The invention discloses organic optical
iridium coordination compounds and application thereof in an organic electro-generated white or orange optical device. The orange optical
iridium coordinate compounds have a
structural formula as formula 1 or formula 2 which is shown in the specification, wherein R1 can be
trifluoromethyl or pentafluoroethyl, R4 can be
trifluoromethyl or pentafluoroethyl or R1=R4, R2 is selected from
hydrogen, methyl, ethyl and
halogen or
halogen-substituted methyl or ethyl, R3 is independently selected from
hydrogen, methyl, ethyl,
halogen or halogen-substituted methyl or ethyl or R2=R3, and the halogen is
fluorine,
chlorine,
bromine or
iodine. The invention has the advantages as follows: a
fluorine-containing modified
iridium coordination compound can be used for effectively lowering vibrating frequency, reducing non-
radiative transition and increasing
electroluminescence efficiency; a film prepared by using a
fluorine atom-containing modified coordination compound has better feature; self-
quenching behaviors are restrained by steric hindrance of CF3; and charge transfer
balance performance is increased by very good current carrier
transmission performance, so that an efficient doped organic electro-generated luminescent device can be manufactured.