The invention discloses a heat conducting and storing graphene sizing phase-change material and a preparation method thereof, and relates to the technical field of heat conducting materials. The heatconducting and storing graphene sizing phase-change material comprises the following steps that graphene powder is added into a reactor with deionized water to prepare a graphene solution, the reactoris placed into an ice water bath, H2SO4 with the mass concentration being 98%, a saline solution and potassium permanganate are added into the reactor, after the certain operation, a proper amount ofhydrogen peroxide is dropwise added, and a graphene oxide solution is obtained; dimethyl vinyl silicone rubber, heat conducting filler, crosslinking agent, coupling agent, platinum catalyst and dispersing agent are added into a vacuum kneading machine, the graphene oxide solution is poured into the vacuum kneading machine to be kneaded, thermal treatment is performed in the specific environment,and then the graphene sizing phase-change material is obtained; the heat conducting and storing graphene sizing phase-change material has the natural physical state temperature regulating characteristics and flexibility of various phase-change materials and can be applied in the fields of thermal interface material and electronic component cooling and heat dissipation, medical apparatuses and instruments, protective clothing and the like.