The invention relates to the field of glass new materials, and particularly discloses a manufacturing method for a lead-free sealing glass with a transitional expansion coefficient. The lead-free sealing glass is obtained by using quartz sand, aluminium hydroxide, bismuth trioxide, ferric oxide, sodium carbonate, potassium carbonate, magnesium oxide, calcium carbonate, barium carbonate and zinc oxide as raw materials and through the steps of mixing the above raw materials uniformly, melting the mixed materials and homogenizing to obtain a glass melt, then treating the glass melt by casting, annealing, cutting, buffing, polishing and performing heat treatment under a reduction atmosphere. The manufacturing method for the lead-free sealing glass with the transitional expansion coefficient overcomes various disadvantages in a conventional transitional sealing method, has the advantages of simple sealing process, low cost, easily controllable quality and the like, and is very suitable for situations that the cross section of a to-be-sealed device is in a circle structure.