The invention provides a high-temperature-resistant abrasion-resistant non-stick pan coating, a preparation method and a non-stick pan with the same. Nickel plating is conducted on the surface of a metal pan base body through the electrochemical method. Under the action of a magnetic field, a formed surface nickel layer is uniform and flat, and accordingly it is guaranteed that the subsequent coating is flat and uniform. Secondly, an annular structure in a poly(aryl ether nitrile ketone) molecular main chain makes the coating have good high temperature resistance, a molecular structure contains strong-polarity groups, namely nitrile groups, and the nitrile groups generate strong action force on the surface of a metal base material. Thirdly, under the action of irradiation, a silane coupling agent KH792 and poly(aryl ether nitrile ketone) have grafting reaction, and heat resistance is further improved, so that organic solvent molecules cannot permeate into the metal base material, stability is improved, the organic solvent molecules and the surface of the metal base material are connected in a strong chemical bond mode, and adhesion of the coating is greatly improved. Accordingly, the high-temperature-resistant anti-wear non-stick pan coating prepared through the method does not contain fluorine and is resistant to high temperature, abrasion and scratching.