Highly effective two-color white light high polymer material and method for making same
A polymer material and two-color technology, applied in the direction of luminescent materials, chemical instruments and methods, sustainable buildings, etc., can solve the problems that the efficiency is still far from practicality, and achieve high electroluminescence efficiency, electroluminescence The effect of stable spectrum and low energy consumption
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0023] Example 1: Preparation of 4,7-bis(4-(N-phenyl-N-(4-methylphenyl)amino)phenyl)-2,1,3-benzothiadiazole
[0024] Under the protection of nitrogen atmosphere, 4,7-dibromo-2,1,3-benzothiadiazole (1.47g, 5.0mmol), tributyl (4-(N-phenyl-N-(4- Methylphenyl) amino)-phenyl) tin (6.03g, 11mmol), tetrakis (triphenylphosphine) palladium (0.057g, 0.05mmol), the mixture of toluene (100ml) was reacted at 100°C for 30 hours , and then the reaction mixture was poured into potassium fluoride aqueous solution, extracted with chloroform, then washed three times with water, dried, concentrated, and column separated to obtain pure intermediate product 4,7-bis(4-(N-phenyl-N-(4- Methylphenyl)amino)-phenyl-)-2,1,3-benzothiadiazole 2.340 g, yield 72%.
Embodiment 2
[0025] Example 2: 4,7-bis(4-(N-(4-bromophenyl)-N-(4-methylphenyl)amino)-phenyl-)-2,1,3-benzo Synthesis of Thiadiazoles
[0026] Under the protection of nitrogen atmosphere, 4,7-bis(4-(N-phenyl-N-(4-methylphenyl)amino)-phenyl-)-2,1,3-benzothiadi Azole (0.651g, 1mmol) was dissolved in chloroform, aluminum trichloride was added, and then tetrabutylammonium tribromide (1.446g, 3mmol) was added in batches several times, and reaction was carried out for 30 minutes after adding, and then the reaction mixture was used Washed once with aqueous sodium bisulfite solution, washed several times with water, dried, concentrated, and separated by column to obtain pure intermediate product 4,7-bis(4-(N-(4-bromophenyl)-N-(4-methylbenzene Base) amino)-phenyl-)-2,1,3-benzothiadiazole 0.751g, yield 93%.
Embodiment 3
[0027] Example 3: Synthesis of two-color white light polymer material P1 (structural formula shown below)
[0028]
[0029]Under nitrogen protection, 9,9-dioctyl-2,7-dibromofluorene (0.2740g, 0.4997mmol), 9,9-dioctyl-2,7-(trimethylene Borate)fluorene (0.2792g, 0.5mmol), 4,7-bis(4-(N-(4-bromophenyl)-N-(4-methylphenyl)amino)-phenyl- )-2,1,3-benzothiadiazole (0.0005g, 0.0006mmol), 2M potassium carbonate aqueous solution (2mL), toluene (10mL), methyl trioctyl ammonium chloride (0.13g) mixture, in React at 80°C for ten minutes, then add tetrakis(triphenylphosphine)palladium into the reaction bottle, stir at 90°C for 48 hours, then stir at 60°C for 24 hours. The reaction mixture was dissolved in chloroform, washed several times with water, dried, concentrated, and then settled three times with methanol. The product was placed in a Soxhlet extractor and extracted with acetone for 24 hours. Then it was dissolved in chloroform, settled in methanol, and the product was vacuum-dried...
PUM
Property | Measurement | Unit |
---|---|---|
Maximum brightness | aaaaa | aaaaa |
Lumen efficiency | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com