The invention discloses a method for raising quality of
biomass pyrolysis oil by reactive extraction. By selecting reactive extracting agent, two unit operations of reaction and extraction are carried out simultaneously, and the method comprises: a first step, according to a proportion of the
biomass pyrolysis oil to low-carbon
alcohol to a catalyst by
mass being 100:40-100:2-10, adding the
biomass pyrolysis oil, the low-carbon
alcohol and the catalyst into a reaction kettle, dripping
hydrogen peroxide water solution into the reaction kettle at a temperature of 80 DEG C according to a proportion of the biomass
pyrolysis oil to oxidant by
mass being 100:20-60, and then heating the mixture for reacting for 5 to 8 hours at a temperature of between 80 and 100 DEG C; and a second step, after total
reflux reaction is ended, cooling, condensing and layering the mixture, and obtaining clear and transparent water solution on the lower layer; and separating a
black oil phase on the upper layer, distilling and reclaiming the unreacted low-carbon
alcohol in the
oil phase at a temperature of 80 DEG C under 10KPa, obtaining the black sticky liquid which is not distilled, namely a product, and diluting and dissolving the product by
methanol according to a proportion of the product to the
methanol by
mass being 4:1 to obtain the modified biological oil, wherein the pH is 4 to 6, the density is 1.0 to 1.1 g / cm<3>, the
water content is 0.5 to 2.0 percent, the thermal value is 25.0 to 30.0 kilojoules per
gram, and the
viscosity is 35 to 40 mm<2> / s at a temperature of 30 DEG C.