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72 results about "Plastic crystals" patented technology

Electrolyte for an electrochemical device, method for manufacturing same, and electrochemical device including same

The present invention relates to a solid electrolyte for an electrochemical device comprising a plastic crystal matrix electrolyte doped with ionic salt, and a complex of a polymer having a cross-linking structure including a chemically bonded linear polymer having a weight average molecular weight of 100 to 5,000 and one functional group, and to a method for manufacturing same. Since the electrolyte is obtained using the plastic crystal, the electrolyte has good ion conductivity which is a feature of a liquid electrolyte. Since the electrolyte includes the polymer having the cross-linking structure, the electrolyte has good mechanical strength which is a feature of a solid electrolyte. In addition, a solvent is not necessarily required while manufacturing the electrolyte, and therefore a drying process can be omitted to simplify the manufacturing process. The electrolyte has high ion conductivity and the mechanical strength of a solid electrolyte, and therefore the electrolyte can be used in a cable-type battery, the form of which is easily modified.
Owner:LG ENERGY SOLUTION LTD

Plastic crystal polymer electrolyte material prepared by in-situ polymerization and preparation method therefor

The invention relates to a plastic crystal polymer electrolyte material prepared by in-situ polymerization and a preparation method therefor, and belongs to the technical field of an electrolyte material. The plastic crystal polymer electrolyte material prepared by the in-situ polymerization comprises a monomer, an initiator, a cross-linking agent, a lithium salt, and plastic crystals; a mixed solution of the monomer, the initiator, the cross-linking agent, the lithium salt and the plastic crystals is heated to be subjected to the in-situ polymerization to obtain the plastic crystal polymer electrolyte material; the preparation method for the plastic crystal polymer electrolyte material prepared by the in-situ polymerization comprises the steps of mixing and dissolving the monomer, the initiator, the cross-linking agent, the lithium salt and the plastic crystals; and pouring the solution into a polytetrafluoroethylene die, and heating and performing the in-situ polymerization to obtain the plastic crystal polymer electrolyte material. By adoption of a one-step method for synthesis, the preparation process is simple and industrial production can be realized favorably; and in addition, the plastic crystal polymer electrolyte material is high in conductivity at room temperature, high in thermal stability and interface stability, high in mechanical property, excellent in electrochemical performance, and the like.
Owner:CHINA ELECTRONIC TECH GRP CORP NO 18 RES INST

Porous membrane reinforced polymer-plastic solid electrolyte membrane, preparation method thereof and application thereof

The invention discloses a porous membrane reinforced polymer-plastic solid electrolyte membrane, a preparation method thereof and application thereof. The polymer-plastic solid electrolyte membrane includes a support layer including a porous membrane and a polymer-plastic solid electrolyte layer covering at least one side of the surface of the porous membrane, wherein the porous membrane plays therole of a support frame and has a continuous three-dimensional network structure, the mechanical properties of the solid electrolyte membrane can be improved, and at the same time, the preparation ofa thinner solid electrolyte membrane is facilitated by the porous membrane support frame. The polymer-plastic solid electrolyte layer contains a polymer, lithium salt and a plastic crystal compound,and a porous membrane reinforced flexible polymer-plastic solid electrolyte membrane with high voltage resistance and high low-temperature conductivity can be obtained by optimizing the proportions ofthe polymer, the lithium salt and the plastic crystal. The polymer-plastic solid electrolyte membrane can be applied to an all-solid lithium-ion battery, the preparation process is simple, and the polymer-plastic solid electrolyte membrane is suitable for industrial production.
Owner:SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI

Composite solid electrolyte material, preparation method thereof, and all-solid-state battery

The invention discloses a composite solid electrolyte material, a preparation method thereof, and an all-solid-state battery. The all-solid-state battery includes a positive electrode layer, a negative electrode layer, and the composite solid electrolyte material positioned between the positive electrode layer and the negative electrode layer. The composite solid electrolyte material includes polyoxyethylene, an inorganic powder having a high ionic conductivity, a plastic crystal compound and a lithium salt. The preparation method comprises the following steps: weighing the polyoxyethylene andthe lithium salt in proportion, adding the weighed substances to an organic solution, and performing stirring to obtain a solution A; weighing the inorganic powder and the plastic crystal compound inproportion, adding the weighed substances to the solution A, and performing stirring to obtain a uniformly mixed suspension B; and pouring the suspension B into a mold, and drying the suspension B inthe mold to obtain the organic/inorganic composite solid electrolyte material. The composite solid electrolyte material has an obviously improved room-temperature ionic conductivity and an enhanced electrochemical stability, and has a stable interface contact with a positive electrode and a negative electrode, and the capacity attenuation problem of the all-solid-state battery formed by assembling the composite solid electrolyte material is significantly improved.
Owner:ZHUHAI SMOOTHWAY ELECTRONICS MATERIALS +1

Self-assembled polyhedral multimeric chemical structures

Self-assembled, closed and hollow chemical multimer structures having a dodecahedral morphology, composed of chemical monomers having a structurally symmetric core which possess a 5-fold rotational symmetry, are provided. Also provided are methods of creating such chemical monomers, methods of creating such chemical multimer structures and compositions comprising these chemical multimer structures. Also provided are uses of these chemical multimer structures in applications such as drug delivery, imaging, immunization, formation of plastic crystals and nanoparticle matrices and other medical and material science applications.
Owner:TECHNION RES & DEV FOUND LTD

Solid-state refrigeration method based on static-pressure driving of plastic crystal materials

The invention provides a novel efficient solid-state refrigeration method driven by pressure of plastic crystal materials. Plastic crystals are orientation ordered-unordered transformed organic molecular crystals or inorganical crystals with molecules or structural units. The plastic crystals are transformed in a solid state by a two-step melting process along with entropy change and enthalpy change comparable to the melting process. The phase change can be induced by lower pressure to generate huge pressure clamping effect. Taking the plastic crystal materials-neopentyl glycol as an example,the thermal insulation temperature change of 9 K is generated under the pressure of 20 MPa to achieve higher advantage compared with other pressure clamping effect material systems.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

On-line plastic crystallinity measuring method based on pressure sensor and temperature sensor

ActiveCN103358511ALow priceSolving problems that can only be measured offlinePlastic crystalSpecific volume
The invention discloses an on-line plastic crystallinity measuring method based on a pressure sensor and a temperature sensor. The on-line measuring method comprises the following steps of: (1) constructing a relation curve of the pressure, specific volume and temperature of plastic, namely a PVT curve; (2) measuring pressure and temperature values of the plastic in a mould in real time by utilizing the pressure sensor and the temperature sensor; (3) calculating the current specific volume v of the plastic according to the PVT curve in combination with the pressure and temperature values measured in real time; (4) calculating the specific volume va when the plastic crystallinity is 0 and the specific volume vc when the plastic crystallinity is 1 according to the PVT curve; (5) calculating the current crystallinity Xc of the plastic. Through the on-line measurement of the crystallinity by using the temperature sensor and the pressure sensor, the invention provides a new universal method for on-line measurement on the plastic crystallinity which is low in price, easy to operate, high in precision and wide in application range, and can be used for solving the difficult problem that the plastic crystal morphology generally only can be measured off-line.
Owner:ZHEJIANG UNIV

Gel-state electrode and preparation method thereof

The invention discloses a gel-state electrode and a preparation method thereof. The electrode comprises an electrode active material, a conductive agent, SN, a lithium salt, a polymer and an additive. The preparation method comprises the following steps of dissolving the lithium salt and the additive in SN at 60-80 DEG C, adding the polymer, and fully stirring and dissolving to form a gel-state substance, and then, mixing the prepared gel-state substance, an electrode active material and a conductive agent, stirring or uniformly grinding, and coating one side of a solid electrolyte with the mixture to serve as the gel-state electrode of the solid-state battery. According to the type of the added polymer, whether cross-linking treatment is carried out or not is determined. The lithium salt can be completely dissolved in SN to form a plastic crystal electrolyte, and the selected polymer can also be dissolved in the plastic crystal electrolyte. According to the gel-state electrode provided by the invention, the contact performance between the electrode and the solid electrolyte can be improved, the ion transmission in the electrode can be improved, and the negative effect on the battery performance caused by the volume change generated in the charging and discharging process of the electrode active material can also be inhibited.
Owner:SHANGHAI INST OF SPACE POWER SOURCES

Solid-state battery based on plastic crystal modified positive electrode and preparation method of solid-state battery

The invention belongs to the technical field of solid-state batteries, and particularly relates to a solid-state battery based on a plastic crystal modified positive electrode and a preparation method thereof.The preparation method of the solid-state battery based on the plastic crystal modified positive electrode comprises the following steps that firstly, plastic crystal, lithium salt, a polymer and inorganic filler are heated and mixed, and the plastic crystal melted into a liquid state serves as a solvent; 2, mixing positive electrode material powder, a conductive agent, the plastic crystal-based composite positive electrode adhesive obtained in the step 1 and an organic solvent, and coating a current collector with the mixture; and 3, preparing a plastic crystal-based positive electrode surface treatment liquid, coating or spraying the plastic crystal-based positive electrode surface treatment liquid on the surface of the positive electrode layer obtained in the step 2, and carrying out in-situ polymerization by adopting heating or irradiation. According to the solid-state battery based on the plastic crystal modified positive electrode and the preparation method of the solid-state battery, the interface compatibility and the compatibility with a high-specific-energy electrode material are improved, and the problem that the battery performance cannot be brought into full play due to poor battery interface contact and low material conductivity is solved.
Owner:CHINA ELECTRONIC TECH GRP CORP NO 18 RES INST
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