Disclosed are: a non-aqueous electrolytic solution which comprises a
lithium salt and a non-aqueous
organic solvent, and which is characterized in that the non-aqueous
organic solvent contains at least one component selected from the group consisting of a saturated cyclic
carbonate, a linear
carbonate and an aliphatic
carboxylic acid ester in the total amount of more than 90 vol%, and a
fluorine-substituted aromatic ester compound represented by general formula (1) is additionally contained in an amount of 0.01 to 10 wt% relative to the total weight of the non-aqueous electrolytic solution; and a non-
aqueous electrolyte battery comprising the non-aqueous electrolytic solution. Xn-Ph-OCOR (1) [In general formula (1), Ph represents a
phenylene group; R represents a
hydrocarbon group which has 1 to 12 carbon atoms and may be substituted by a
fluorine atom; X represents a
fluorine atom, or a fluorine-substituted
alkyl group having 1 to 12 carbon atoms; and n represents an integer of 1 to 4.] Also disclosed are: a non-aqueous electrolytic solution which comprises an
electrolyte and a non-aqueous
solvent, and which is characterized by additionally containing a compound represented by general formula (3); and a non-
aqueous electrolyte battery comprising the non-aqueous electrolytic solution. [In general formula (3), R1 represents a
hydrocarbon group which has 1 to 12 carbon atoms and may be substituted by a fluorine atom; R2 to R6 independently represent a
hydrogen atom, a fluorine atom, or an
alkyl group which has 1 to 12 carbon atoms and may be substituted by a fluorine atom, wherein at least one of R2 to R6 represents an
alkyl group which has 2 or more carbon atoms and may be substituted by a fluorine atom; and n represents an integer of 0 or 1, wherein at least one of R2 to R6 represents an alkyl group which has 5 or more carbon atoms and may be substituted by a fluorine atom when n is 1.]