The invention discloses a high molecular weight
guanidine salt and polybasic amine
antibiosis type
polymer and a preparation method and the application thereof. The
polymer comprises a repeated
unit structure as right, wherein, X1 and X2 are the same or different polybasic amines; Y is Cl<->, NO3<->, HCO3<-> or H2PO4<->; Z is polyprotic acid, polyprotic
acid anhydride or multielement ester. When in preparation, the mixture of polynary amine and
guanidine salt is heated for reaction, and then polyprotic acid, polyprotic
acid anhydride or multielement ester is added, and the temperature is continuously raised for reaction. The invention solves the problem that the polybasic amine and the
guanidine salt react through a main body, thereby being difficulty to obtain a higher molecular weight
polymer. In lower
reaction temperature and shorter reaction time, by the chain expanding reaction to a polynary amine and guanidine salt
prepolymer by the polyfunctionality substance, the high molecular weight guanidine salt and polybasic amine
antibiosis polymer is formed. The polymer can be used as the anti
fungus agent of the
fiber product, the paper product, the non-weaving product and the tissue, etc.