33results about How to "Strong ionization ability" patented technology

The invention discloses a secondary amide di-quaternary ammonium salt type hydroxypropyl sodium sulfonate asphalt emulsifier and a preparation method thereof, wherein the secondary amide di-quaternary ammonium salt type hydroxypropyl sodium sulfonate asphalt emulsifier is prepared from the following raw materials N-hydrogenated tallow-1,3-propylene diamine, an alcohol solvent, N-hydroxymethyl acrylamide, epichlorohydrin and sodium bisulfite according to a molar ratio of 1:(5.00-11.00):(3.00-3.10):(2.00-2.30):(2.10-2.50), and the alcohol solvent is ethanol, methanol or isopropanol. According to the present invention, the preparation method has advantages of easily available raw material, low production cost, simple process and no requirement of high temperature reaction; and the obtained secondary amide di-quaternary ammonium salt type hydroxypropyl sodium sulfonate asphalt emulsifier can emulsify a variety of different types of asphalts, and can be used for preparing cationic emulsified asphalts, and the emulsified asphalt prepared from the secondary amide di-quaternary ammonium salt type hydroxypropyl sodium sulfonate asphalt emulsifier has advantages of fine and uniform property and good storage stability.

The invention discloses a carboxylic acid diquaternary ammonium salt type sodium hydroxypropyl sulfonate asphalt emulsifier, the molecular structure of which is as follows: it is prepared from raw materials with the following molar ratio: N-hydrogenated tallow-1,3- The molar ratio of propylene diamine, alcohol solvent, acrylic acid, epichlorohydrin, sodium bisulfite is 1mol: (5.00‑11.00) mol: (3.00‑3.10) mol: (2.00‑2.30) mol: (2.10‑ 2.50) mol. The production cost of the asphalt emulsifier of the invention is low, the process is simple, and no high-temperature reaction is required.

The invention discloses a lignin polyamine cation rapid-cracking type asphalt emulsifier and a preparation method thereof. The molecular structure of the emulsifier is as shown in the specification. In the formula, R is methyl (-CH3), ethyl (-C2H5) or ethoxyl (-C2H4OH); LIGNIN represents a lignin molecular chain. The lignin polyamine cation rapid-cracking type asphalt emulsifier is prepared from the following raw materials in parts by weight: lignin, water, sodium hydroxide, diethylenetriamine, crylic acid, formaldehyde (37%), low-carbon-number tertiary amine and industrial hydrochloric acid in a ratio of 100:(159-230):(19-27):(32-40):(23-29):(30-36):(35-82):(42-50):(31-37). The lignin polyamine cation rapid-cracking type asphalt emulsifier disclosed by the invention is high in synthesis raw material availability, low in production cost, simple in process and free of high-temperature reaction. Multiple types of asphalt of different models can be emulsified, the prepared emulsified asphalt is fine and uniform, the storage stability is good, and the rapid-cracking type cation emulsified asphalt can be prepared.

The invention discloses a lignin cyclamine cationic-type asphalt emulsifier and a preparation method and application thereof. The molecular structure general formula of the emulsifier is as shown in the description, wherein R is a methyl group (-CH3) or an ethyl group (-C2H5) or a hydroxyethyl group (-C2H4OH), and LIGNIN represents a lignin molecular chain. The lignin cyclamine cationic-type asphalt emulsifier is prepared from, by mass, 100 parts of lignin, 159-230 parts of water, 19-27 parts of sodium hydroxide, 42-50 parts of N-aminoethylpiperazine, 23-29 parts of acrylic acid, 30-36 parts of formaldehyde (37%), 35-82 parts of tertiary amine with a low carbon number, 42-50 parts of industrial hydrochloric acid (30%) and 31-37 parts of epoxy chloropropane. According to the lignin cyclamine cationic-type asphalt emulsifier, the synthesis raw materials are easy to obtain, the production cost is low, the technology is simple, and high-temperature reacting is not needed; the emulsifier can emulsify different types of asphalt, the prepared emulsified asphalt is fine and uniform, the storage stability is good, and rapid-cracking cationic-type emulsified asphalt can be prepared.

The invention discloses a primary amide quaternary ammonium salt type sodium hydroxypropyl sulfonate asphalt emulsifier. Its molecular structure is: it is prepared from the following molar ratio raw materials: octadecylamine, alcohol solvent, acrylamide, The molar ratio of epichlorohydrin and sodium bisulfite is 1 mol: (4.00-9.00) mol: (2.00-2.10) mol: (1.00-1.15) mol: (1.05-1.25) mol. The production cost of the asphalt emulsifier of the invention is low, the process is simple, and no high-temperature reaction is required.

The present invention discloses a multi-positive-ion amide-type asphalt emulsifier and a preparation method thereof, and the asphalt emulsifier is prepared from raw materials of N-hydrogenated tallow-1,3-propylene diamine, an alcohol solvent, acrylamide, a low-carbon tertiary amine, industrial hydrochloride and epichlorohydrin in the molar ratio of N-hydrogenated tallow-1,3-propylene diamine to alcohol solvent to acrylamide to low-carbon tertiary amine to industrial hydrochloride to epichlorohydrin of 1mol: (5.00-11.00) mol: (3.00-3.10) mol: (2.02-2.10) mol: (2.02-2.10) mol: (2.02-2.08) mol. The alcohol solvent is ethanol, methanol or isopropanol. The low-carbon tertiary amine is a trimethylamine aqueous solution, triethylamine or triethanolamine. The asphalt emulsifier synthetic raw materials are readily available, production cost is low, a process is simple, and a high temperature reaction is not required. The asphalt emulsifier can emulsify a variety of different types of asphalt, the prepared emulsified asphalt is fine, uniform, and good in storage stability, and positive-ion-type emulsified asphalt can be prepared.

The invention discloses a dicationic amide type asphalt emulsifier, the molecular structure of which is represented by a formula, wherein R is a methyl group (-CH3), an ethyl group (-C2H5) or an alcoholic group (-C2H4OH); The emulsifier is prepared from the following raw materials in a following molar ratio: octadecylamine: an alcohol solvent: acrylamide: low carbon number tertiary amine: technical hydrochloric acid: epichlorohydrin=1mol:(4.00-9.00)mol:(2.00-2.10)mol:(1.02-1.10)mol:(1.02-1.10)mol:(1.02-1.08)mol. The dicationic amide type asphalt emulsifier disclosed by the invention is easily available in synthetic raw materials, low in production cost, simple in process and free of high-temperature reactions. The emulsifier can be used for emulsifying asphalt in various different types and the prepared emulsified asphalt is fine and smooth and uniform and good in storage stability. The emulsifier can be used for prepare rapid type cationic emulsified asphalt.

The invention discloses a tertiary amide quaternary ammonium salt type sodium hydroxypropyl sulfonate asphalt emulsifier and a preparation method thereof. The asphalt emulsifier is prepared from the following raw materials in molar proportions: octadecylamine, alcohol solvent, The molar ratio of N,N-dimethylacrylamide, epichlorohydrin and sodium bisulfite is 1mol: (4.00-9.00)mol: (2.00-2.10)mol: (1.00-1.15)mol: (1.05-1.25) ) mol. The alcoholic solvent is ethanol, methanol or isopropanol. The synthetic raw materials of the asphalt emulsifier of the invention are easy to obtain, the production cost is low, the process is simple, and no high-temperature reaction is required. It can emulsify various types of asphalt, the prepared emulsified asphalt is fine and uniform, has good storage stability, and can prepare cationic emulsified asphalt.

The invention discloses a tert-amide bis-quaternary phosphonium type sodium hydroxypropyl sulfonate asphalt emulsifier and a preparation method thereof. The asphalt emulsifier is prepared from, by mole, 1 part of N-hydrogenated tallow-1,3-diaminopropane, 5.00-11.00 parts of an alcohol solvent, 3.00-3.10 parts of N,N-dimethylacrylamide, 2.00-2.30 parts of epoxy chloropropane and 2.10-2.50 parts of sodium hydrogen sulfite, wherein the alcohol solvent is ethanol or methanol or isopropanol. The asphalt emulsifier has the advantages that the synthesis raw materials are easy to obtain, the production cost is low, the process is simple, a high-temperature reaction is not needed and can emulsify multiple different types of asphalt, the prepared emulsified asphalt is fine, uniform and good in storage stability, and cationic emulsified asphalt can be prepared.

The invention discloses a lignin polyamine cation type asphalt emulsifier as well as a preparation method and an application thereof. The asphalt emulsifier has the molecular structural general formula shown in the specification, wherein R refers to methyl (-CH3), ethyl (-C2H5) or an ethoxy group (-C2H4OH); LIGNIN refers to a lignin molecular chain. Acrylic acid, triethylene tetramine, low-carbon-number tertiary amine and epoxy chloropropane are added to raw materials, so that a prepared asphalt emulsifier molecule adopts the polyamine cation type chemical structure, the charge strength of the asphalt emulsifier molecule is enhanced, and the hydrophilia of the asphalt emulsifier molecule is improved.

The present invention discloses an electro-spray desorption ionization device for mass spectrometry imaging. The device comprises a carrier liquid inner tube and a carrier liquid outer tube sleeved at the outer portion of the carrier liquid inner tube, the carrier liquid inner tube is configured to output spray solution applied by high voltage, a carrier gas cone outer tube is configured to output spray auxiliary airflow acted on the spray solution output by the carrier liquid inner tube, and formed electrospray is configured to perform desorption ionization of samples. The device also comprises external airflow field devices arranged at the carrier liquid inner tube and the exit of the carrier gas cone outer tube, and the external airflow field devices apply an airflow field to the electrospray when being controlled to start so as to separate the electrospray from areas where the samples are located. The device can remove noise caused by pollution of samples through spray in the detection motion process, eliminate the fuzzy imaging and improve the imaging resolution while ensuring the continuous and stable spraying.

The invention discloses a dicationic and monoanionic tertiary amide asphalt emulsifier and a preparation method thereof. The asphalt emulsifier is prepared from the following raw materials of octadecylamine, an alcohol solvent, N,N-dimethylacrylamide, low-carbon tertiary amine, industrial hydrochloric acid, epoxy chloropropane and sodium chloroacetate at the molar ratio of 1mol:(4.00-9.00)mol:(1.00-1.08)mol:(1.02-1.10)mol:(1.02-1.10)mol:(1.02-1.08)mol:(1.02-1.10)mol. An amide group is introduced into a molecular structure of the prepared asphalt emulsifier through adding N,N-dimethylacrylamide to form the dicationic and monoanionic tertiary amide asphalt emulsifier, so that the hydrophilicity of the asphalt emulsifier and the compatibility of the emulsifier and asphalt are improved.