The invention relates to a dust removal process of a pulverized coal making and spraying system, and after coals to be sprayed are ground to powder by a coal mill, and the gas and powder are separated by a bag powder collecting device, and the pulverized coal is gathered into a pulverized coal collecting bin, and then unloaded to a spraying pot, and the spraying pot uses a pneumatic method to transport the pulverized coal into metallurgy furnaces. The dust removal process removes a bag dust remover originally arranged at the top of the pulverized coal collecting bin, and uses the bag powder collecting device on the pulverized coal collecting bin to replace functions of the bag dust remover, and the bag powder collecting device can be directly used for carrying out the gas-powder separation of mixtures in the pulverized coal collecting bin to discharge the purified waste gas into air through a pipe on the pulverized coal collecting bin and connected with an inlet of the bag powder collecting device. The dust removal device arranges a discharging pipe on the pulverized coal collecting bin, and connects the discharging pipe to the inlet of the bag powder collecting device and removes the bag dust remover arranged at the original pulverized coal collecting bin, thus simplifying the process equipment, saving the construction space and reducing the investment cost.