The invention discloses a modeling method of a
liquid state or semi-
liquid state metal battery. The modeling method comprises the following steps: according to a battery
impedance spectrum, carrying out fitting, constructing a battery
impedance spectrum fitting circuit, and constructing the
equivalent circuit model of the battery according to the battery
impedance spectrum fitting circuit; adopting symmetrical impulse to carry out a
hybrid impulse
power performance test on the battery, and obtaining
test data used for distinguishing the open-circuit
voltage, the resistance and the
capacitance parameters of the battery; according to the
test data, fitting a function relationship between SOC (
State of Charge) and the electrodynamic force, the Ohmic
internal resistance, the polarization resistance, the polarization
capacitance, the
diffusion equivalent resistance and the
diffusion equivalent capacitance of the battery, and distinguishing the parameters of the
equivalent circuit model; adopting an
ampere-hour method to calculate the SOC of the battery; correcting the SOC to obtain a corrected SOC; according to the corrected SOC, correcting the parameters of the
equivalent circuit model; and finishing modeling. The modeling method can accurately simulate the external characteristics of the
liquid state or semi-liquid state
metal battery, and lays a foundation for the charging and discharging management and the subsequent application of the type of novel
power grid type
energy storage battery including the liquid state or semi-liquid state
metal battery.