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46results about How to "Good thermal and hydrothermal stability" patented technology

Pentasil-type molecular sieve containing composition and its preparation method

A molecular sieve containing composition, which can be applied in catalytic cracking reaction for producing more ethylene and propylene, and its preparation method. The composition contains a pentasil-type molecular sieve having a SiO2 / Al2O3 molar ratio of 15-60, prepared by activation and modification with phosphorus, alkaline earth metal and transition metal. The composition essentially includes 85 DIFFERENCE 98% wt of pentasil-type molecular sieve, 1 DIFFERENCE 10% wt of P2O5, 0.3 DIFFERENCE 5% wt of alkaline earth oxide, and 0.3 DIFFERENCE 5% wt of transition metal oxide. The molecular sieve structure and active centers have high thermal and hydrothermal stability. The salient feature of this composition is that when applied as an active component of cracking catalyst for catalytic pyrolysis process, the yield of ethylene is above 18% and the total yield of ethylene and propylene is more than 40%.
Owner:CHINA PETROCHEMICAL CORP +1

Double micro pore high silicon composite molecular sieve and its preparing method

The present invention belongs to the field of fine chemical technology, and is especially the preparation process of double pore high silicon zeolite molecular sieve as one kind of composite molecular sieve. The present invention features that by using type-Y high silicon zeolite as silicon and aluminum source, and through dissolving the surface of the high silicon type-Y crystal grain, mixing with ammonia water solution of ammonium tetraethyl bromide, adding certain amount of silica gel via stirring, crystallizing at 140-170 deg.C for 5-10 days, washing, stoving and roasting to eliminate template agent, double pore high silicon zeolite molecular sieve with both type-Y and type-beta molecular sieve pore canals is obtained. The double pore high silicon zeolite molecular sieve has low synthesis cost and high hydrothermal stability, and may be used in petrochemical industry.
Owner:TAIYUAN UNIV OF TECH

Beta/ZSM-5 compound borosilicate molecular sieve and preparation method thereof

The invention relates to a beta / ZSM-5 compound borosilicate molecular sieve. Non-water chemical constitution expression of the molecular sieve is: xNa2O.B2O3.ySiO2, wherein, x is 0.03-2 and y is 10-400. The molecular sieve is prepared by adding beta borosilicate molecular sieve, which is taken as inoculating seed, to synthetic materials of the ZSM-5 compound borosilicate molecular sieve by hydrothermal crystallization; therefore, the molecular sieve has strong acidic property and high aromatization performance.
Owner:CHINA PETROLEUM & CHEM CORP +1

Beta molecular sieve of high-content Fe in framework and preparing method of beta molecular sieve

The invention relates to a beta molecular sieve of high-content Fe in a framework and a preparing method of the beta molecular sieve. Tetraethylammonium hydroxide serves as a template agent, a Fe- complex serves as a Fe source, and the Fe-beta zeolite molecular sieve of high-content Fe in the framework is synthesized through a one-step method. The synthesizing method is simple, the silica-alumina ratio can be adjusted, the mass fraction of Fe in the framework can reach 3-8%, and the synthesized Fe-beta zeolite molecular sieve is neat in structure, high in crystallinity and good in application prospect.
Owner:BEIJING UNIV OF CHEM TECH

Copper-containing molecular sieve Cu-CHA, catalyst and use thereof

The present application discloses a copper-containing molecular sieve Cu-CHA, a catalyst thereof and use thereof in the treatment of diesel vehicle exhaust gas, and belongs to the field of catalytic materials. The copper-containing molecular sieve Cu-CHA consists of zeolite having a CHA framework structure and containing silicon and aluminum elements as well as 1.65-3.05wt% of Cu; the Cu-CHA molecular sieve also comprises 0.5-1.5wt% of boron, and the Cu-CHA molecular sieve has an acid content of 0.25-0.98mmol/g. The Cu-CHA molecular sieve of the present application has an acid density as highas 0.25-0.98mol/g and a Cu content as low as 1.65-3.05wt%. As a catalyst for the selective catalytic reduction of ammonia, the Cu-CHA molecular sieve has excellent storage capacity for NH3 and good low-temperature activity, and the absence of CuOx species in the high-temperature section prevents the reduction of high-temperature activity due to non-selective oxidation of NH3. The Cu-CHA molecularsieve catalyst shows excellent catalytic activity in a wide temperature window, taking into account both low temperature and high temperature activities, and still shows good catalytic activity afterbeing subjected to hydrothermal aging treatment; and after being used in the treatment of diesel vehicle exhaust, the Cu-CHA molecular sieve catalyst has significant performance advantages.
Owner:SHANDONG SINOCERA FUNCTIONAL MATERIAL CO LTD

Hydrocracking catalyst carrier and preparation method thereof

The invention discloses a hydrocracking catalyst carrier and a preparation method of the hydrocracking catalyst carrier. The hydrocracking catalyst carrier is prepared by using modified Y zeolite, aluminum oxide and amorphous silicon-aluminum. The modified Y zeolite has the following physiochemical properties: the mole ratio of SiO2 to Al2O3 is 30-120; the lattice constant is 2.420-2.435nm; the relative crystallinity is more than or equal to 90%; the specific surface area is 750-850m<2> / g; the secondary pore with 1.7-10nm accounts for more than 50% of the total pore volume; the infrared acidity is 0.10-0.50mmol / g; the ion exchange capacity is less than or equal to 0.10%; and the water adsorption quantity is less than 5.0% in percentage by weight at 25 DEG C and P / P0 of 1.0. The preparation method of the catalyst carrier provided by the invention comprises the following steps: mechanically mixing the modified Y zeolite, aluminum oxide, amorphous silicon-aluminum and adhesive, grinding, extrusion-moulding, drying and calcining to obtain the catalyst carrier. The catalyst carrier prepared by using the modified (deeply dealuminated) Y zeolite as the acidic cracking component is suitable to be used as the hydrocracking catalyst for middle distillates oil.
Owner:CHINA NAT OFFSHORE OIL CORP +2

Modified Y zeolite and preparation method thereof

A modified Y zeolite and a preparation method thereof are disclosed; the modified Y zeolite comprises a IVB metal oxide and phosphor, the ratio of distorted four-coordinated framework aluminum to four-coordinated framework aluminum in the lattice structure of the modified Y zeolite is(0.2-0.8):1, and the ratio of zeolite surface IVB metal content to zeolite internal IVB metal content is not higher than 0.5. The preparation method comprises the following steps: acid treatment of zeolite materials, dehydration, immersion of a metal in an organic solvent, treatment of the zeolite immersed with the metal in the organic solvent, treatment of the modified Y zeolite by a phosphorus containing compound and calcination. The modified Y zeolite has high cracking activity, higher gasoline yield and lower coke yield for heavy oil cracking.
Owner:CHINA PETROLEUM & CHEM CORP +1

Double-micropore zeolites and method of making thereof

A kind of double microporous zeolite and preparation method thereof belong to the technical field of fine chemical industry, it is characterized in that adopting two-step crystallization method, the first step first synthesizes Beta, then with the synthetic Beta reaction mixture as the raw material of the second step synthesizing Y zeolite, The composite zeolite product with BEA / FAU structure is obtained by supplementing the aluminum source, adjusting the basicity of the system, adding the directing agent for synthesizing Y zeolite for reaction crystallization, filtering, washing, drying, and calcining. The method successfully solves the problems of pouring part of the clear liquid and difficult control of the amount of aluminum source and base added in the synthesis because the clear liquid contains components such as silicon, aluminum and alkali, and the product repeatability is difficult to control. The synthesized Beta / Y composite zeolite products can be used as various catalysts, catalyst assistants and adsorbents. After ion exchange, they have strong acidity and good thermal and hydrothermal stability. They can be used as various catalysts, catalyst assistants It is bound to have potential application value in catalytic cracking and hydrocracking of petrochemical industry.
Owner:TAIYUAN UNIV OF TECH
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