The invention discloses a method for synthesizing fluorine halogenated ether. The method comprises the following steps of: 1) adding ethylene glycol, solvent and catalyst into a reaction kettle, introducing tetrafluoroethylene with stirring and starting to react, wherein the mass ratio of tetrafluoroethylene to ethylene glycol is 1:(2-8), the mass ratio of the solvent to the ethylene glycol is (0.25-4.5):1, the mass ratio of the catalyst to the ethylene glycol is 1:(5-27), controlling reaction temperature to be 10 to 125 DEG C and reaction pressure to be 0.1 to 1.5MPa, stopping introducing tetrafluoroethylene, then cooling, discharging, and rectifying to obtain 2-(1,1,2,2-tetrafluoroethoxy) ethanol; and 2) reacting the 2-(1,1,2,2-tetrafluoroethoxy) ethanol which is obtained in the step 1) and a halogenating agent in a mass ratio of 1:(0.5-2) at the temperature of between 50 and 100 DEG C for 1 to 5 hours, cooling a reaction solution, washing, layering, and rectifying to obtain a product. The method is mild in reaction condition, low in cost, and in yield; and the product is high in quality.