A molecular sieve containing composition, which can be applied in catalytic cracking reaction for producing more ethylene and propylene, and its preparation method. The composition contains a pentasil-type molecular sieve having a SiO2 / Al2O3 molar ratio of 15-60, prepared by activation and modification with phosphorus, alkaline earth metal and transition metal. The composition essentially includes 85 DIFFERENCE 98% wt of pentasil-type molecular sieve, 1 DIFFERENCE 10% wt of P2O5, 0.3 DIFFERENCE 5% wt of alkaline earth oxide, and 0.3 DIFFERENCE 5% wt of transition metaloxide. The molecular sieve structure and active centers have high thermal and hydrothermal stability. The salient feature of this composition is that when applied as an active component of cracking catalyst for catalytic pyrolysis process, the yield of ethylene is above 18% and the total yield of ethylene and propylene is more than 40%.
The present invention belongs to the field of fine chemical technology, and is especially the preparation process of double pore high siliconzeolitemolecular sieve as one kind of composite molecular sieve. The present invention features that by using type-Y high siliconzeolite as silicon and aluminum source, and through dissolving the surface of the high silicon type-Y crystal grain, mixing with ammonia water solution of ammonium tetraethyl bromide, adding certain amount of silica gel via stirring, crystallizing at 140-170 deg.C for 5-10 days, washing, stoving and roasting to eliminate template agent, double pore high silicon zeolitemolecular sieve with both type-Y and type-beta molecular sieve pore canals is obtained. The double pore high silicon zeolite molecular sieve has low synthesis cost and high hydrothermal stability, and may be used in petrochemical industry.
A modified Y zeolite and a preparation method thereof are disclosed; the modified Y zeolite comprises a IVB metaloxide and phosphor, the ratio of distorted four-coordinated framework aluminum to four-coordinated framework aluminum in the lattice structure of the modified Y zeolite is(0.2-0.8):1, and the ratio of zeolite surface IVB metal content to zeolite internal IVB metal content is not higher than 0.5. The preparation method comprises the following steps: acid treatment of zeolite materials, dehydration, immersion of a metal in an organic solvent, treatment of the zeolite immersed with the metal in the organic solvent, treatment of the modified Y zeolite by a phosphorus containing compound and calcination. The modified Y zeolite has high cracking activity, higher gasoline yield and lower coke yield for heavy oil cracking.