effect" patented technology

The invention discloses a temperature resistant salt tolerant high efficiency gel and a preparation method and application thereof. The preparation method is characterized in that the preparation method comprises the following steps: preparing a comb-shaped associated copolymer PAH containing macromonomers and functional hydrophobic monomers into an aqueous solution having the concentration of 0.1 to 4g / L, the crosslinking agent concentration of 0.01 to 1.0g / L, the surfactant concentration of 0.01 to 8mmol / L and the sodium sulfite thermal stabilizer concentration of 0.005 to 1.0g / L; adding the aqueous solution into a mixing container with a stirring device; stirring the aqueous solution evenly at the room temperature; regulating the pH value of the solution to be equal to between 4 and 11, and obtaining a temperature resistant salt tolerant high efficiency gel polymer solution system used for tertiary oil recovery and scavenge, displacement modification, profile modification or water shutoff. The polymer solution system has micro-crosslinking to form the gel during the flowage inside the oil reservoir. The gel has good elasticity, not easy dehydration, stable gelling performance, and excellent tackification, temperature resistance, salt tolerance, shearing resistance and ageing resistance.

The invention discloses acrylamide modified polymer micro-crosslinking gel and a preparation method thereof. The preparation method is characterized in that the method comprises the following steps that: acrylamide modified polymer PAE containing functional macro monomer is prepared into an aqueous solution with the concentration between 0.1 and 4g / L, the concentration of crosslinking agent between 0.01 and 1.0g / L, the concentration of surface active agent between 0.01 and 8mmol / L and the concentration of heat stabilizer sodium sulfite between 0.005 and 1.0g / L; the aqueous solution is added in a mixing container with a stirring device and is stirred evenly at room temperature; the pH value of the solution is adjusted between 4 and 11 to prepare a polymer solution system of the acrylamide modified polymer micro-crosslinking gel used for tertiary oil recovery and displacement, oil displacement modification, profile modification or water plugging; and the polymer solution system undergoes micro crosslinking during flowing inside an oil layer to form the gel. The acrylamide modified polymer micro-crosslinking gel has ideal elasticity, difficult dehydration, stable performance and excellent performances on tackifying, temperature resistance, salt resistance, shearing resistance and ageing resistance.

The invention discloses a water soluble copolymer with high viscosity and salt resistance, and a preparation method and an application thereof. The preparation method comprises the steps of: adding acrylamide 20 weight parts, an anionic monomer or / and a cationic monomer 0.1-15 weight parts,, a vinyl polycyclic aromatic hydrocarbon 0.05-4 weight parts,, a surfactant 0.5-90 weight parts,, and deionized water 70-900 weight parts, into a three-neck reaction bottle, adjusting the solution pH to 2.5-9, introducing N2 for 30min, adding an initiator persulfate 0.001-0.2 weight parts, at 20-70DEG C, and reacting for 6-36 hours to obtain a low-molecular weight water soluble copolymer with molecular association ability, high viscosity and salt resistance, which can be used in intermediate-permeability oil reservoir and low-permeability oil reservoir development. An associated water soluble polymer oil displacement agent is obtained by preparing the copolymer into an aqueous solution with copolymer concentration of 0.3-3 g / L and surfactant concentration of 0.01-4 mmol / L, adding into a mixer with a stirring device, and stirring uniformly at room temperature; and the obtained oil displacement agent has high viscosity, salt resistance, temperature resistance and shear resistance, and can be used in intermediate-permeability oil reservoir and the low-permeability oil reservoir development.

The invention relates to a temperature and salt resistant copolymer KWKY-PAD for oil field and a preparation method thereof, and mainly solves the problem that polyacrylamide is easy to hydrolyze at high temperature and high salinity in the prior art. The temperature and salt resistant copolymer KWKY-PAD as shown in formula (I) is obtained by the copolymerization of acrylamide and a N-alkyl substituted acrylamide derivative. The technical scheme provided by the invention greatly solves the problem. By the adoption of the preparation method, the hydrolytic stability of the copolymer is raised,and the copolymer has good viscosifying ability and hydrolytic stability at high temperature and high salinity as well as good temperature and salt resistance. The copolymer provided by the inventioncan be used in an oil displacement agent for oil extraction in oil field, and also can be used in oil field application fields of a thickening agent of fracturing fluids, a water plugging profile modification agent, a drilling fluid processing agent and the like. In addition, the preparation method requires less monomer, is simple and is suitable for industrialization.

The invention discloses a viscosifier for drilling fluid and a preparation method thereof. An amphiprotic hydrophobic association type water-soluble viscosifier for drilling fluid is prepared by steps of mixing water-soluble monomers with hydrophobic monomers to perform a polymerization reaction, wherein the water-soluble monomers and the hydrophobic monomers have different ion categories. Amphiprotic ionic groups simultaneously exist in the structure of the viscosifier for drilling fluid provided by the invention to effectively absorb or bridge clay particles so as to guarantee an excellent tackifying effect; meanwhile, the ionic water-soluble monomers can be used for greatly improving the content of hydrophobic units in the polymer structure through hydrophilic ionic groups on the condition of high macromolecular water-solubility; and the ionic hydrophobic monomer units are introduced to guarantee the tackifying effect and water loss reduction effect of the viscosifier under high-temperature and high-salt conditions through hydrophobic association. As shown in an experimental result, the viscosifier provided by the invention still has excellent tackifying performance when the temperature is as high as 260 DEG C, and meanwhile, the viscosifier has excellent high-temperature and high-pressure water loss performance, so that the viscosifier has extensive practical application prospect and economic benefit.

The invention relates to a hydrophobically associating polymer and mixed surfactant binary compound oil displacement system for use in tertiary oil extraction. The system mainly comprises the following components in percentage by weight: 0.1 to 0.3 percent of hydrophobically associating polymer, 0.1 to 0.6 percent of surfactant and 99.2 to 99.8 percent of water. The hydrophobically associating polymer in the system has high temperature resistance, high salt resistance and viscosity increasing capacity and can largely reduce dosage of polymer; and with high solubilizing capacity, the polymer can increase the dissolution of the surfactant in sewage, thereby increasing the use concentration of the surfactant. The oil displacement system which is dissolved by sewage from extraction can save lots of fresh water; with high viscosity increasing capacity, the system can effectively control flow rate, increase swept volume, increase oil water interface tension to 10<-3>mN / m and increase the oil extraction rate; and because of high stability and injection property, the system can be injected in large dose. According to an indoor oil displacement experiment, the binary compound oil displacement system can improve the extraction rate by over 20 percent compared with that of water displacement. The system without alkali avoids serious damage to the oil layer and corrosion and damage to oilpipes and has a great application prospect.

The invention provides an acrylamide polymer thickener and a preparation method thereof, and a fracturing fluid, wherein the acrylamide polymer thickener is composed of the components by the mass percentage: 20%-45% of a hydrophilic propenyl monomer, 4%-6% of a hydrophobic propenyl monomer, 1%-2% of an emulsifier, 0.2%-0.5% of an initiator, a latent crosslinking agent and the balance water, wherein the latent crosslinking agent accounts for 0.5%-1.8% of the total mass of the hydrophilic propenyl monomer and the hydrophobic propenyl monomer; the acrylamide polymer thickener provided by the invention solves the technical problems in the prior art that a polymer thickener has poor temperature resistance and salt tolerance and poor shearing stability, and the prepared acrylamide polymer thickener has high-temperature performance, and can effectively meet the requirements of on-site construction of slick water fracturing.

The invention relates to a compounding method to form water solubility intermolecular association ternary hydrophobic association polymer that includes acrylamide, sodium acrylate, and allyl-alkylphenyl aether three constructions. The method includes the following steps: using acetone as reacting solvent, alkylphenols and allyl chloride as raw material, benzyl triethyl ammonium chloride as phase-transfer catalyst, reacting for 4-8 hours at 40-60 degree centigrade to form drainage monomer allyl-alkylphenyl aether; adding sodium acrylate, acrylamide and allyl-alkylphenyl aether monomer into reactor according to the mol ratio as 20-30:69.2-79.2:0.8, adding inducing agent, sealing reacting for 2-6 hours to gain terpolymer. The terpolymer has good temperature resistance, saline tolerance, dissolubility and high temperature stability. The invention is easy to compound and has mild condition.

There is a method of high stickly thick water association polymer degreaser, its character is that the propylene acyl (AM)-natrium acrylate (NaAA)-N-p-butyl benzene propylene acyl (BPAM) thick water association water soluble polymer is confected into 0.1-0.3 wt% thickness, the thickness of surface active agent is 0.01-1 mmol / liter and the thickness of NaCL is 0.5-1.5 wt5, they are added into blending pot which has blender and thermometer, they are blended under 25-40 degree C equably, the degreaser is got.

The invention discloses a comb-type amphipathicity water-solubility multipolymer and a method for making the same as well as an application. The method is characterized in that: 20 portions of acrylamide, 0.1 to 10 portions of negative ion monomer, 0.5 to 15 portions of at least one of the surface activity macromolecular monomer 4-vinyl benzyl alkylphenol polyoxyethylene ether or / and allyl alkylphenol polyoxyethylene ether and 30 to 600 portions of deionized water are added into a three-necked reaction bulb, the pH value of the solution is adjusted to between 4 and 9, N2 is introduced into the solution for 30 minutes, 0.002 to 0.3 portion of evocating agent sulphate is added at the temperature of between 30 and 70 DEG C to react 12 to 36 hours in order to prepare PABE which is diluted by water to obtain the PABE strong solution; the comb-type amphipathicity water-solubility multipolymer which can viscosify, has salt resistance and the low surface tension as well as the molecular association ability and can be used for the fuel scavenge. The multipolymer is prepared into a water solution with a mass concentration between 0.3 and 3g / L and a surface active agent concentration between 0.01 and 2mmol / L, the water solution is added into a blending container with a stirring device and is stirred evenly at room temperature so that the polymer oil-displacing agent which can viscosify and shear-resistant and has excellent anti-aging performance in a hyperhaline state and at the temperature of 70 DEG C. The PABE has the double function of a tackifier and a macromolecule surfactant. Infinitesimal low molecular surface active reagent is added into the PABE solution, thereby evidently increasing the apparent viscosity of the solution, reducing the surface tension and the oil-water boundary tension of the solution and contributing to improving the recovery ratio.

The invention discloses a copolymer with temperature resistance and water solubility and the preparation method and application thereof, which is characterized in that: 20 portions of acrylic amide, 0.1 to 10 portions of anion monomer or / and cation monomer, 0.05 to 3 portions of fluorine-containing styrene or / and perfluoroalkyl styrene hydrophobic monomer, 0.5 to 60 portions of surface active agent and 50 to 700 portions of deionized water are put into a three-necked reaction bulb; after the solution pH is regulated to be equal to 2.5 to 9 and N2 is connected for 30 minutes, 0.001 to 0.2 portion of an evocating agent of persulfate is added under temperature of 20 to 70 DEG C, reacting for 6 to 36 hours, and PATF is prepared. Then water is used for diluting so as to prepare PATF concentrated solution, thus obtaining a copolymer that has medium molecular weight and water solubility, is high-temperature resistant, has an ability of molecular association and can be used in high temperature and high salinity reservoir. The copolymer is prepared into aqueous solution with a mass concentration of 0.3 to 3g / L and a surface-active-agent concentration of 0.01 to 4mmol / L, which is put in a blending container with a dasher and is stirred even at room temperature to prepare a polymer oil-displacing agent which is high-temperature resistant, high tackifying and anti-sharing and has excellent aging resistance under high salinity and the temperature of 110 DEG C. The prepared oil-displacing polymer has excellent solution properties owing to the supermolecular structure formed by the association between molecules of fluorine-containing cinnamene or / and alkylbenzene hydrophobic groups, thus having favorable application prospects in high temperature and high salinity reservoir exploitation.

The invention discloses a kind of hydrophobic association polyacrylamide and its preparative method. The product is the copolymer of acrylamide and dendritic I branch-like hydrophobic monomers, in which, the amount of monomeric unit of acrylamide is integer of 124013~139860, the amount of monomeric units of dendritic hydrophobic monomers is integer of 140~6527. In the invention, high degreed branching hydrophobic monomers are inlet on a chain of macromolecules by the way of micelles' copolymerization, the monomers can promote the capability of hydrophobic interaction of polymers' chain without any curling for its greater hydrophobic volume, so a better viscosity can be achieved. The content of the hydrophobic chain can be controlled by the way of controlling the amount of hydrophobic monomers to improve the solubility of copolymer

The invention discloses a hyperbranched hydrophobical-associating water-soluble polymer and its preparation method. The polymer is obtained through copolymerizing acrylamide, acrylic acid, a hydrophobic monomer and functional hyperbranched macromolecules. The preparation method of the polymer comprises the following steps: 1, respectively dissolving a hyperbranched polyamide-amine macro-molecular skeleton treating diethylenetriamine as a core and maleic anhydride (or acryloyl chloride or acrylic anhydride) in dimethyl sulphoxide, slowly adding the skeleton monomer solution to the maleic anhydride solution in a dropwise manner, letting in nitrogen, placing the obtained system in an icy salt bath, stopping the dropwise addition of the skeleton monomer solution when the pH value of a reaction solution reaches 4-5, and precipitating with chloroform to obtain a functionalized skeleton monomer; and 2, carrying out free radical aqueous solution polymerization of sodium acrylate, acrylamide, the hydrophobic monomer dimethylallyl-N-alkylammonium chloride and the functional skeleton monomer. The preparation method has a reliable principle and is simple to operate, and the synthesized polymer still has a good thickening capability and a good seepage performance under a high mineralization degree and a strong shearing action.

The invention provides a tackifier for a drilling fluid, and a preparation method and application thereof. The tackifier is a quadripolymer formed by polymerization of four alkene monomers, wherein the four alkene monomers are selected from a temperature-resistant salt-tolerant monomer, a hydrated monomer and an adsorptive monomer; the temperature-resistant salt-tolerant monomer is selected from an alkenyl sulfonic acid monomer; the hydrated monomer is selected from alkenyl carboxylic acid, alkenyl alkane ketone and double-bond-containing quaternary ammonium salt compounds; and the adsorptive monomer is selected from an alkenyl amide monomer. The tackifier provided by the invention can resist a high temperature of no less than 180 DEG C, is resistant to saturated salt, has remarkable tackifying effect, is low in toxicity and environmentally friendly, and can obviously improve the dehydration and wall building capability of the drilling fluid, thereby effectively reducing the dehydration. The invention solves the downhole complexity possibly caused by the fact that the drilling fluid system can not carry and suspend rock debris and thus can not clear boreholes in time due to reduced viscosity shearing force as a result of poor temperature resistance and salt tolerance of the tackifier in deep well, ultradeep well, horizontal well and extended reach well operations.

The invention discloses a hydrophobically associating polymer, a preparation method and an application thereof. The hydrophobically associating polymer is shown as formula I, wherein x is 0.001-0.01, y is 0.7-1.0 and X is C1, Br or I. The preparation method comprises the steps of uniformly mixing acrylic acid, acrylamide, hydrophobic monomer, light initiator and ethylene diamine tetraacetic acid in deionized water, allowing reaction in illumination conditions; and after reaction, obtaining the polymer. The invention adopts ultraviolet-induced polymerization, so that the total activation energy is low and the reaction can be performed at low temperature; the product has better repeatability and the product quality is more stable; the polymerization can be controlled by powering on and powering off, at the same time the performance of the hydrophobically associating polymer can be controlled by controlling illumination time and light source strength. The polymer of the invention shows better dissolubility and viscosity in water and can form a space network structure in the solution.

The invention relates to a polymer mobility control agent suitable for a high-temperature and high-salinity harsh reservoir and a preparation method of the polymer mobility control agent, and the polymer mobility control agent is mainly used for solving the problems that the polymer in the prior art is poor in heat and salt resistance and long-term stability, and cannot meet the requirements of tertiary oil recovery. In order to better solve the problems, the technical scheme adopted by the invention is as follows: an amphoteric hydrophobic association polymer is prepared from the following raw materials in parts by weight: 5-99.9 parts of a non-ionic water-soluble monomer, 0-50 parts of an anionic monomer or / and cationic monomer, 0.1-10 parts of a hydrophobic monomer with surface activity, 0-20 parts of a viscosity stabilizer and 0-20 parts of a surfactant. The preparation method can be applied to industrial production and application of the polymer mobility control agent for the high-temperature and high-salinity harsh reservoir.

A water-soluble zwitterionic copolymer contains two structure units: 2-methyl-2- acrylamido propanesulfonic acid and methyl acrylyloxyethyl trimethyl ammonium chloride. Its preparing process includes such steps as proportionally adding the anhydrate sorbitol monooleate and the anhydrated sorbitol monostearate to kerosene, proportionally dissolving two monomers in water and regulating its pH=7, proportionally mixing oil phase with water phase, filling N2, adding redox trigger, and redox reaction in constant-temp water bath.

The invention relates to a preparation method of a high-temperature-resistant high-salt polymer oil-replacement agent, which comprises the following steps: dissolving 10-20 parts by weight of anionic monomer, 50-65 parts by weight of sodium allylsulfonate, 11-22 parts by weight of cationic monomer, 2-4 parts by weight of acrylate, 0-3.5 parts by weight of alpha-alkene and 50-60 parts by weight ofacrylamide in deionized water, wherein the total mass concentration of the monomers is 15-23%; adding a surfactant which accounts for 1-5% of the total weight of the monomers, regulating the pH valueof the solution to 9-10, introducing ammonia gas at 30-60 DEG C for 30 minutes, and adding a persulfate initiator which accounts for 0.05-0.1% of the total weight of the monomers; and reacting at 30-60 DEG C for 12 hours, precipitating with acetone, washing, and carrying out vacuum drying to obtain the white powdery polymer. The invention is characterized in that long-carbon-chain alkyl group, anionic and cationic unit structures are introduced into the water-soluble polymer macromolecules to obtain the high-temperature-resistant high-salt water-soluble polymer oil-replacement agent.

The invention provides a water-based clean fracturing fluid for fracturing. The fracturing fluid is formed by a small canonic antiswelling agent, organic sodium salt, a cationic surface active agent and water, wherein the concentration of the small canonic antiswelling agent is 0.4 percent by mass, the concentration of the organic sodium salt is 0.06 to 0.18 percent by mass, the concentration of the cationic surface active agent is 0.2 to 0.6 percent by mass, the mass ratio of the cationic surface active agent and the organic sodium salt is 1:0.3, the organic sodium salt is sodium salicylate, and the cationic surface active agent is any one or the mixture of 16-18 alkyl-3-methylammonium chloride. The invention can well solve the pollution problem of the fracturing fluid to the coal bed, simultaneously improve the sand-carrying performance of the fracturing fluid greatly, the price thereof is only 1.5 to 2.0 times of active water fracturing fluid and is far lower than that of guargum fracturing fluid and common clean fracturing fluid.

The invention relates to a fracturing fluid thickening agent and preparation and application thereof. The thickening agent is mainly prepared from the following components in percentage by weight: 15-20% of acrylamide monomer, 6-10% of acrylic monomer, 3-6% of sodium carbonate, 3-8% of 2-acrylamide-2-methylpropanesulsonic acid, 1-4% of dimethyldiallylammonium chloride (60% aqueous solution), 0.03-0.08% of potassium persulfate and the balance of water. The preparation comprises the following steps of: adding the acrylic monomer and water into a reaction kettle; starting stirring and slowly adding sodium carbonate, wherein the adding speed is proper when the bubbles generated by the reaction do not overflow out of the reaction kettle; stirring till sufficient dissolution; adding 2-acrylamide-2-methylpropanesulsonic acid, and stirring till sufficient and uniform mixing; adding the acrylamide monomer and dimethyldiallylammonium chloride, and stirring till sufficient dissolution; heating the reaction liquid to 40 DEG C, introducing nitrogen, and performing thermal insulation stirring for 20 minutes; adding potassium persulfate; continuously introducing nitrogen, and stirring for 30 minutes; stopping the stirring, and reacting for 4 hours to obtain gel; and grinding the reaction product, drying and granulating to obtain the thickening agent.

The invention provides a temperature resist, salt resist crosslinked polymer system with controllable crosslinking time and strength, comprising water, polyacrylamide, melamine, formaldehyde and additive, wherein the polyacrylamide 0.03-8 weight%, melamine 0.01-4 weight%, formaldehyde solution(35-38weight%) 0.03-10 weight%, additive <2 weight%. The salt content of oilfield sewage is less than 35 *104mg / L, the total content of Ca2+ and Mg2+ is less than 5000mg / L. The temperature range of reservoir bed is 30-110 degree, the crosslinking time is 6 hours-25 days, and the viscosity after crosslinking is less than 40*104mPa.s. The long-term stability is good. The viscosity is greatly increased compared to oil displacement of polymer, suitable for reducing the use concentration of polyacrylamide and the cost is reduced, at the same time the oil displacement effect is increased and the treatment difficulty of output liquid is reduced. The crosslinked polymer system can be useful for recycling the polyacrylamide output liquid of high concentration. The invention can be used in oilfield profile controlling, exclusion of water, leak stopping and oil displacement technique. The locale preparation is simple.

The invention discloses an inorganic-organic salt-resisting and high temperature-resisting polymer fluid loss additive for drilling fluid, which is characterized in that: 2-acrylamide group-2-methyl sodium propanesulfonic acid, dimethyl diene propyl group ammonium chloride, acrylamide and sodium acrylate are used as main polymers, and inorganic salt is used as transformation temperature stabilizing agent. Aqueous solution is prepared according to a certain mass ratio, initiators are added for polymerization at certain temperature, so as to generate macromolecule polymer of elastic colloid, and after drying and grinding are carried out, a target compound is obtained. The additive is easy to dissolve in water, has good capacity of filtration loss reduction, temperature resistance, salt resistance, calcium resistance and magnesium pollution resistance, has good tackifying effect, can effectively control mud making of the stratum and inhibit the dispersion of clay and drilling cuttings, and has good compatibility with the common treating agents.

The invention relates to a pre-crosslinking gel retarding-swelling microsphere profile control agent and a preparation method and application thereof. The pre-crosslinking gel retarding-swelling microsphere profile control agent comprises a polyacrylic acid grafting prepolymer, an acrylamide monomer, a hydrophobic monomer, an anti-salt monomer, a temperature-resistant tackifying monomer, pure alkaline, a composite surfactant, modified kaolin powder, a composite crosslinking agent, an initiator and deionized water. The pre-crosslinking gel retarding-swelling microsphere profile control agent has the advantages that by selecting particular components, particularly modifying multiple components, and utilizing the comprehensive synergistic and promoting functions of multiple technical features, the profile control agent with excellent result is obtained; the excellent high temperature-resistant property, high salt-resistant property, good tackifying property, plugging property and the like are realized; the good application prospect and industrial potential are realized in the field of petroleum exploitation.

The invention discloses adamantyl-containing hydrophobic association zwitter-ion xanthan gum and a preparation method thereof. The adamantyl-containing xanthan gum is prepared from raw materials in parts by weight as follows: 30-120 parts of xanthan gum, 1-2 parts of adamantly hydrophobic monomers, 30-70 parts of alkenyl amide, 25-60 parts of alkenyl carboxylate and 10-30 parts of alkenyl quaternary ammonium salt. The preparation method comprises steps as follows: Step one, all the raw materials are dissolved in distilled water and stirred at the room temperature until complete dissolution, and the solution is poured into a reactor; Step two, a surfactant is added to the reactor; Step three, an initiator is added to a reaction system obtained in Step two; Step four, absolute ethyl alcohol is added to a colloidal crude product obtained in Step three for precipitation, filtration is performed, and a finished product of the adamantyl-containing hydrophobic association zwitter-ion xanthan gum is obtained. The xanthan gum and the preparation method have the benefits as follows: the anti-polyelectrolyte effect of the solution is enhanced and the salt resistance is improved.

The invention discloses a concrete viscosity adjusting agent and a preparation method thereof. The concrete viscosity adjusting agent is prepared by copolymerizing a cationic monomer, an anion carboxyl monomer and an inner cross-linking agent together with a free radical, wherein the mole ratio of the cationic monomer to the anion carboxyl monomer and the inner cross-linking agent is 1:(0.5-5):(0.01-0.1). As the cationic monomer and the anion carboxyl monomer are adopted to copolymerize to obtain an amphoteric polymer, the concrete viscosity adjusting agent has remarkable antipolyelectrolyte property and is relatively good in viscosity improvement property; due to adoption of the inner cross-linking agent, three-dimensional net-shaped structures are formed among the viscosity adjusting agent and binding material grains, the concrete disintegration bleeding problem is greatly solved, and the peaceability of concrete is improved. The prepared concrete viscosity adjusting agent is good in compatibility with other additives, the strength development of concrete is not affected, and particularly the concrete disintegration bleeding problem can be effectively solved under the condition of low binding materials.

The invention belongs to the technical field of a chemical reagent for oil production, and discloses a viscosity-increasable profile control agent and a preparation method thereof. The profile control agent is obtained through adding functional monomers, inorganic nanometer particles, main crosslinking agents and auxiliary crosslinking agents into an acrylamide monomer water solution, introducing nitrogen gas to remove dissolved oxygen and adding initiators under the water bath condition of 40 to 60 DEG C for polymerization; after the polymerization is completed, pelleting, drying and crushing are performed; a final product is obtained. The prepared profile control agent can realize the continuous viscosity increase on formation water to achieve a certain displacement effect; meanwhile, good anti-salt performance is realized; the water absorption swelling can be generated in the high-concentration salt brine; after the expansion, high intensity is still realized, so that the high seepage layer in an oil deposit can be effectively sealed and plugged; the profile control effect is achieved.

The invention relates to an oil-displacement composition with improved injectivity, and a preparation method and application thereof. The main objective of the invention is to overcome the problems of poor injectivity at zones near a well on site due to proneness to obstruction at pore throats of strata caused by strong adsorption effect of hydrophobic associated polymers on the surface of sandstone. The oil-displacement composition with improved injectivity comprises, by weight, 0.01 to 1 part of an anti-adsorption agent, 0.3 to 3 parts of a hydrophobic associated polymer and 96 to 99.69 parts of water, wherein the anti-adsorption agent is at least one or a mixture of two or more selected from a group consisting of nonionic surfactants and anionic surfactants. The oil-displacement composition provided by the invention perfectly overcome the above-mentioned problem and can be used for on-site injection of a polymer fluidity control agent into a high-temperature high-salt severe oil reservoir for oil displacement.

The invention relates to adamantyl contained hydrophobic association zwitter-ion starch and a preparation method thereof. The zwitter-ion starch is prepared from raw materials of starch, adamantyl hydrophobic monomer, alkenyl amide, alkenyl carboxylate and alkenyl quaternary ammonium salt. According to the invention, the adamantyl hydrophobic monomer is introduced to polymer molecules, so that the modified starch has a hydrophobic association property and the viscosity increasing capacity of the starch is increased. As an anion group and a cation group are introduced in the starch molecule chain simultaneously, the anti-polyelectrolyte effect of the solution is enhanced and the salt resistance is improved.

The invention provides a method and a device for tackifying a rail train and a wheel rail. By the method and the device, tackifying of the wheel rail under a clean dry state can be realized, tackifying effect is good, and control is simpler and easier to implement. The tackifying method includes: 11), setting a jetting and sweeping device capable of generating jetting air and sweeping the wheel rail; 12), heating gas forming the jetting air in the jetting and sweeping device to a preset temperature; and 13), enabling the jetting and sweeping device to move along with the rail train and sweep a rail face and a contact area of the wheel tail and the wheel rail at a preset air speed. The tackifying device comprises the jetting and sweeping device capable of jetting air and sweeping and a heater for heating the gas forming the jetting air in the jetting and sweeping device to the preset temperature, and an air jetting position of the jetting and sweeping device is arranged correspondingly to the contact area and the rail face. By the method and the device for tackifying the rail train and the wheel rail, the contact area of the wheel rail and the rail face can be swept through air energy, good contact adhesiveness of the wheel rail can be guaranteed to enable the wheel rail to normally run, and control of the device is simpler and easier to implement.

This invention discloses slurry for protecting the walls during nonexcavating drilling. The slurry comprises: water 100 parts, bentonite 3-10 parts, and slurry-treating agent 0.75-2.5 parts. When the bentonite is calcium soil, the slurry-treating agent comprises sodium carbonate, Na-CMC and biotreating agent, and the proportions are: calcium soil 5-10 parts, sodium carbonate 0.25-0.5 part, Na-CMC 0.25-1 part, and biotreating agent 0.25-1 part. When the bentonite is sodium soil, the slurry-treating agent comprises Na-CMC and biotreating agent, and the proportions are: sodium soil 3-8 parts, Na-CMC 0.3-0.6 part, and biotreating agent 0.6-1.5 parts. The biotreating agent is Marchilus pauhoi gum, and Na-CMC is medium viscosity sodium carboxymethylcellulose. The slurry can avoid the difficulties in drilling and expanding the holes, as well as hole caving and pipe sticking.