The invention relates to a
zinc-based
metal organic framework with a selective fluorescent recognition function on
acetylacetone and a preparation method thereof. A
chemical formula is C80H48N8O12Zn3;a
crystal is crystallized in a monoclinic
system; lattice parameters are as follows: a is equal to 18.96 angstroms, b is equal to 11.21 angstroms, c is equal to 36.62 angstroms, alpha is equal to 90degrees, beta is equal to 100.91 degrees and gamma is equal to 90 degrees. The invention further provides the preparation method of the
zinc-based
metal organic framework; the preparation method comprises the following steps: adding
zinc nitrate hexahydrate, 1,3-bis(
benzimidazole-1-yl)
benzene, 1,4-naphthalic acid, N,N-
dimethylformamide and
ethanol into a small glass
bottle; carrying out ultrasonictreatment to uniformly mix the materials; raising the temperature of a mixture and reacting for 65 to 80 h; cooling to obtain a colorless block-shaped
crystal; collecting the
crystal and washing withethanol; after
drying in the air, obtaining the zinc-based
metal organic framework. According to the preparation method provided by the invention, a new direction is provided for preparation of a light-emitting
metal organic framework material based on a relatively strong coordination capability of
divalent zinc ions and cooperative coordination of two organic ligands; the zinc-based
metal organic framework can be used as a fluorescent material for recognizing small molecular organic matters and has potential application value in the fields of
chemistry and materialogy.