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47results about How to "Improve up-conversion luminous efficiency" patented technology

Infrared laser detection card and method for making same

The invention discloses an infrared laser detection card and its preparation method. The infrared laser detection card comprises the bottom substrate and the nanocrystalline powder coated in the bottom substrate and mixed with the rare earth ion, and using PVC plastic molding; the chemical composition of the said nanocrystalline powder is Si2O.Al2O3.PbF2.CdF2:Re3+, in which Re3+ is one or more combinations of the rare earth ion Yb, Er, Pr, Ho, Eu or Tm. The nanocrystal is that the rare-earth ions exists in the fluoride nanocrystal of glass ceramic, the nanocrystal size for the 10-90nm. The invention uses the rare earth nanocrystalline powder for the infrared laser detection card of luminous preparation, and when infrared laser irradiating, the rare earth ion-doped nanocrystalline powder takes luminous effect to convert the unseen infrared laser into visible light, and it can detect the infrared laser location and intensity with the 0.8-2.2 micron wavelength.
Owner:NANKAI UNIV

Highly-doped broadband excited rare earth up-conversion fluorescent nanomaterial and preparation method thereof

The invention discloses a highly-doped broadband excited rare earth up-conversion fluorescent nanomaterial and a preparation method thereof, belonging to the technical field of luminescent materials and aiming to solve the problems of small doping amount, narrow absorption interface and low luminescence efficiency of the luminescence center of an up-conversion fluorescent material in the prior art. In the highly-doped broadband excited rare earth up-conversion fluorescent nanomaterial, NaYF4 is taken a substrate, rare earth sensitized ions are doped, and rare earth luminescence center ions are highly doped, so that the nanomaterial is in nano-crystalline micromorphology, and nanoparticles have homogeneous core-shell structures. Organic antenna molecules are compound on the surfaces of the nanoparticles, the broadband adsorption range of the organic antenna molecules is 750-1,100 nanometers, and the coverage range is 980 nanometers. The up-conversion luminescence efficiency of the fluorescent nanomaterial is 1.2 percent, the minimum particle diameter of the nanoparticles can be up to 25 nanometers, and the nanoparticles are uniformly distributed.
Owner:CHANGCHUN INST OF OPTICS FINE MECHANICS & PHYSICS CHINESE ACAD OF SCI

Triplet state and triplet state annihilation up-conversion chemiluminescent system based on photonic crystal and preparation method thereof

The invention provides a triplet state and triplet state annihilation up-conversion chemiluminescent system based on a photonic crystal and a preparation method thereof. The triplet state and triplet state annihilation up-conversion chemiluminescent system comprises up-conversion solution and a photonic crystal film, wherein the up-conversion solution and the photonic crystal film interact according to the following mode that the up-conversion solution enters the photonic crystal film, so as to form a single layer mixed system, and enhances the up-conversion fluorescence of the up-conversion chemiluminescent system through the Bragg specular reflection effect of the photonic crystal film. The system has the advantages that the up-conversion solution enters the photonic crystal film to form a single layer mixed system, the low light up-conversion efficiency is improved through the Bragg specular reflection effect of the photonic crystal film, the problem of low luminous efficiency of a triplet state and triplet state annihilation up-conversion system in the prior art is solved, the up-conversion efficiency can reach 15 percent, and the system has obvious technical effect.
Owner:SUZHOU UNIV OF SCI & TECH

Ytterbium and holmium codoped lithium niobate crystals and preparation method thereof

The invention discloses ytterbium and holmium codoped lithium niobate crystals and a preparation method thereof, and relates to doped lithium niobate crystals and a preparation method thereof, which solve the technical problems that the conventional lithium niobate crystals cannot be used as a laser crystal material. The ytterbium and holmium codoped lithium niobate crystals are prepared from niobium pentaoxide, lithium carbonate, ytterbium oxide and holmium oxide. The method comprises the following steps of: mixing the niobium pentaoxide, the lithium carbonate, the ytterbium oxide and the holmium oxide and baking to obtain polycrystal powder; growing crystals at equal diameter from the polycrystal powder in a single crystal growth furnace through seeding, necking, shouldering and folding by a crystal pulling method; and annealing to obtain the ytterbium and holmium codoped lithium niobate crystals. The ytterbium and holmium codoped lithium niobate crystals can emit red light and green light when activated by laser of 980nm and has a broad application prospect in the fields of optical data storage, submarine communication, optical display, color display, photoelectrons, medical diagnosis and the like.
Owner:HARBIN INST OF TECH

Solid-state upconversion light emitting material based on triplet state-triplet state annihilation and preparation method thereof

The invention discloses a solid-state upconversion light emitting material based on triplet state-triplet state annihilation, and relates to the technical field of photon upconversion. The solid-stateupconversion light emitting material comprises a photosensitive agent and an annihilation agent with a 9,10-diphenyl vinyl anthracene structure, wherein the annihilation agent has AIE (aggregation-induction emission) effect. The solid-state upconversion light emitting material is formed by physically doping the annihilation agent into the photosensitive agent, and has the advantages that becausethe annihilation agent has regular structure in the solid state, the fluorescence quantum yield is high in the solid state, the energy transfer in the annihilation is favorably performed, the self-quenching of conversion light emitting is avoided, and the problem of self-quenching of the annihilation agent in the solid due to aggregation is certainly solved; the quick energy transfer among the triplet states of the annihilation agent in the solid is favorable for realizing the triplet state-triplet state annihilation of the molecules of the annihilation agent, and is further favorable for improving the upconversion light emitting efficiency.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Transparent rare earth ion-doped hexagonal sodium yttrium fluoride oxyfluoride glass-ceramics and preparation method thereof

The invention provides a transparent rare earth ion-doped hexagonal sodium yttrium fluoride oxyfluoride glass-ceramics and a preparation method thereof. The glass is prepared from the following compositions: 50-70mol% of SiO2, 3-12mol% of Al2O3, 15-20mol% of Na2O, 5-12mol% of NaF and 5-12mol% of YF3, and a sum of the compositions is 100 percent; and the glass also is prepared from ErF3 which accounts for 0.1-1mol% of the sum of the compositions, wherein the molar content ratio of SiO2 to Al2O3 is larger than 6.5. Compared with silicate glass, the hexagonal sodium yttrium fluoride oxyfluoride glass-ceramics has lower phonon energy (as low as 230cm<-1>), lowers the multi-phonon nonradiative relaxation rate of rare earth ions, and thus enabling the up-conversion luminescence efficiency of the rare earth ions in the glass-ceramics to be obviously improved.
Owner:WUHAN UNIV OF TECH

Calcium titanate up-conversion luminescence nanoparticle and preparation method thereof

The invention discloses a calcium titanate up-conversion luminescence nanoparticle prepared by using the combination of a sol-gel method and a coprecipitation method. By adding rare earth elements ytterbium and erbium, an up-conversion luminescence effect can be achieved, and the method is simple, and strong in maneuverability. Obtained materials are calcium titanate luminescence nanoparticles with an average particle size of 65 nm and with uniform size distribution, good monodispersity and good biocompatibility. The nanoparticle has a wide application prospect in the biomedicine, for example, the nanoparticle can be used as biological probes, tissue or cell imaging and drug tracers and the like; and the nanoparticle also has important applications in the field of light-emitting devices.
Owner:ZHEJIANG UNIV

Barium fluoride up-conversion transparent ceramic and preparation method thereof

The invention discloses a barium fluoride up-conversion transparent ceramic and a preparation method thereof, and belongs to the technical field of optically functional materials. The existing alumina up-conversion transparent ceramic has low up-conversion luminous efficiency and is prepared difficultly. The barium fluoride up-conversion transparent ceramic utilizes barium fluoride transparent ceramic as a matrix and comprises: by mole, 60 to 89% of barium fluoride, 10 to 25% of ytterbium fluoride, and 1 to 15% of one or more of fluorides of erbium, holmium, neodymium, thulium and promethium. The preparation method comprises the following steps of blending raw material nanometer powder according to the mole percentage, wherein barium fluoride powder has particle sizes of 20 to 80nm and rare earth fluoride powder has particle sizes of 10 to 90nm, pressing the blended raw material nanometer powder into a biscuit, pre-sintering the biscuit at a temperature of 500 to 800 DEG C for 0.5 to 5 hours, carrying out vacuum sintering of the pre-sintered biscuit under the conditions of pressure of 50 to 500MPa, a vacuum degree of 10<-2> to 10<-3>Pa, a heating rate of 1 to 20 DEG C / min, a sintering temperature of 600 to 1200 DEG C and sintering time of 0.5 to 5 hours, and cooling to a room temperature at a rate of 1 to 20 DEG C / min to obtain the barium fluoride up-conversion transparent ceramic.
Owner:CHANGCHUN UNIV OF SCI & TECH

Green titanium niobate up-conversion luminescent material, and preparation method and application thereof

The invention discloses a green titanium niobate up-conversion luminescent material, and a preparation method and application thereof. The green titanium niobate up-conversion luminescent material has a general chemical formula of Ca<5-5x>Er<5x>Yb<5y>Nb<4>Ti<3>O<21>, wherein x is the doping mol ratio of Er<3+> ions, y is the doping mol ratio of Yb<3+> ions, and the sum of x and y is no less than 0.001 and no more than 0.20. The green titanium niobate up-conversion luminescent material prepared in the invention has uniform particles, and under the excitation of light with a wavelength of 976 nm, the material emits green light with a wavelength of about 550 nm and has high luminescent intensity and high up-conversion luminescent efficiency. The green titanium niobate up-conversion luminescent material has good stability, no toxicity and no pollution and can be widely applied to fields like infrared radiation detection, optical fiber communication technology, fiber amplifiers, three-dimensional stereo display and biomolecular fluorescent marking. The preparation method is simple, safe, low in production cost, not restricted by raw material supply and easy for operation and industrial production.
Owner:NANJING TONGLI CRYSTAL MATERIALS RES INST CO LTD

Laminated glass material

The invention discloses a laminated glass material capable of realizing simultaneous emission of blue, green and red colors without reducing the intensity of blue-green light up-converted by rare earth ions. The glass material is composed of two or more glass materials doped with two different ions, one of which is doped with Yb 3+ / Er 3+ , another glass material doped with Yb 3+ / Tm 3+ . Compared with adding multiple kinds of rare earth luminescent ions to the same matrix material, the invention avoids fluorescence quenching between rare earth ions and improves up-conversion luminous efficiency. Especially in the three-dimensional display, the graphics formed by the light emitted at different thicknesses of the glass have a more three-dimensional display effect, and the present invention has a remarkable application prospect.
Owner:SOUTH CHINA UNIV OF TECH

Superbright monochromatic upconversion nanoprobe for excitation/emission in biological window as well as preparation method and application of superbright monochromatic upconversion nanoprobe

ActiveCN113817469AOvercoming limited penetration depthHigh sensitivity signal to noise ratioLuminescent compositionsImage analysisRed light
The invention discloses a superbright monochromatic upconversion nanoprobe for excitation / emission in a biological window as well as a preparation method and application of the superbright monochromatic upconversion nanoprobe, and belongs to the technical field of preparation of rare earth luminescent nanomaterials and biological living body imaging. The nanoprobe provided by the invention is a nano-particle which is formed by co-doping Nd<3+>, Yb<3+>, Er<3+> and Mn<2+> and has a multi-layer core-shell structure, and the chemical composition of the nanoprobe is alpha-NaYF4:Yb / Er / Mn coated CaF2:Yb coated NaNdF4:Yb. Through component optimization and structural design, the prepared up-conversion probe material obtains high-quantum-efficiency single-band red light emission under the excitation of 808nm near-infrared light. The up-conversion fluorescent probe material is unique in structure and stable in performance, has the advantages of high tissue penetration depth, high sensitivity, high resolution, high signal-to-noise ratio and the like when being applied to mouse living body imaging analysis, and has a good application prospect in the aspect of biological imaging.
Owner:NANJING FORESTRY UNIV

Chameleon-like rare earth inorganic material, preparation method thereof and application of chameleon-like rare earth inorganic material in fluorescence anti-counterfeiting

The invention discloses a rare earth inorganic material as well as a preparation method and application thereof. The rare earth inorganic material is represented by a chemical formula XAF4: y% B or XAF4: y% B@XMF4, wherein X is selected from at least one of Li, Na and K, A represents sensitizing ions and is selected from Yb and / or Nd, B represents emission ions and is selected from at least one ofEr, Ho and Tm, M is selected from at least one of rare earth elements Gd, Y and Tb, and y represents the molar doping amount of B in the rare earth inorganic material and ranges from 0.01% to 40%. The material shows sensitive excitation light power dependent up-conversion luminescence and excitation light wavelength dependent down-transfer single-band emission characteristics, and the applicationof the material in multi-dimensional fluorescence anti-counterfeiting can be realized by utilizing the characteristics.
Owner:FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI

Magnesium, erbium and ytterbium doped sodium niobate, preparation method and application thereof

The invention relates to a magnesium, erbium and ytterbium doped sodium niobate, a preparation method and an application thereof. The preparation method comprises the following steps: S1) dissolving erbium source, ytterbium source, niobium source and sodium source in a solvent, thereby acquiring a mixed solution, wherein the solvent is a mixed solvent of water and ethylene glycol; S2) triggering the mixed solution to react for 24-48h at 260-270 DEG C, filtering and drying, thereby acquiring solid powder; S3) calcining the solid powder for 0.5-2h at 900-1050 DEG C, thereby acquiring the magnesium, erbium and ytterbium doped sodium niobate. The preparation method provided by the invention is a solvothermal method; the preparation process is simple; in the magnesium, erbium and ytterbium doped sodium niobate provided by the invention, under 980nm laser excitation, erbium ion (Er3+) is a rare earth luminescence center, ytterbium ion (Er3+) is a sensitizing ion and magnesium metal ion (Mg2+) is used for increasing the up-conversion luminescence efficiency.
Owner:GUANGDONG UNIV OF TECH

Thermo-responsive upconversion luminescent material and preparation method thereof

The invention relates to the technical field of luminescent materials, in particular to a thermo-responsive upconversion luminescent material and a preparation method thereof. The preparation method of the thermo-responsive upconversion luminescent material comprises the following steps: 1, calcium hydroxide, aluminum hydroxide, thulium nitrate pentahydrate and ytterbium nitrate pentahydrate are added with aqueous ethanol to obtain a mixed solution, a first solvent thermal reaction is conducted to obtain a first reaction product, and then the first reaction product is calcined primarily to obtain a C12A7 material; and 2, calcium hydroxide, aluminum hydroxide and ytterbium nitrate pentahydrate are added with aqueous ethanol to be ball-milled, then the C12A7 material subjected to ultrasonicdispersion is added, a second solvent thermal reaction is conducted to obtain a second reaction product, and the second reaction product is calcined secondarily to obtain the thermo-responsive upconversion material. The technical defect that the prior art lacks in a cladding technology to improve the rare earth ion doped C12A7 material can be effectively overcome.
Owner:GUANGDONG UNIV OF TECH

Preparation method of tio2-based nanocrystal up-conversion luminescent material with core-shell structure

The invention relates to the technical field of up-conversion luminescent materials, in particular to a method for preparing up-conversion luminescent materials. First, a TiO2:Er-Yb nanocrystalline up-conversion luminescent material embedded in an amorphous matrix is ​​prepared by a sol-gel method. , and then immerse the up-conversion luminescent material in a Mo(NO3)3 solution for chemical modification, and anneal at a temperature of 500-1000° C. to prepare a TiO2-based nanocrystal up-conversion luminescent material with a core-shell structure. On the one hand, the present invention uses the amorphous embedded in TiO2:Er-Yb nanocrystals to reduce the light scattering of TiO2:Er-Yb nanocrystals, and on the other hand, utilizes the shell formed by surface modification to reduce surface states to improve upconversion luminescence It not only has the advantages of simple operation, can greatly improve the luminous performance, obtain high luminous intensity and high brightness, but also has the advantages of high luminous efficiency, especially reduces the production cost and reduces the toxicity of organic solvents.
Owner:ZHEJIANG ORIENT CRYSTAL OPTICS

Preparation method and application of graphene-rare earth up-conversion composite nano microspheres

The present invention relates to a preparation method and an application of graphene-rare earth up-conversion composite nano microspheres, and belongs to the technical field of nano drug-loaded materials. The method comprises the following steps: firstly, preparing histidine functionalized graphene quantum dots and then preparing a graphene quantum dot-rare earth fluoride up-conversion compound; and conducting loading of medicines and then conducting compounding with photothermal agent gold nanoparticles to prepare the graphene-rare earth up-conversion composite nano microspheres. Effective regulation and control of sizes and shapes of rare earth UCNP are realized by utilizing strong coordination capability of histidine and rare earth ions; up-conversion luminous efficiency of the rare earth UCNP materials is improved by utilizing strong infrared light absorption capability of nano graphene and high-efficiency energy transfer between the rare earth UCNP; and the nano-gold is used for absorbing a visible light part in the up-conversion luminescence to generate heat, so that light-controlled release of the medicines is realized.
Owner:JIANGNAN UNIV

Method for reinforcing upconversion luminous efficiency of rare earth doped nano-crystal powder material

The invention provides a method for reinforcing the upconversion luminous efficiency of a rare earth doped nano-crystal powder material. The method comprises the following steps of: pressing rare earth ion doped nano-crystal powder into a thin slice by a tablet press; irradiating the surface of the thin slice by high power laser to ensure the position of the irradiated point to be molten until a micro hole is formed; stopping carrying out laser irradiation; and cooling. According to the method provided by the invention, a preparation method, preparation conditions and a doped matrix of the rare earth doped nano-crystal powder material are not changed; other metal ions do not need to be doped; and the obvious reinforcement of the upconversion luminescence can be obtained only by carrying out secondary processing on a formed product.
Owner:三亚哈尔滨工程大学南海创新发展基地

Ytterbium and up-conversion rare earth luminescent ion double-doped potassium sodium niobate thick film

The invention discloses an ytterbium and up-conversion rare earth luminescent ion double-doped potassium-sodium niobate thick film and a preparation method thereof.The preparation method comprises the steps that firstly, a niobium source is prepared, then RE3+ / Yb3+ double-doped K0.5Na0. 5NbO3 sol (RE=Er, Ho and Tm) is synthesized, the sol is dried into xerogel, then the xerogel is sintered into nano powder, then a tape casting technology is adopted, pressureless sintering is conducted at the temperature of 950-1050 DEG C, and the RE3+ / Yb3+ double-doped K0.5Na0.5NbO3 thick film which has a pure perovskite structure, a compact structure and fine and uniform crystal grains, and has strong up-conversion luminescence under 980 nm exciting light is obtained. The method is simple in process step, low in cost, good in repeatability and easy to operate, the thickness of the thick film is controllable, and the method is expected to be applied to the fields of microelectronic devices, information communication, clinical medicine and the like.
Owner:FUZHOU UNIV

Erbium-doped calcium titanate light-emitting nanoparticle and preparation method thereof

The invention relates to a calcium titanate nanoparticle prepared by adopting a sol-gel method and having up-conversion light-emitting effect. The strong up-conversion light-emitting function can be realized by doping rare earth element erbium, and the light-emitting intensity and light-emitting color can be adjusted according to different doping amount. The nanoparticle with small size and good appearance can be obtained by adding a certain amount of glycerol as an additive into an ethanol solvent. The sol-gel preparation method is simple, the controllability is strong, and the prepared nanoparticle is high in purity and high in yield, and has important application prospects in the field of preparation of light-emitting devices, biotissue imaging and medicine tracing.
Owner:ZHEJIANG UNIV

Method for reinforcing upconversion luminous efficiency of rare earth doped nano-crystal powder material

The invention provides a method for reinforcing the upconversion luminous efficiency of a rare earth doped nano-crystal powder material. The method comprises the following steps of: pressing rare earth ion doped nano-crystal powder into a thin slice by a tablet press; irradiating the surface of the thin slice by high power laser to ensure the position of the irradiated point to be molten until a micro hole is formed; stopping carrying out laser irradiation; and cooling. According to the method provided by the invention, a preparation method, preparation conditions and a doped matrix of the rare earth doped nano-crystal powder material are not changed; other metal ions do not need to be doped; and the obvious reinforcement of the upconversion luminescence can be obtained only by carrying out secondary processing on a formed product.
Owner:三亚哈尔滨工程大学南海创新发展基地

A preparation method of flat hexagonal rare earth doped up-conversion material

The invention relates to a method for preparing a flat hexagonal prism rare-earth doped up-conversion material. The method comprises the following steps: (1) putting a rare-earth oxide into a dilutedhydrochloric acid solution, stirring until complete dissolution, removing excessive hydrochloric acid, and cooling so as to obtain a rare-earth chloride storage liquid for later use; (2) putting a surfactant and a morphology control agent into the rare-earth chloride storage liquid prepared in the step (1), and sufficiently stirring; (3) dropping a sodium fluoride solution, and performing a stirring reaction so as to obtain a rare-earth precursor; (4) finally, putting the rare-earth precursor prepared in the step (3) into a reaction kettle, performing a hydrothermal reaction, separating reaction products, cleaning, and drying, so as to obtain a target product. Compared with the prior art, the method has a function that a flat hexagonal prism beta-NaYF4:Er3+ / Yb3+ material which is smooth insurface and uniform in morphology is prepared through hydro-thermal synthesis for a first time, and the product is complete in morphology, stable in property, uniform in size, large in application value, and the like.
Owner:SHANGHAI JIAOTONG UNIV

Measurement method for energy level radiation-free relaxation coefficients of sensitized ions and activated ions in ytterbium and erbium co-doped sodium yttrium fluoride nanocrystal

The invention provides a measurement method for energy level radiation-free relaxation coefficients of sensitized ions and activated ions in an ytterbium and erbium co-doped sodium yttrium fluoride nanocrystal and belongs to the field of fluorescence imaging application of rare-earth doped up-conversion nanocrystals, aiming at solving the problem that the energy level radiation-free relaxation coefficient W of rare-earth ions cannot be measured through an existing method. The measurement method comprises the following steps: firstly, preparing a nanocrystal with a core-shell-shell structure; taking a NaYF4 core as the center, covering the outer side of the center with a NaYF4:Yb<3+>,Er<3+> luminous layer and taking a NaYF4 shielding shell layer as the outermost layer to obtain the nanocrystal with the core-shell-shell structure; measuring a time-resolved spectrum curve of the sensitized ions and the activated ions of the nanocrystal to obtain service life values of the sensitized ionsand the activated ions; obtaining the energy level radiation-free relaxation coefficients of the sensitized ions and the activated ions respectively according to an energy level radiation theoreticaltransition probability A=A0+W. The measurement method provided by the invention gives a relation between the environment and the energy level radiation-free relaxation coefficients and an optimal shielding shell layer thickness is determined, so that the up-conversion luminous efficiency of the rare-earth ions is improved.
Owner:HARBIN UNIV

Preparation method of small-sized NaYF4 nano substrate material with hexagonal phase by inducement

The invention belongs to the technical field of a nano up-conversion luminescent material, in particular relates to a preparation method for a small-sized NaYF4 nano substrate material with a hexagonal phase by inducement with rare earth nano crystal nucleus. In the method, rare earth ions are doped in the NaYF4 nano substrate material so as to obtain a nano material with a low up-conversion luminescence threshold and high luminescence strength. In the method, the small-sized beta-NaYF4 nano substrate material is generated by inducement with a hydrothermal (solvent) process in the presence of rare earth fluoride nano crystal nucleus, wherein the size of the particle is from 20nm to 200nm, and distribution of the size is even. According to the invention, a preparation method of the small-sized NaYF4 nano substrate material with the hexagonal phase is expanded, and the problem that the NaYF4 nano substrate material, especially water-soluble NaYF4 nano substrate material is difficultly generated at low temperature, is solved. By using the nano up-conversion luminescent material, the demand on biological fluorescent identification probes and disease diagnosis and treatment materials is met, and a foundation is established for the practicable application of the up-conversion luminescent material.
Owner:JILIN UNIV

Erbium-doped calcium titanate luminescent nanoparticles and preparation method thereof

The invention relates to a calcium titanate nanoparticle prepared by adopting a sol-gel method and having up-conversion light-emitting effect. The strong up-conversion light-emitting function can be realized by doping rare earth element erbium, and the light-emitting intensity and light-emitting color can be adjusted according to different doping amount. The nanoparticle with small size and good appearance can be obtained by adding a certain amount of glycerol as an additive into an ethanol solvent. The sol-gel preparation method is simple, the controllability is strong, and the prepared nanoparticle is high in purity and high in yield, and has important application prospects in the field of preparation of light-emitting devices, biotissue imaging and medicine tracing.
Owner:ZHEJIANG UNIV

Gd < 3 + >-doped micron crystal material as well as preparation method and application thereof

The invention belongs to the technical field of rare earth luminescent materials, and discloses a Gd < 3 + >-doped micron crystal material and a preparation method and application thereof.The micron crystal material is obtained by doping Gd < 3 + > with a Y site of a matrix material LiYF4: Yb < 3 + > / Ho < 3 + > micron crystal, and the doping concentration of Gd < 3 + > is smaller than or equal to 60 mol% of the total amount of rare earth elements in the micron crystal material; the preparation method comprises the following steps: dispersing the dispersing agent in a water solvent, sequentially adding the rare earth element source and the matrix source, uniformly mixing, and preserving heat at 210-250 DEG C for 24-60 hours to obtain the micron crystal material. Gd < 3 + > is used for replacing part of Y < 3 + > in the LiYF4 crystal, so that lattice distortion of the LiYF4 crystal is realized, the field symmetry of the crystal is reduced, the transition probability and the number of excited state particles of Ho < 3 + > are increased, energy transfer between Yb < 3 + > and Ho < 3 + > is accelerated, and up-conversion luminescence of Ho < 3 + > is enhanced.
Owner:XIAN UNIV OF POSTS & TELECOMM

A kind of plasmon-enhanced upconversion luminescent nanoparticle and its preparation method and application

The invention discloses a plasmon-enhanced up-conversion luminescent nanoparticle, a preparation method and an application thereof. The plasmon-enhanced upconversion luminescent nanoparticles of the present invention include gold nanosphere groups and Gd wrapped gold nanosphere groups 2 o 3 Nanoparticles; the gold nanosphere group is composed of 38-119 gold nanospheres, and the particle size of the gold nanospheres is 5-15nm; the Gd 2 o 3 Nanoparticles doped with metal ions Yb 3+ and Ln 3+ . by Gd 2 o 3 :Yb 3+ / Ln 3+ The nanoparticles wrap the gold nanosphere group, and under the condition that the gold nanosphere itself has a plasmon resonance wavelength of 538nm, the gold nanosphere group will produce two other resonance peaks in the near-infrared region. The excitation field enhancement effect induced by SPR, the Purcell effect and the quenching effect are mutually synergistic and competitive, which effectively enhances the emission intensity of the upconversion and improves the luminous efficiency of the upconversion.
Owner:SUN YAT SEN UNIV

Fluorosilicate-based up-conversion luminescent ceramic material and preparation method thereof

The invention discloses a fluosilicate based up-conversion luminescence ceramic material and a preparation method thereof; the general chemical formula of the ceramic material is Ca10-10xEr10xYb10ySi3O15F2, wherein x is Er3+ doped chemical metering percent, y is ytterbium ion Yb+3 mixed chemical metering percent, 0.001 is not more than x+y< 0.2. The up-conversion luminescence ceramic material prepared by the method is stable in crystal structure, uniform in grain diameter size, and stable in lighting performance; under the excitation of 976 nanometer infrared laser, a red lighting peak is appeared in the vicinity of 670 nanometer, and the lighting purity is high, and the up-conversion efficiency is high. For the matrix structure is stable and the doped rare earth concentration is high, the ceramic material is good for enhancing the lighting efficiency and realizing the excitation under a high power. In preparation, the compounds containing elements required by compounding lighting materials are mixed at ratio, the ceramic material is prepared by a high-temperature solid phase method; the preparation method is simple in technique, rich in raw material source, and low in price; moreover, the technique process is free from waste water and waste gas, and is toxic-free and environment-friendly; the fluosilicate based up-conversion luminescence ceramic material is further popularized and used.
Owner:NANJING TONGLI CRYSTAL MATERIALS RES INST CO LTD

Lithium niobate up-conversion luminescent material with core-shell structure and preparation method of lithium niobate up-conversion luminescent material

The invention belongs to the technical field of up-conversion / down-conversion luminescent materials. According to the lithium niobate up-conversion luminescent material with the core-shell structure provided by the invention, the inner core and the shell layer are rare earth element doped lithium niobate luminescent materials, so that luminescent centers exposed on the surfaces of particles can beeffectively passivated, and the up-conversion luminescent efficiency is improved. Besides, rare earth ions in the shell layer can be used for down-conversion, invisible light in an ultraviolet regionis converted into visible light, the absorption spectrum of the rare earth ions in the solar cell is expanded, and the application range of the rare earth ions in the solar cell is further expanded;and the lithium niobate up-conversion luminescent material with the core-shell structure has high conversion luminescent efficiency, can achieve up- and down-convertion, also has ferroelectric piezoelectric characteristics, and provides more excellent performance for the use of the lithium niobate up-conversion luminescent material in an integrated device. The preparation method is simple to operate and short in reaction period.
Owner:GUANGDONG UNIV OF TECH

Titanium-aluminate-based up-conversion luminescent material, preparation method and application

The invention relates to a titanium-aluminate-based up-conversion luminescent material, a preparation method and an application, and belongs to the technical field of inorganic luminescent materials. The chemical formula is: Ba 4(1‑x‑y) Er x Yb y Ti 10 Al 2 o 27 , where x is Er 3+ The stoichiometric fraction of doping, y is the ytterbium ion Yb 3+ The stoichiometric fraction of doping, 0.001≤x+y≤0.2, can be prepared by simple high-temperature solid-phase method and sol-gel method. Under the excitation of 976nm infrared laser, the present invention has yellow-green luminous peaks near the wavelengths of 550nm and 660nm, the matrix structure is stable, and the concentration of doped rare earth is high, which is beneficial to enhance the luminous efficiency and realize the excitation under high power, and the up-conversion efficiency High; the prepared up-conversion luminescent material has a uniform particle size, is innovative and has good repeatability, and can be widely used in infrared radiation detection, optical fiber communication technology, fiber amplifier, three-dimensional display, biomolecular fluorescent labeling and other fields. The preparation method of the invention is simple, the cost is low, the raw material supply is unlimited, and the operation and industrial production are easy.
Owner:XUZHOU NORMAL UNIVERSITY

A kind of titanium niobate green up-conversion luminescent material, preparation method and application

The invention discloses a green titanium niobate up-conversion luminescent material, and a preparation method and application thereof. The green titanium niobate up-conversion luminescent material has a general chemical formula of Ca<5-5x>Er<5x>Yb<5y>Nb<4>Ti<3>O<21>, wherein x is the doping mol ratio of Er<3+> ions, y is the doping mol ratio of Yb<3+> ions, and the sum of x and y is no less than 0.001 and no more than 0.20. The green titanium niobate up-conversion luminescent material prepared in the invention has uniform particles, and under the excitation of light with a wavelength of 976 nm, the material emits green light with a wavelength of about 550 nm and has high luminescent intensity and high up-conversion luminescent efficiency. The green titanium niobate up-conversion luminescent material has good stability, no toxicity and no pollution and can be widely applied to fields like infrared radiation detection, optical fiber communication technology, fiber amplifiers, three-dimensional stereo display and biomolecular fluorescent marking. The preparation method is simple, safe, low in production cost, not restricted by raw material supply and easy for operation and industrial production.
Owner:NANJING TONGLI CRYSTAL MATERIALS RES INST CO LTD
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