34results about How to "High molecular sieve content" patented technology

The present invention relates to preparation of a wearing-resistant catalyst, which comprises the following steps: (1) preparing slurry which comprises molecular sieve, binding agent, additive and dispersing agent; (2) mixing each component of the slurry to uniform and reducing particle rate through mixing and grinding; and (3) converting the slurry to formed particles through a forming step; and (4) drying or calcining the formed catalyst; wherein LOI (cutting down) value of the catalyst after drying or calcining is smaller than 8. The invention firstly describes a fact that LOI value reduction of the catalyst can reduce catalyst wearing. In the preparation process, the LOI of the catalyst is reduced so that the prepared catalyst has lower wearing rate. The wearing rate of FCC catalyst is reduced from best 2.5% / hr previously to 0.3% / hr.

The invention relates to a method for preparing a coating slurry for a cellular carrier catalyst, which comprises the following steps: mixing a molecular sieve and water, and grinding to obtain a slurry with the molecular sieve particle diameter d90 of 1-10 microns; mixing the slurry and an Si-Al component with the particle diameter of less than 100nm in the presence or absence of a dispersant; based on the weight of the coating slurry, allowing the content of the molecular sieve in the coating slurry to be 3 to 60% by weight, allowing the weight ratio of a matrix component to the molecular sieve to be 0.1-30:100, and allowing the weight ratio of the dispersant to the molecular sieve to be 0-20:100; and the dispersant being selected from one or more of compounds with molecules containing polyhydroxyl, polyoxyethylene poly vinyl or polycarboxylic acid. The cellular carrier catalyst prepared by the coating slurry containing the molecular sieve composition prepared by the method providedby the invention has the advantages of firmer coating, gasoline conversion, strong ability of olefin conversion and high propylene yield.

The invention relates to a method for preparing low-carbon olefin through methanol dehydration, and mainly solves the problems that the activity of a catalyst and the yield of the low-carbon olefin are low in the conventional technology for preparing the low-carbon olefin through catalytic pyrolysis. In the invention, methanol which is taken as a raw material is contacted with an adhesive-free molecular sieve catalyst through a catalyst bed to generate the low-carbon olefin under the conditions that the reaction temperature is 400 to 600 DEG C, the gauge pressure of the reaction is 0.001 to 0.5MPa, the weight space velocity of the reaction is 0.1 to 4h<-1> and the weight ratio of water to methanol is (0.1-3):1, wherein the pore volume, the average aperture and porosity of the adhesive-free molecular sieve catalyst are tested by mercury porosimetry, the pore volume is 0.31 to 0.5ml / g, the average aperture is 71 to 100nm, and the porosity is 31 to 40 percent. Through the technical scheme, the problems are better solved. The method can be used for the industrial production of the low-carbon olefin through methanol dehydration.

The invention discloses a hydrocracking method, which includes the following contents: (1) Diesel feedstock is mixed with hydrogen and first enters a hydrorefining reactor for desulfurization, denitrogenation and aromatics saturation reaction; (2) Step (1) effluent enters Hydrocracking reactor, along the material direction, the hydrocracking reactor includes the 1st to nth catalyst beds, wherein n≥3, preferably n is 3 or 4, wherein, the 1st to n-1th catalyst beds are filled A hydrocracking catalyst containing a modified Y molecular sieve; the nth catalyst bed is filled with a hydroisomerization catalyst containing molecular sieves such as β or ZSM with strong isomerization performance. The method uses diesel oil as a raw material, increases the production of heavy naphtha with high aromatic potential, and improves the low-temperature fluidity of jet fuel and diesel products through a reasonable combination of hydrocracking catalysts with different functions.

The invention provides a method for synthesizing NaA-type molecular sieve materials from catalytic cracking waste catalysts, using catalytic cracking waste catalysts as raw materials, adding sodium carbonate and sodium silicate, and roasting at high temperature to obtain a solid solution; Hydrothermal crystallization, filter the hydrothermal crystallization product, add the filter material to a certain concentration of sodium hydroxide solution, stir for a period of time, then add a certain amount of sodium aluminate powder, fully stir and leave to age; Stir the aged mixture at a certain temperature, centrifuge the reaction product, rinse with deionized water, and dry to obtain NaA molecular sieve material. The composition of raw and auxiliary materials is simple, the reaction conditions are moderate, and the cost is low. The prepared NaA molecular sieve has a high content of materials and has a good solidification and stabilization effect on heavy metals such as nickel, and realizes resource utilization while harmlessly treating waste catalysts.

The invention relates to a method for preparing light olefin by dehydrating oxygen compound, mainly solving the problems that activity of a catalyst is low and yield of the light olefin is low in the traditional technology for preparing the light olefin through catalytic pyrolysis. In the invention, a method for preparing the light olefin by dehydrating the oxygen compound is adopted, a binder-free molecular sieve is taken as a catalyst, methanol or dimethyl ether is taken as raw material, the raw material is contacted with the catalyst by virtue of a catalyst bed and reaction is carried out to generate the light olefin under the conditions that reaction temperature is 400-600 DEG C, reaction gauge pressure is 0.001-0.5MPa, reaction weight airspeed is 0.1-4 / hour and weight ratio of water to methanol is (0.1-3): 1, wherein pore volume of the binder-free molecular sieve catalyst is 0.1-0.3ml / g, average pore size is 50-70nm, porosity factor is 20-30%, and content of the binder is 0-5%; and strength of the catalyst after moulding and sintering is 60-200N. By adopting the technical scheme, the problems are solved, and the method provided by the invention can be applied to industrial production of the light olefin prepared by dehydrating the oxygen compound.

The invention belongs to the technical field of adsorption materials, and in particular relates to a concentrated runner adsorption material, and also relates to a preparation method of the above-mentioned adsorption material. The adsorption material includes: base material: high silica zeolite molecular sieve ZSM‑5; inorganic binder: fumed silica and activated alumina precursor; dispersant: alcohol ether, lubricant: oil; organic binder : Alcohol and / or cellulose; Purified water. The beneficial effect of the present invention is that the adsorption material obtained by using the raw material and process of the present invention has the advantages of high molecular sieve content, high strength, high specific surface area, high adsorption-desorption ratio, low specific heat capacity, low wind resistance, etc., which solves the problem of traditional molecular sieve Adsorbent materials have problems such as low adsorption efficiency, low strength, poor thermal stability, and short service life.

A preparation method and application of a mixed matrix membrane with a thermoplastic elastomer as a matrix. An unconventional solvent (acid) is used to configure a casting liquid, and the mixed matrix membrane is prepared by casting. When the molecular sieve content reaches a certain level, a layered structure similar to a composite membrane is formed, and the selectivity remains unchanged when the permeation flux is greatly increased, overcoming the traditional compromise relationship between permeability / selectivity . The process of the method is simple and convenient, and the obtained membrane can be used for gas separation, especially CO2 / light gas (N2, CH4, H2, O2) separation.

The invention provides a preparation method for a honeycomb supported catalyst containing a coating of a molecular sieve composition. The method comprises the step of coating a honeycomb support with coating slurry, wherein, the coating slurry comprises a molecular sieve, phosphorus and aluminum components, a dispersant and water, on the basis of the weight of the coating slurry, the content of the molecular sieve in the slurry is 3 to 60 wt %, the weight ratio of the phosphorus and aluminum components to the molecular sieve is 0.1-30:100, the weight ratio of the dispersant to the molecular sieve is 0-20:100, the weight of the phosphorus and aluminum components is counted on the basis of total weight of P2O5 and Al2O3, the weight of the molecular sieve is counted in terms of a dry basis, the dispersant is one compound or more compounds containing polyhydroxy groups, polyoxyethylene groups or polycarboxylic groups, the particle diameter of the phosphorus and aluminum components is less than 100 nm, and the particle diameter d90 of the molecular sieve is 1 to 10 mu m. The honeycomb supported catalyst containing the molecular sieve composition in the invention has a firm coating.

The invention relates to the field of adsorbents, and concretely provides a 5A molecular sieve adsorbent, and a preparation method and an application thereof. The method comprises the following steps:(1) carrying out rolling molding on a powder containing 4A molecular sieve and a binder source to obtain pellets, and drying and calcining the pellets to obtain matrix pellets; (2) pre-wetting the matrix pellets, and carrying out crystal transformation to basically convert the binder in the matrix pellets into 4A molecular sieve in order to obtain 4A molecular sieve pellets; and (3), washing the4A molecular sieve pellets with water, carrying out calcium exchange to obtain 5A molecular sieve pellets, washing the 5A molecular sieve pellets with water, drying the washed 5A molecular sieve pellets, and calcining the dried 5A molecular sieve pellets, wherein the pre-wetting process comprises a stage (1), a stage (2) and a stage (3), and the ambient humidity in the stage (1) and the ambient humidity in the stage (3) are higher than the ambient humidity in the stage (2). The 5A molecular sieve adsorbent has the advantages of high 5A molecular sieve content, large n-pentadecane adsorbing capacity, high adsorbing efficiency and good strength.

The present invention relates to the field of catalyst molding, and particularly provides a titanium-silicon molecular sieve molding method, which comprises: mixing a titanium-silicon molecular sieve and a water-containing mixture, carrying out hydrothermal treatment under a sealed condition, molding the slurry obtained from the hydrothermal treatment to obtain a molding body, and calcining the molding body, wherein the water-containing mixture contains a silicon element, a titanium element and a nitrogen element, and is at least partially derived from the crystallization mother liquor of the titanium silicon molecular sieve. The present invention provides a molding catalyst prepared according to the preparation method, and applications thereof. The invention further provides a cyclohexanone oxidation method. According to the present invention, with the titanium-silicon molecular sieve molding method, the industrial waste liquid is effectively utilized, and the problems of complex process, corrosion on equipment, harmful emission and the like of the traditional process are overcome; and the molding catalyst has characteristics of high titanium-silicon molecular sieve content, high pore volume, high crushing resistance, and high selectivity to the target product.

The invention relates to a preparation method of an aluminum-free MFI structure spherical molecular sieve catalyst. The method includes the steps of: molding an aluminum-free MFI structure molecular sieve, then contacting the molded molecular sieve with an alkaline buffer solution of a nitrogen-containing compound. Specifically, the molding process of the aluminum-free MFI structure molecular sieve consists of: under the rotating operation conditions of a turntable molding machine, (1) placing a molecular sieve raw material of 200-500 meshes in the turnable molding machine to undergo mixing contact with water and / or a binder, thus obtaining spherical particles with a diameter of 0.1-1mm; (2) then adding a molecular sieve raw material of 100-1000 meshes and the binder to obtain a spherical catalyst with a diameter of 1.5-2.5mm; and (3) drying and roasting the spherical catalyst. The spherical molecular sieve catalyst prepared by the method has a high molecular sieve content, crushing strength of 1.5-5.0kg / particle, and can satisfy the technological requirements of fixed-bed and moving-bed reactors.

The invention discloses a hydrocracking method, which comprises the following steps: (1) a diesel oil feedstock is mixed with hydrogen gas and then enters a hydrorefining reactor to carry out desulfurization, denitrification and aromatic saturation reaction; (2) the effluent from step (1) enters a hydrocracking reactor, wherein the hydrocracking reactor comprises at least two catalyst beds, wherein the molecular sieve content of the hydrocracking catalyst containing the modified Y molecular sieve in each catalyst bed increases progressively along the flow direction, and the average pore diameter of the catalyst decreases progressively; (3) the effluent of the hydrocracking reactor is separated into a gas phase and a liquid phase, the gas phase is recycled, the liquid phase enters a fractionation tower, and the fractionating products are obtained and comprise naphtha, aviation fuel, diesel oil and tail oil. The method takes diesel oil as a feedstock and increases the production of high-aromatic latent heavy naphtha through reasonable combination of different functional hydrocracking catalysts, thereby improving the quality of aviation fuel and diesel oil products.

The invention relates to the field of molecular sieve adsorbents, and specifically discloses a 5A molecular sieve adsorbent and its preparation method and application. The 5A molecular sieve adsorbent of the present invention, based on the dry weight of the adsorbent, has a content of 5A molecular sieve in the adsorbent. 92% by weight or more, the crushing rate of the adsorbent at 250N is below 6.9%, and the n-pentadecane adsorption capacity of the adsorbent is above 103 mg / g. The 5A molecular sieve adsorbent provided by the invention has high molecular sieve content, good strength and large adsorption capacity, and is especially suitable for the adsorption of n-pentadecane.