The invention discloses a porous temperature-sensitive gel coated slow-release
fertilizer prepared by a freeze
polymerization method and a preparation method thereof. The preparation method comprisesthe following steps:
sodium alginate is subjected to oxidization treatment by using
sodium periodate as an oxidant, so as to obtain oxidized
sodium alginate, and
urea is coated by using the oxidized
sodium alginate as a base material, so as to obtain
sodium alginate-
coated urea microspheres; and a
polymer poly(N-isopropylacrylamide) gel is synthesized by the freeze
polymerization method, so as toobtain a porous
structural temperature-sensitive gel, and the slow-release
fertilizer is obtained through
fluidized bed spray granulation by using the porous
structural temperature-sensitive gel as acoated material. According to the porous temperature-sensitive gel coated slow-release
fertilizer prepared by the freeze
polymerization method and the preparation method thereof, in the synthesis of the poly(N-isopropylacrylamide) gel, the reaction solution is transferred into freeze polymerization after pre-polymerization, so that mutually continuous ice
crystal regions can be formed, and pores are left after the poly(N-isopropylacrylamide) gel is thawed at
room temperature, therefore, a mutually penetrating open-celled pore structure can be formed, specific surface area of the prepared gel is greatly increased,
diffusion resistance of water molecules is small, swelling / deswelling rate of the gel can be improved, and
temperature response rate of the gel can be significantly improved.