The invention belongs to the technical field of lithium-ion batteries, and in particular relates to a lithium-ion battery that can be discharged at ultra-low temperatures, including a positive electrode sheet, a negative electrode sheet, a separator spaced between the positive electrode sheet and the negative electrode sheet, and an electrolyte thereof. The electrolytic solution includes, by mass percentage, 5%-10% of lithium salt, 85%-94% of solvent and 1-10% of additive, and the additive is three-arm polyethylene carbonate. In the present invention, the three-arm polyvinyl carbonate additive obtained by the cycloaddition reaction of VC, PS and VEC solvents is added to the electrolyte. Since the additive has a VC ring group, it can form polymerized alkylene on the surface of the graphite negative electrode. The base lithium carbonate film can effectively avoid the side reaction between the electrolyte and the negative electrode; at the same time, the addition reaction of the VEC double bond can effectively inhibit the decomposition and co-embedding of PC on the graphite negative electrode, thus improving the cycle performance of the battery. The high and low temperature resistance performance of the battery.