An organic compound and its application in organic electronic devices
A technology of organic electronic devices and organic compounds, which is applied in the field of organic electroluminescence, can solve the problems of device performance and life expectancy, and achieve the effects of improving electroluminescence efficiency and device life, close stacking, and effective transmission effect
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preparation example Construction
[0099] The preparation method as described above is characterized in that the thickness of the formed functional layer is 5nm-1000nm.
[0100] The invention further relates to an organic electronic device comprising at least one organic compound according to the invention, or at least one functional layer, which is produced using a composition according to the invention. Generally, such an organic electronic device at least comprises a cathode, an anode and a functional layer between the cathode and the anode, wherein the functional layer contains at least one organic compound as mentioned above.
[0101] In a more preferred embodiment, the above-mentioned organic electronic device is an electroluminescent device, especially an OLED (such as figure 1 shown), which includes a substrate (101), an anode (102), at least one light-emitting layer (104), and a cathode (106).
[0102] OLEDs can also contain other functional layers such as hole injection layer (HIL) or hole transport...
Synthetic example 1
[0107] Synthesis Example 1: Synthesis of Compound 1
[0108]
[0109] Materials 1-1 (6.56g, 20mmol), 1-2 (5.3g, 20mmol), Pd(dba) 2 (0.345g, 0.6mmol), sodium tert-butoxide (5.76g, 60mmol) and tri-tert-butylphosphine (plasmid ratio 10%, 3.5ml) were placed in a 1000ml two-necked flask, anhydrous toluene 100mL was added under nitrogen protection, and 90 Celsius, and stir overnight. Cooled to room temperature, washed with water, dried, and purified by column chromatography to obtain compound 1 (7.8 g, 70%).
Synthetic example 2
[0110] Synthesis Example 2: Synthesis of Compound 2
[0111]
[0112] The raw material 2-1 (6.56g, 20mmol), 2-2 (6.8g, 20mmol), Pd (dba) 2 (0.345g, 0.6mmol), sodium tert-butoxide (5.76g, 60mmol) and tri-tert-butylphosphine (plasmid ratio 10%, 3.5ml) were placed in a 1000ml two-necked flask, anhydrous toluene 100mL was added under nitrogen protection, and 90 Celsius, and stir overnight. Cooled to room temperature, washed with water, dried, and purified by column chromatography to obtain compound 2 (8.9 g, 70%).
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