The invention relates to a method for preparing
rare earth fluoride by taking
rare earth oxide as a
raw material, which comprises the steps of: (1) mixing the
rare earth oxide with water, and adding concentrated
hydrochloric acid into the mixture to generate rare earth
chloride solution; (2) increasing the temperature of the rare earth
chloride solution to be between 70 and 90 DEG C, adding a precipitator into the rare earth
chloride solution, and performing
thermal insulation for 10 to 30 minutes; (3) adding
hydrofluoric acid into a reaction liquid, and performing a
fluoridation reaction for 5 to 30 minutes at a temperature of between 70 and 90 DEG C until the reaction is complete; and (4) obtaining the rare earth
fluoride by a precipitate generated by the reaction through washing, settlement,
filtration and
drying. The method ensures that the formed rare earth
fluoride has large particles and is easy to filter, wash and precipitate after the precipitator, namely
propane diacid is added, and effectively overcomes the disadvantages that the rare earth fluoride is easy for penetration
filtration and is difficult to precipitate in the prior art; a fluorination
endpoint determination method is adopted, which avoids the various problems caused by adding excessive
hydrofluoric acid; and at the same time, mother solution containing
hydrochloric acid can be circularly used, which has less
discharge of waste liquid and is favorable for
environmental protection.