55results about How to "Burning at high temperature makes the organic matter completely carbonized and strong adsorption" patented technology

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical catalysts. The preparation method includes: using a diatom purifier, kyanite, aluminum hydroxide, celestite, fly ash and coal gangue as the carriers, using lithium hypochlorite and bis(acetylacetone) beryllium to perform pore expansion on the carriers, adding chlorinated dodecyl dimethyl hydroxyethyl ammonium to activate the carriers under ultrasonic action, allowing the carriers to have hydrothermal reaction with compound mineralizer including borax and potassium sulfate, catalytic activity promoter precursors including tri(hexafluoroacetylacetone) yttrium(III) dihydrate, acetylacetone samarium, tri(4, 4, 4-trifluoro-1-(2-thiophene)-1, 3-butanedione) europium and tri(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octene diketone) dysprosium(III), and catalytic activity central precursors including pyruvic acid isonicotinoyl hydrazone vanadium, nickel citrate, cupric glutamate and dipotassium hexachloroosmate in a hydrothermal reaction kettle under the effect of N-dodecyl dimethyl-N'-dodecyl-dimethyl-2-hydroxypropyl ammonium dichloride, drying to remove moisture, and burning in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidized solid catalyst, and belongs to the technical field of environmental protection and chemical catalyst. The preparation method comprises the following steps: taking maifanite, wollastonite, potassium feldspar, szaibelyite, illite and raphite as carriers, performing lithium hypochlorite and bis(acetylacetonato) beryllium reaming, adding octadecyl trimethyl ammonium chloride to perform activating treatment under an ultrasonic effect; and then enabling the active carriers to perform hydrothermal reaction with the compound mineralizing agent borax and potassium sulfate, catalytic active promoter precursors scandium isopropoxide (III), thulium trifluoromethane sulfonate (III), tri(trifluoromethane sulfimide)ytterbium, lutetium carbonate hydrate, catalytic active center precursors titanocene ring substituted salicylic complex, L-aspartic acid molybdenum, gold potassium tetrachloride and iridium tetrachloride dihydrate under the effect of the emulsifier N-decyl dimethyl-N -trimethyl-2-hydroxypropyl ammonium dichloride, drying to remove the moisture, firing in a muffle furnace to obtain the ozone heterogeneous oxidized solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking medical stones, wollastonite, light shale ceramisite, pyrophyllite, nitratine and dolomite as carriers, after chambering and modifying the carriers through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant, octadecyl trimethyl ammonium chloride, for surface activating treatment under the action of ultrasonic waves; then causing the carriers to generate hydrothermal reaction with borax and potassium sulfate which serve as compound mineralizers, isoproscandium oxide (III), 1,1,1-trifluoroacetyl acetone neodymium, tri(2,2,6,6-tetramethyl-3,5- heptylic diketone acid) gadolinium and holmium oxalate decahydrate which serve as catalytic active auxiliary agent precursors, and a titanocene ring substituted salicylic acid complex, nickel citrate, molybdenum L-aspartate and gold potassium tetrachloride which serve as catalytic active central compound precursors in a hydrothermal reaction kettle under the action of an emulsifier, N-octadecyl dimethyl-N'-propyl ammonium dichloride, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical field of environmentally-friendly and chemical catalysts. The preparation method comprises the following steps: by taking diatom pure, kyanite, illite, ulexite, hydrotalcite and alunite as carriers, reaming the carriers with lithium hypochlorite and bis(acetylacetone) beryllium, then adding monoalkyl ether trimethyl ammonium chloride serving as a surfactant for activation treatment under ultrasonic action, putting the carriers into a hydrothermal reaction kettle for hydrothermal reaction together with borax and potassium sulfate which serve as composite mineralizers, tri(hexafluoroacetylacetone) yttrium (III) dihydrate, 1,1,1-trifluoroacetylacetone neodymium, tri(trifluoromethane sulfimide) ytterbium and lutetium carbonate hydrate which serve as catalytic active auxiliary precursors, pyruvate iso-nicotinazone vanadium, cobalt gluconate and zirconium ammonium carbonate which serve as catalytic active center precursors and gold potassium chloride under the action of N-decylalkyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonia dichloride serving as an emulsifier, drying a reaction product to remove water, and firing the reaction product in a muffle furnace, thus obtaining the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environmental-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking erionite, garnet, diatom pure, kyanite, bentonite and polyhalite as a carrier, after chambering and modifying the carrier through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant dodecyl trimethyl ammonium chloride for surface activating treatment under the action of ultrasonic waves; then performing a reaction on the ultrasonic surface activated carrier in a hydrothermal reaction kettle and a compound mineralizer borax and potassium sulfate and catalytic active auxiliary agent precursors isoproscandium oxide (III), a tri(hexafluoroacetyl acetone) yttrium (III) dihydrate, tri(3-trifluoro acetyl-D-camphor) praseodymium (III) and thulium trifluoromethanesulfonate (III); and performing a hydrothermal reaction with catalytic active central compound precursors a titanocene ring substituted salicylic acid complex, vanadium isonicotinoyl hydrazone pyruvate, cupric glutamate and dichlorotetraaminopalladium under the action of an emulsifier N-dodecyl dimethyl-N'-dodecyl-2-hydroxypropyl ammonium dichloride, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, belonging to the technical field of environment-friendly and chemical catalysts. The preparation method comprises the following steps: by taking gama-aluminum oxide, baryte, basalt, blodite, brucite and serpentinite porous materials as carriers, performing pore expansion and modification to the carriers through lithium hypochlorite and beryllium bis(acetylacetonate), adding a surfactant dimethyl distearylammonium chloride and performing surface activation treatment under ultrasonic wave effect, then leading the ultrasonically surface-activated carriers to have hydrothermal reaction with a complex mineralizer (borax and potassium sulfate), catalytic activity assistant precursors, namely tetra(2,2,6,6-tetramethyl-3,5-heptanedionato)cerium(IV), samarium (iii) acetylacetonate dehydrate, tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyloctane-3,5-dionato-O,O')dysprosium (III), thulium(III) trifluoromethanesulfonate rare earth metal organic compound, and catalytic active site component precursors, namely common transitional metal organic compound manganese lysinate, zirconium ammonium carbonate and tungsten catechol ethylenediamine complex and precious metal compound tetraammine dichloropalladium in a hydrothermal reactor under the action of an emulsifier 2,6-di(diethylaminomethyl)-4-nonylphenol-epichlorohydrin quaternary ammonium salt, drying reactive products to remove moisture, and firing in a muffle furnace at certain temperature, to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environmental-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking erionite, garnet, diatom pure, kyanite, potassium feldspar and szaibelyite as a carrier, after chambering and modifying the carrier through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant dodecyl trimethyl ammonium chloride for surface activating treatment under the action of ultrasonic waves; then performing a reaction on the ultrasonic surface activated carrier in a hydrothermal reaction kettle and a compound mineralizer borax and potassium sulfate and catalytic active auxiliary agent precursors isoproscandium oxide (III), a tri(hexafluoroacetyl acetone) yttrium (III) dihydrate, tri(3-trifluoro acetyl-D-camphor) praseodymium (III) and tri(trifluoromethane sulfimide) ytterbium; and performing a hydrothermal reaction with catalytic active central compound precursors a titanocene ring substituted salicylic acid complex, vanadium isonicotinoyl hydrazone pyruvate, cupric glutamate and dipotassium hexachloroosmate under the action of an emulsifier N-dodecyl dimethyl-N'-dodecyl-2-hydroxypropyl ammonium dichloride, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, potassium feldspar, ascharite, illite and ulexite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-bis(diethylamino methyl)-4-nonyl phenol-chlorinated benzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, holmium oxalate decahydrate, trifluoromethane thulium sulfonate (III) and tri(trifluoromethane sulfimide)ytterbium and catalytic activity central precursor cobalt gluconate, nickel citrate, terpyridyl ruthenium chloride hexahydrate and potassium tetrachloroaurate in a hydrothermal reaction kettle under action of an emulsifier octadecyl dimethyl ethoxy ammonium laurate; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidized solid catalyst, and belongs to the technical field of environmental protection and chemical catalyst. The preparation method comprises the following steps: taking perlite, albite, nitratine, dolomite, coal ash and coal gangue as carriers, performing lithium hypochlorite and bis(acetylacetonato) beryllium reaming, adding a surfactant N-decyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride to perform activating treatment under an ultrasonic effect; and then enabling the active carriers to perform hydrothermal reaction with the compound mineralizing agent borax and potassium sulfate, catalytic active promoter precursors tri(cyclopentadienyl) promethium, tris(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono)europium (III), holmium oxalate decahydrate, lutetium carbonate hydrate, catalytic active center precursors cobalt gluconate, cupric glutamate, terpyridyl ruthenium chloride hexahydrate, dipotassium hexachloroosmium under the emulsifier N-oleyl-N'N'-diethyl ethylenediamine dihydrochloride, drying to remove the moisture, firing in a muffle furnace to obtain the ozone heterogeneous oxidized solid catalyst.

The invention belongs to the technical field of environment protection and chemical catalysts and relates to an ozone heterogeneous oxidation solid catalyst preparation method. The preparation method includes: taking porous mineral materials including perlite, albite, bentonite, polyhalite, basalt and bloedite as carriers; subjecting the carriers to lithium hypochlorite and bis(acetylacetone)beryllium broaching modification; adding surfactant nonylphenol biquaternary ammonium salt for surface activation under the action of ultrasonic waves; subjecting the carriers subjected to ultrasonic surface activation to hydrothermal reaction, with a complex mineralizer composed of borax and potassium sulfate, catalytic activity auxiliary agent precursors including1,1,1-neodymium trifluoroacetylacetonate, tri(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octenyldiketone)dysprosium (III), tris[N,N-bis(trimethylsilane)amine]erbium and tri(trifluoromethanesulfonimide)ytterbium rare earth metal organic compounds and catalytic activity central component precursors including normal transition metal organic compounds namely cobalt gluconate and nickel citrate and precious metal compounds namely potassium dithiocyanoargentate (I) and tetraammine dichloropalladium, in a hydrothermal reactor under the action of trimethylamino glycolate ammonium iodide palmitate serving as an emulsifying agent; drying reaction products to remove moisture, and firing in a muffle furnace at a certain temperature to obtain an ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical field of environmentally-friendly and chemical catalysts. The preparation method comprises the following steps: by taking porous materials of perlite, albite, aluminum hydroxide, phosphorite, illite and ulexite as carriers, reaming and modifying the carriers with lithium hypochlorite and bis(acetylacetone) beryllium, then adding N-octadecyldimethyl-N'-trimethyl-propyl ammonia dichloride serving as a surfactant for surface activation treatment under ultrasonic action, putting the ultrasonically surface-activated carriers into a hydrothermal reaction kettle for hydrothermal reaction together with borax and potassium sulfate which serve as composite mineralizers, 1,1,1-trifluoroacetylacetone neodymium, tri(2,2,6,6-tetramethyl-3,5-hepta-diketo acid) gadolinium, holmium oxalate hydrate and tri(trifluoromethane sulfimide) ytterbium which serve as catalytic active auxiliary precursors, a rare earth metal organic compound, cobalt gluconate, nickel citrate and zinc lactate which serve as catalytic active center component precursor common transition metal organic compounds and dichlorodiamineplatinum Pt serving as a precious metal compound under the action of trimethylaminic acid trimethylamine iodide serving as an emulsifier, drying a reaction product to remove water, and firing the reaction product in a muffle furnace at certain temperature, thus obtaining the ozone heterogeneous oxidation solid catalyst.

The invention belongs to the technical field of environment protection and chemical catalysts and relates to an ozone heterogeneous oxidation solid catalyst preparation method. The preparation method includes: taking porous mineral materials including gamma-aluminum oxide, barite, activated carbon, carnallite, kaolin and rutile as carriers; subjecting the carriers to lithium hypochlorite and bis(acetylacetone)beryllium broaching modification; adding surfactant dimyristyldimethyl ammonium chloride for surface activation under the action of ultrasonic waves; subjecting the activated carriers to hydrothermal reaction, with a complex mineralizer composed of borax and potassium sulfate, catalytic activity auxiliary agent precursors including tetra(2,2,6,6-tetramethyl-3,5-hydrochelidonic acid)cerium (IV), tri(3-trifluoroacetyl-D-camphor)praseodymium (III), thulium trifluoromethanesulfonate (III) and lutetium carbonate hydrate and catalytic activity central precursors including lysine manganese, copper glutamate, potassium dithiocyanoargentate (I) and tetraammine dichloropalladium, in a hydrothermal reactor under the action of N-decylalkyldimethyl-N'-trimethyl-2-hydroxypropyl ammonium chloride serving as an emulsifying agent; drying to remove moisture, and firing in a muffle furnace at a certain temperature to obtain an ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical field of environmentally-friendly and chemical catalysts. The preparation method comprises the following steps: by taking porous materials of perlite, albite, montmorillonite, sylvinite, nitratine and dolomite as carriers, reaming and modifying the carriers with lithium hypochlorite and bis(acetylacetone) beryllium, then adding nonylphenol diquaternary ammonium salt serving as a surfactant for surface activation treatment under ultrasonic action, putting the ultrasonically surface-activated carriers into a hydrothermal reaction kettle for hydrothermal reaction together with borax and potassium sulfate which serve as composite mineralizers, 1,1,1-trifluoroacetylacetone neodymium, terbium acetate hydrate, thulium trifluoromethane sulfonate (III) and lutetium carbonate hydrate which serve as catalytic active auxiliary precursors, a rare earth metal organic compound, cobalt gluconate, nickel citrate and a catechol ethanediamine tungsten complex which serve as catalytic active center component precursor common transition metal organic compounds and tetraammine dichloropalladium (II) serving as a precious metal compound under the action of dodecanoylamidopropyl dimethyl dihydroxypropyl ammonium chloride serving as an emulsifier, drying a reaction product to remove water, and firing the reaction product in a muffle furnace at certain temperature, thus obtaining the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a perlite, albite, montmorillonite, sylvine, brucite and serpentinite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant nonylphenol diquaternary ammonium salt and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including 1,1,1-trifluoroacetylacetone neodymium, terbium acetate hydrate, tri[N,N-bi(trimethyl silyl)amide] erbium and tri(fluoroform sulfimide) ytterbium rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound cobalt gluconate, nickel citrate, catechol ethylene diamine tungsten compound and precious metal chemical complex gold potassium chloride in a hydrothermal reaction kettle under the effect of oleamide propyl dimethyl hydroxyethyl ammonium chloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a perlite, albite, aluminum hydroxide, phosphorite, hydrotalcite and alunite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant nonylphenol diquaternary ammonium salt and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including 1,1,1-trifluoroacetylacetone neodymium, tri(2,2,6,6-tetramethyl-3,5-hydrochelidonic acid) gadolinium, tri[N,N-bi(trimethyl silane) amine] erbium and lutetium carbonate hydrate rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound cobalt gluconate, nickel citrate, L-aspartic acid molybdenum complex and precious metal chemical complex hexa-nitroso rhodium trisodium Pt in a hydrothermal reaction kettle under the effect of N-decylalkyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: by taking medical stone, wollastonite, dolomite, calcite, illite and ulexite as carriers, modifying the carriers by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding a surfactant, tetradecyl tributyl ammonium chloride, and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an activated carrier, compound mineralizers including borax and potassium sulphate, catalytic activated assistant precursors including isopropoxy scandium (III), tri(4,4,4-trifluoro-1-(2-thiophene)-1,3-butanedione) europium, holmium oxalate hydrate and tri[N,N-bi(trimethyl silane) amine] erbium, and catalytic active core component precursors including dicyclopentadienyl titanium substituted salicylic acid complex, zinc lactate, diphenol ethylene diamine tungsten compound and iridium tetrachloride in a hydrothermal reaction kettle under the effect of N-octadecyl dimethyl-N'-trimethyl-propyl ammonium dichloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical fields of environment protection and catalysts for chemical industry. The preparation method comprises the following steps of using diatomite, kyanite, talcum, trona, brucite and serpentinite as carriers, expanding pores of the carriers by lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant (monoalkyl ether trimethyl ammonium chloride) for activating treatment under the action of ultrasonic wave; then, performing hydrothermal reaction on the carriers, composite mineralizing agents (borax and potassium sulfate), catalytic activity additive precursors (yttrium tri(hexafluoroacetylacetone) (III) dihydrate, tri(cyclopentadienyl) promethium, tris(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono)europium (III), and tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium), and catalytic activity center precursors (pyruvic acid isonicotinyl hydrazone vanadium, cobalt gluconate, catechol ethylenediamine tungsten complex and sodium hexanitrorhodate(III)) in a hydrothermal reaction kettle under the action of an emulsifier (hexadecyl dimethylamine ethyl sulfate), drying to remove water, and firing in a muffle furnace, so as to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, belonging to the technical field of environment-friendly and chemical catalysts. The preparation method comprises the following steps: by taking attapulgite, diopside, basalt, blodite, brucite and serpentinite porous materials as carriers, performing pore expansion and modification to the carriers through lithium hypochlorite and beryllium bis(acetylacetonate), adding a surfactant trilaurylammonium chloride and performing surface activation treatment under ultrasonic wave effect, then leading the ultrasonically surface-activated carriers to have hydrothermal reaction with a complex mineralizer, namely borax and potassium sulfate, catalytic activity assistant precursors, namely praseodymium(III) tris[3-(trifluoroacetyl)-D-camphor], promethium tricyclopentadienide, holmium oxalate and lutetium carbonate hydrate rare earth metal organic compound, and catalytic active site component precursors, namely common transitional metal organic compound ferrous fumarate and nickel citrate and precious metal compound tris(bipyridine)ruthenium(ii)chloride hexahydrate and tetraammine dichloropalladium in a hydrothermal reactor under the action of an emulsifier 2,6-di(diethylaminomethyl)-4-nonylphenol-epichlorohydrin quaternary ammonium salt, drying reactive products to remove moisture, and firing in a muffle furnace at certain temperature, to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, potassium feldspar, ascharite, hydrotalcite and alunite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-bis(diethylamino methyl)-4-nonyl phenol-chlorinated benzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, tri[N, N-bis(trimethyl silane)amine]erbium, trifluoromethane thulium sulfonate (III) and lutenium carbonate hydrate and catalytic activity central precursor cobalt gluconate, nickel citrate, terpyridyl ruthenium chloride hexahydrate and dipotassium hexachloroosmium in a hydrothermal reaction kettle under action of an emulsifier octadecyl dimethyl hydroxypropyl ammonium chloride; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, bentonite, polyhalite, magnesium spinel and olivinite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-di(diethylamino methyl)-4-nonyl phenol-chlorobenzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, tri(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octene diketone)dysprosium (III), trifluoromethane thulium sulfonate (III) and lutenium carbonate hydrate and catalytic activity central precursor cobalt gluconate, nickel citrate, silver dithiocyanate (I) acid potassium and cis-dichlorodiamineplatinum in a hydrothermal reaction kettle under action of an emulsifier N-decaalkyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a perlite, albite, montmorillonite, sylvine, amazonite and kunzite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant nonylphenol diquaternary ammonium salt and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including 1,1,1-trifluoroacetylacetone neodymium, terbium acetate hydrate, tri(fluoroform sulfimide) ytterbium and lutetium carbonate hydrate rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound cobalt gluconate, nickel citrate, catechol ethylene diamine tungsten compound and precious metal chemical complex dipotassium hexachloroosmium in a hydrothermal reaction kettle under the effect of N-oleoyl-N',N'-diethylethane-1,2-diamine hydrochloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a perlite, albite, imvite, sylvine, bentonite and polyhalite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant nonylphenol diquaternary ammonium salt and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including 1,1,1-trifluoroacetylacetone neodymium, terbium acetate hydrate, tri(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octene diketone) dysprosium (III) and tri(fluoroform sulfimide) ytterbium rare-earth metal organic compound and holmium oxalate hydrate rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound cobalt gluconate, nickel citrate, ammonium zirconium carbonate and precious metal chemical complex terpyridyl ruthenium chloride hexahydrate in a hydrothermal reaction kettle under the effect of octadecyl dihydroxyethyl ammonium sulfate used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: by taking medical stone, wollastonite, dolomite, calcite, basalt and blodite as carriers, modifying the carriers by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding a surfactant, tetradecyl tributyl ammonium chloride, and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on the carriers, compound mineralizers including borax and potassium sulphate, catalytic activated assistant precursors including isopropoxy scandium (III), tri(4,4,4-trifluoro-1-(2-thiophene)-1,3-butanedione) europium, holmium oxalate hydrate and lutetium carbonate hydrate, and catalytic active core component precursors including dicyclopentadienyl titanium substituted salicylic acid complex, zinc lactate, diphenol ethylene diamine tungsten compound and gold potassium chloride in a hydrothermal reaction kettle under the effect of 2,6-bi(diethylamine)-4-nonyl phenol-epoxy chloropropane hyamine used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environmental-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking perlite, albite, metaaluminum hydroxide, phosphorite, potassium feldspar and camsellite as a carrier, after chambering and modifying the carrier through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant N-octadecyl dimethyl-N'-trimethyl-propyl ammonium dichloride for surface activating treatment under the action of ultrasonic waves; then performing a reaction on the ultrasonic surface activated carrier in a hydrothermal reaction kettle and a compound mineralizer borax and potassium sulfate and catalytic active auxiliary agent precursors 1,1,1-trifluoroacetyl acetone neodymium, tri(2,2,6,6-tetramethyl-3,5-heptylic diketone acid) gadolinium, holmium oxalate decahydrate and thulium trifluoromethanesulfonate (III); and performing a hydrothermal reaction on catalytic active central compound precursors cobalt gluconate, nickel citrate, zinc lactate and iridic tetrachloride dehydrate under the action of an emulsifier ethyl trimethylamine stearate ammonium chloride, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a perlite, albite, magnesia spinel, olivinite, aluminum hydroxide and celestite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant N-decyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including tricyclopentadiene promethium, tri(4,4,4-trifluoro-1-(2-thiophene)-1,3-butanedione) europium, tri(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octene diketone) dysprosium (III) and holmium oxalate hydrate rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound cobalt gluconate, cupric glutamate and precious metal chemical complex gold potassium chloride and terpyridyl ruthenium chloride hexahydrate in a hydrothermal reaction kettle under the effect of hexadecyl dimethylammonium ethyl sulfate used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment-friendly and chemical engineering catalysts. The preparation method comprises the following steps: by taking medical stones, wollastonite, bentonite, polyhalite, coal ash and gangue as carriers, after chambering and modifying the carriers through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant, octadecyl trimethyl ammonium chloride, for surface activating treatment under the action of ultrasonic waves; then causing the carriers to generate hydrothermal reaction with borax and potassium sulfate which serve as compound mineralizers, isoproscandium oxide (III), tri[N,N-bis(trimethyl silyl)amide erbium, tri(trifluoromethane sulfimide) ytterbium and a lutetium carbonate hydrate which serve as catalytic active auxiliary agent precursors, and a titanocene ring substituted salicylic acid complex, molybdenum L-aspartate, gold potassium tetrachloride and dipotassium hexachloroosmate which serve as catalytic active central compound precursors in a hydrothermal reaction kettle under the action of an emulsifier, 2,6-di(diethylamino methyl)-4-nonyl phenol-epichlorohydrin quaternary ammonium salt, drying a reaction product to remove water, and firing the reaction product in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical fields of environmental protection and chemical engineering catalysts. The preparation method comprises the following steps: by taking porous materials activated carbon, carnallite, kaolin, red stones, bentonite and polyhalite as a carrier, after chambering and modifying the carrier through lithium hypochlorite and di(acetylacetone) beryllium, adding a surfactant beta-hydroxyethyl dimethyl ammonium lauryl sulfate for surface activating treatment under the action of ultrasonic waves; then performing a hydrothermal reaction on the ultrasonic surface activated carrier in a hydrothermal reaction kettle with a compound mineralizer borax and potassium sulfate, catalytic active auxiliary agent precursors of promethium tricyclopentadiene, tri(2,2,6,6-tetramethyl-3,5-gadolinium) dikeone heptylate, holmium oxalate decahydrate and tri(trifluoromethanesulfonimide) ytterbium rare earth metal organic compounds catalytic active central compound precursor common traditional metal organic compounds of cobalt gluconate, zinc lactate and molybdenum L-asparate and a noble metal compound dichlorodiamminoplatinum under the action of an emulsifier oleaminopropyl dimethyl hydroxyethyl ammonium chloride; and after drying a reaction product to remove water, firing the reaction product in a muffle furnace at a certain temperature to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, bentonite, polyhalite, nitratine and dolomite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant 2, 6-di(diethylamino methyl)-4-nonyl phenol-chlorobenzene quaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, holmium oxalate decahydrate, tri[N, N-bis(trimethylsilane)amine]erbium, andtrifluoromethane thulium sulfonate (III) and catalytic activity central precursor cobalt gluconate, nickel citrate, potassium tetrachloroaurate and hexanitroso rhodium trisodium in a hydrothermal reaction kettle under action of an emulsifier diethyl maleate bis(chlorinated dodecyl dimethyl ammonium); drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst and belongs to the technical field of environment protection and chemical engineering catalysts. The preparation method includes using perlite, albite, montmorillonite, sylvinite, magnesium spinel and olivinite as carriers; subjecting the carriers to pore expanding through lithium hypochlorite and bis(acetylacetone)beryllium, and adding a surfactant nonyl phenol diquaternary ammonium salt, activating under ultrasonic action; enabling the activated carriers to be in hydrothermal reaction with composite mineralizing agent borax and potassium sulfate, catalytic active auxiliary precursor 1, 1, 1-trifluoroacetylacetone neodymium, terbium triacetate hydrate, tri[N, N-bis(trimethyl silane)amine]erbium and lutenium carbonate hydrate and catalytic activity central precursor cobalt gluconate, nickel citrate, catechol ethanediamine tungsten complex and terpyridyl ruthenium chloride hexahydrate in a hydrothermal reaction kettle under action of an emulsifier oleamide propyl trimethyl ammonium methyl sulfate; drying for removing water; firing in a muffle furnace to obtain the ozone heterogeneous oxidation solid catalyst.

The invention relates to a preparation method of an ozone heterogeneous oxidation solid catalyst, and belongs to the technical field of environmentally-friendly and chemical catalysts. The preparation method comprises the following steps: by taking perlite, albite, kaolin, red gold stone, aluminum hydroxide and celestite as carriers, reaming the carriers with lithium hypochlorite and bis(acetylacetone) beryllium, then adding N-octadecyldimethyl-N'-trimethyl-propyl ammonia dichloride serving as a surfactant for surface activation treatment under ultrasonic action, putting the carriers into a hydrothermal reaction kettle for hydrothermal reaction together with borax and potassium sulfate which serve as composite mineralizers, 1,1,1-trifluoroacetylacetone neodymium, tri(2,2,6,6-tetramethyl-3,5-hepta-diketo acid) gadolinium, tri(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octene diketone) dysprosium (III) and holmium oxalate hydrate which serve as catalytic active auxiliary precursors, cobalt gluconate, nickel citrate, zinc lactate and potassium dicyanoargentate (I) which serve as catalytic active center precursors under the action of dodecanoylamidopropyl dimethyl dihydroxypropyl ammonium chloride serving as an emulsifier, drying a reaction product to remove water, and firing the reaction product in a muffle furnace, thus obtaining the ozone heterogeneous oxidation solid catalyst.