The invention belongs to the technical field of
ceramic materials, and discloses high-entropy
ceramic as well as a preparation method and application thereof. The molecular formula of the high-entropy
ceramic is (Me1aMe2bMe3cMe4dMe5eMe6fMe7gMe8h)B2, 0.1< / =a< / =0.9, 0.1< / =b< / =0.9, 0.1< / =c< / =0.9, 0.1< / =d< / =0.9, 0.1< / =e< / =0.9, 0.1< / =f< / = 0.9, 0< / =g< / =0.9, 0< / =h< / =0.9, and a+b+c+d+e+f+g+h=1; Me1-Me8 are any 6-8 of Hf, Mo, Zr, Nb, Ti, V, W, Cr and Ta; the high-entropy ceramic is prepared by the following steps of adding any 6-8 of
metal oxides HfO2, MoO3, ZrO2, Nb2O5, TiO2, V2O5, WO3, Cr2O3 and Ta2O5, B4C and carbon
powder into a
solvent, carrying out ball milling and mixing to obtain mixed
powder, carrying out
compression molding to obtain a blank, heating the blank to 1400-1600 DEG C, heating the obtained high-entropy
powder to 1000-1400 DEG C by adopting
spark plasma sintering, filling a protective
atmosphere, then heating to 1900-2100 DEG C, pressurizing to 10-100 MPa, and calcining to obtain the high-entropy ceramic. The
relative density of the high-entropy ceramic is greater than 98%, the
hardness is 35-40 GPa, and the
thermal conductivity is 0.1-1 W / (mK).