The embodiment of the invention provides a method for delaying
calcium sulfate scaling in pretreatment and
hardness removal processes of desulfurization
wastewater, and relates to the field of
wastewater treatment. The method comprises the steps that the high-COD and high-salt
flue gas washing desulfurization
wastewater is subjected to
neutralization magnesium removal treatment to obtain a
neutralization solution, the pH value of the
neutralization solution is larger than or equal to 11, and
lime milk is contained in the neutralization solution; adding quantitative
sodium carbonate into the neutralization solution for pre-
softening treatment until 1g / L to 2g / L of
calcium ions are precipitated, so as to obtain a pre-softened treatment solution; carrying out primary
solid-liquid separation on the pre-
softening treatment liquid to obtain a separation liquid;
sodium carbonate is added into the separation liquid for
softening treatment, and softening treatment liquid is obtained; and carrying out
flocculation treatment and secondary
solid-liquid separation on the softening treatment liquid. After the method provided by the invention is used, the
calcium sulfate scaling condition of a plate-and-frame
filter press or filter cloth for carrying out first-time
solid-liquid separation is well improved, and the calcium
sulfate scaling condition is effectively delayed.