793results about "Distillation gas withdrawal" patented technology

A rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. Biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. The liquid product may itself be used as the quench media.

The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.

Disclosed is a scaleable pyrolysis system for batch processing of waste vehicle tires and other waste to provide pyrolysis products. The core pyrolysis system includes one or more batch reactors, heating units, solids processing units, gas / liquid processing units and control units. In operation, the temperature gradients internal to the reactor are controlled by preferential channeling of heat to provide pyrolysis products that are of high quality, and hence commercially advantageous, while facilitating high throughput.

A process for the pyrolysis of carbonaceous material is carried out in a cyclone reactor which is fitted with enhanced filtering equipment. In addition the invention relates to the use of a cyclone fitted with a rotating filter as a pyrolysis reactor. By using a cyclone of the rotating separator type as a pyrolysis reactor, carbonaceous material, such as biomass, can effectively be converted in a product having excellent chemical properties and which product is free from particulate matter.

A process and plant for the thermocatalytic conversion of waste materials into reusable fuels and a fuel produced by the process, involving the steps of delivering melted waste material (11) to one or more pyrolysis chambers (26) via heated and valved manifolds (22) and effecting pyrolysis of the waste material into a gascous state in an oxygen purged and pressure controlled environment. Pyrolytic gases are, then transferred to a catalytic converter (29) where the molecular structure of the gaseous material is altered in structure and form, with gases then transferred to one or more condensers (30a) to distil and cool gases in to their respective fractions. After post pyrolysis treatment, fuel fractions thon form a useable fuel. Includes the melting of waste (plastic) material (11) before delivery into any of the pyrolysis chambers (26), making the movement of material into the catalytic tower (29) a semi-continuous operation, directing melted waste material into one or more, but preferably four, pyrolysis chambers (26a, b, c, d), making each chamber capable of independent operation, optionally mechanically removing waste char from the pyrolysis chamber (107) by use of an internet auger (112) or other suitable means.

This invention involves pyrolysis of feedstock by introducing carbonaceous feedstock, into a hopper and moving it into a reactor tube enclosed in an oven, generating heat within the oven that is in part transferred to the feedstock, heating it to sufficient temperature to pyrolyze the feedstock into useful volatiles and char. A Venturi system produces a negative pressure directing volatiles into a pyro-gas oven producing heat necessary for pyrolysis and generating useful excess heat. The extruded pyrolysis char has uses including charcoal fuel, soil amendments, and activated charcoal while liquids can be produced for processing into fuels. Excess heat may be used to heat water, steam, and air, may be used in air heating and cooling systems, perform mechanical work with a Stirling engine or generate electricity on the order of 100 kW and higher. The system may be operated in a carbon neutral or even carbon negative manner, allowing sequestration of atmospheric carbon dioxide.

A method and apparatus for quenching metallurgical coke made in a coking oven. The method includes pushing a unitary slab of incandescent coke onto a substantially planar receiving surface of an enclosed quenching car so that substantially all of the coke from the coking oven is pushed as a unitary slab onto the receiving surface of the quenching car. The slab of incandescent coke is quenched in an enclosed environment within the quenching car with a plurality of water quench nozzles while submerging at least a portion of the slab of incandescent coke by raising a water level in the quenching car. Subsequent to quenching the coke, the planar receiving surface is tilted to an angle sufficient to slide the quenched coke off of the planar receiving surface and onto a product collection conveyer and sufficient to drain water from the quenched coke.

Methods, process, apparatus, equipment, and systems are disclosed for converting biomass into bio-oil fractions for chemicals, materials, feedstocks and fuels using a low-cost, integrated fast pyrolysis system. The system improves upon prior art by creating stable, bio-oil fractions which have unique properties that make them individually superior to conventional bio-oil. The invention enables water and low-molecular weight compounds to be separated into a final value-added fraction suitable for upgrading or extracting into value-added chemicals, fuels and water. Initial bio-oil fractions from the process are chemically distinct, have low-water content and acidity which reduces processing costs normally associated with conventional bio-oil post-production upgrading since fewer separation steps, milder processing conditions and lower auxiliary inputs are required. Biochar is stabilized so that it can be handled safely. The integrated fast pyrolysis process includes biomass storage, preparation, pretreatment, and conversion, product recovery and processing to create and store stable biochar and bio-oil fractions.

A method of continuously capturing BioOil and its constituents from a gas stream produced in a fast pyrolysis / thermolysis process, in a usable liquid form so as to produce a non-condensable gas free of fouling contaminates. The method includes separating BioOil and its constituents from a gas stream using hot inertial separation to maintain the temperature of said BioOil and its constituents above a temperature at which the thick and / or sticky constituents cause inefficient operation of the equipment but low enough so that they do not undergo rapid degradation. Next the gas velocity is reduced to a temperature sufficiently low to allow droplets in the gas stream to settle out but high enough so that a viscosity of said droplets remains low enough to avoid inefficient operation of the separation equipment. Finally, liquid is condensed out of the gas stream.

A process and system for separating water from bio-oil by using a partial condenser. The process comprises partially condensing vapor conversion products from a biomass conversion reaction to produce a water-rich overhead stream and a water-depleted stream comprising condensed bio-oil. The partial condenser removes a substantial portion of the water from the bio-oil, while providing an effective and flexible process for producing bio-oil.

A process for treating agglomerating coal includes providing dried, pulverized, agglomerating coal, and treating the coal in a vessel with a gas stream having an oxygen content sufficient to form at least some oxides on surface of coal particles, wherein the oxides are sufficient to convert coal into substantially non-agglomerating coal. The treated coal is transferred into a pyrolyzing chamber and passed into contact with an oxygen deficient sweep gas, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to coal indirectly by heating the chamber, wherein the heating of coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. The sweep gas is removed from the chamber and treated to remove condensable components of coal.

Methods and systems for substantially continuously treating comminuted material containing carbon and hydrogen, for example, used tires, are provided. The methods include the steps of introducing the tire material to an elongated chamber, transferring the tire material through the elongated chamber, heating the tire material to a temperature sufficient to pyrolyze the material to produce a gaseous stream; discharging the gaseous stream from the chamber, and cooling at least some of the gaseous stream to liquefy components of the stream. The transfer may be effected by a flexible, center-less screw conveyor to minimize material buildup in the vessel. The cooling of the gaseous stream may be practiced by reverse condensation. One or more re-usable fuel streams are provided by aspects of the invention.

A coke oven includes an oven chamber, an uptake duct in fluid communication with the oven chamber, the uptake duct being configured to receive exhaust gases from the oven chamber, an uptake damper in fluid communication with the uptake duct, the uptake damper being positioned at any one of multiple positions, the uptake damper configured to control an oven draft, an actuator configured to alter the position of the uptake damper between the positions in response to a position instruction, a sensor configured to detect an operating condition of the coke oven, wherein the sensor includes one of a draft sensor, a temperature sensor configured to detect an uptake duct temperature or a sole flue temperature, and an oxygen sensor, and a controller being configured to provide the position instruction to the actuator in response to the operating condition detected by the sensor.

A volatile matter sharing system includes a first stamp-charged coke oven, a second stamp-charged coke oven, a tunnel fluidly connecting the first stamp-charged coke oven to the second stamp-charged coke oven, and a control valve positioned in the tunnel for controlling fluid flow between the first stamp-charged coke oven and the second stamp-charged coke oven.

An apparatus including a coke drum for coking hydrocarbon substances, a valve disposed near the bottom of the coke drum, and a discharge conduit for removing coke from the coke drum, wherein the discharge conduit is connected to the valve such that when the valve is open, the coke may be removed via the discharge conduit.

A divided exchange column includes a shell column having a first longitudinal axis, a cylindrical wall spaced apart from and surrounding the first longitudinal axis and defining a first interior space, a first divided wall column having a second longitudinal axis substantially parallel to the first longitudinal axis, and a second divided wall column having a third longitudinal axis substantially parallel to the first and the second longitudinal axes, where the first divided wall column and the second divided wall column are positioned in the first interior space of the shell column.

An insulated transition spool apparatus for mounting unheading devices to pressure vessels, such as coker vessels, and enabling repetitive operation thereof is disclosed. The apparatus comprises an outer housing, an inner housing that encloses an insulating space between the inner and outer housing, a side feed entry aperture in each housing and a spool adapter flange to facilitate attachment of the spool to the vessel.

The present invention provides a process for the controlled gasification of a carbonaceous feedstock, including: pyrolizing the feedstock to produce a gas product and a solid product, wherein the gas product includes methane and noxious chemicals and the solid product includes carbon; and controlling the pyrolizing step using feedback related to constituents of the gas product. The present invention also provides a system for the controlled gasification of a carbonaceous feedstock, including: a pyrolysis unit including a heater and a conveyor for transporting the feedstock through the heater; a resultant chamber disposed downstream of the pyrolysis unit for separating gas products and solid products; means for adjusting the temperature of the solid products; and a filter for sequestering noxious materials from the gas products, wherein the filter uses at least some of the solid products to filter at least a portion of the gas products.

A coke oven includes an oven chamber, an uptake duct in fluid communication with the oven chamber, the uptake duct being configured to receive exhaust gases from the oven chamber, an uptake damper in fluid communication with the uptake duct, the uptake damper being positioned at any one of multiple positions, the uptake damper configured to control an oven draft, an actuator configured to alter the position of the uptake damper between the positions in response to a position instruction, a sensor configured to detect an operating condition of the coke oven, wherein the sensor includes one of a draft sensor, a temperature sensor configured to detect an uptake duct temperature or a sole flue temperature, and an oxygen sensor, and a controller being configured to provide the position instruction to the actuator in response to the operating condition detected by the sensor.

Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fluidizing dense bed.

The present invention features a flange to flange dynamic seal and sealing system, particularly suited for use within high temperature, high pressure environments, such as a delayed coking process. The dynamic flange seal and sealing system comprises two primary elements or seals, each of which are capable of independently forming a flange seal between two flanged components or combining to create a flange seal. Specifically, these primary seals are an iconel bellows seal and a bi-material gasket, each of which surround a flange opening along a sealing surface. The flange seal created by the dynamic flange seal and sealing system is capable of being maintained in light of, or rather the sealing system adapts to, any structural or environmental changes within the connected flanges. As such, the flange seal may be a dynamic flange seal or a static flange seal or both.

Embodiments of methods and apparatuses for rapid thermal processing of carbonaceous material are provided herein. The method comprises the step of contacting a carbonaceous feedstock with heated inorganic heat carrier particles at reaction conditions effective to rapidly pyrolyze the carbonaceous feedstock to form a product stream comprising pygas, pyrolysis oil, and solids. The solids comprise char and cooled inorganic heat carrier particles. The reaction conditions include a reactor pressure of about 70 kPa gauge or greater.

The damper baffle includes a U-shaped sub-frame and a temperature resistant insulation damper mat draped over and secured upright to the sub-frame for use in the ventilation system of a coke oven. The damper mat is a thick sheet of silica needle mat, which provides the thermal barrier of the damper baffle. The sub-frame is a bent high temperature steel rod which is bolted directly to the base plate of a conventional lift frame and lift mechanism. Two pairs of support plates secure and support the mat over the sub-frame in an upright orientation. The damper baffle seeks to provide a light-weight damper baffle for use in coke ovens, which eliminates the need for the heavy and cumbersome refractory baffle blocks.

The invention relates a method and a device for recovering the waste heat of a coke oven crude gas. In the method, the refractory lining bricks of a riser are improved by using silicon carbide refractory lining bricks, a semiconductor temperature difference power generation module is arranged on the outer wall of the riser so as to use the coke oven crude gas in the riser as the heat source of a semiconductor temperature difference power generator, the riser serves as the heat collector of for semiconductor temperature difference power generation, and the waste heat recovery of the coke oven crude gas in the riser is realized. The method and the device of the invention have the advantages that: 1) the problem of recovering the waste heat of the coke oven crude gas in a coking process is solved; and 2) when the method and the device are used, the waste heat carried by the coke oven crude gas can be recovered for generating power and cooling hot water flowing out from a channel and for civil or industrial heating, cooling and heat production for saving energy and improving energy efficiency.

A volatile matter sharing system includes a first stamp-charged coke oven, a second stamp-charged coke oven, a tunnel fluidly connecting the first stamp-charged coke oven to the second stamp-charged coke oven, and a control valve positioned in the tunnel for controlling fluid flow between the first stamp-charged coke oven and the second stamp-charged coke oven.

Improved, fuel-efficient systems are provided for the processing of biomass, such as wood or crop residues, food waste or animal waste in order to selectively obtain torrefied and / or carbonized final products. In general, the processes involve thermally drying incoming biomass using a dryer employing the hot gas output of a fuel-operated burner. Next, the dried product is torrefied in an indirect torrefaction reactor so as to evolve light volatile organic compounds which are used as a gaseous fuel source for the burner. The torrefied product can be recovered, or some or all of the torrefied product may be directed to a carbonization reactor coupled with a reactor burner. Carbonization serves to remove most of the remaining VOCs which are used as a gaseous fuel input to the dryer. In certain instances, portions of the dried biomass are directed to the burners, as an additional source of fuel.

A method of continuously capturing BioOil and its constituents from a gas stream produced in a fast pyrolysis / thermolysis process, in a usable liquid form so as to produce a non-condensable gas free of fouling contaminates. The method includes separating BioOil and its constituents from a gas stream using hot inertial separation to maintain the temperature of said BioOil and its constituents above a temperature at which the thick and / or sticky constituents cause inefficient operation of the equipment but low enough so that they do not undergo rapid degradation. Next the gas velocity is reduced to a temperature sufficiently low to allow droplets in the gas stream to settle out but high enough so that a viscosity of said droplets remains low enough to avoid inefficient operation of the separation equipment. Finally, liquid is condensed out of the gas stream.

The invention discloses a drying and dry distillation combined quality improving process and a drying and dry distillation combined quality improving system for low rank coal, which are used for overcoming the defects existing in the prior art and are particularly suitable for drying and dry distillation combined quality improvement of brown coal with high water content or other low rank coal such as long flame coal, non-caking coal or weakly caking coal, gas coal and the like. In the process, a combined quality improving method in which a steam revolving drier for drying and a multi-pipe revolving low-temperature dry distiller for dry distillation are provided is adopted, so that the problems of large coking wastewater handling capacity, large coal gas handling capacity and the like existing in a pure dry distillation process are solved. The drying and multi-pipe revolving low-temperature dry distillation combined quality improving process provided by the invention has the advantages of high energy utilization ratio, safe and stable systems, small dry distillation gas handling capacity, small coking wastewater handling capacity, high tar yield, high coal gas heat value and the like.