Provided are a piezoelectric
ceramic and a piezoelectric device having a larger piezoelectric strain constant and capable of being fired at a lower temperature. A main component of PbA[(Mg1 / 3Nb2 / 3)a(Zn1 / 3Nb2 / 3)bTicZrd]O3 (a+b+c+d=1, 0.99≦A≦1.01, 0.15≦a+b≦0.5, 0.05≦b≦0.25, 0.2≦c≦0.5, 0.15≦d≦0.6) and 0.01
mass % to 0.8
mass % inclusive of at least one kind selected from the group consisting of Fe, Co, Ni and Cu in the form of
oxide per 1 mol of the main component as a first sub-component are comprised. Thereby, a larger piezoelectric strain constant can be obtained, and a firing temperature can be reduced. In the main component, a part of Pb may be replaced with at least one kind selected from the group consisting of Ca, Sr and Ba. Further, as a second sub-component, 0.05
mass % to 1.0 mass % inclusive of at least one kind selected from the group consisting of Sb, Nb and Ta in the form of
oxide per 1 mol of the main component may be comprised.