The invention discloses a method for purifying
dodecanedioic acid, which comprises the following steps of: carrying out demulsification,
filtration and decoloration on stop
fermentation liquor of
dibasic acid and adding pure water to dilute; adding
purified water into a
crystallization kettle, pumping diluted fermented
clear liquid into a crystallizer, simultaneously filling dilute sulphuric acid with the
mass concentration of 30 percent into a
discharge hole of an external
circulating pump and adding the dilute sulphuric acid into the crystallizer, and controlling the PH of reaction materials; ensuring
crystal mush to flow to the lower part of a
crystallization chamber through a central downcomer and then flow upwards, so that crystals with large granularities are enriched on the bottom layer of the
crystallization chamber; and cooling the crystals outflowing from a
discharge hole of the crystallizer by a cooler and carrying out filter pressing, washing and
drying to obtain the
dodecanedioic acid. Due to the adoption of the purifying method, the micro
mixing effect is achieved by diluting local concentration of the reaction
mass through the material
circulating pump, the solution
nucleation rate, the
crystal growth rate and the
aggregation rate are reduced, the
moisture percentage and the
impurity content of a
filter cake are obviously reduced, the dried
dibasic acid product has large and uniform particles, good glossy and high purify, and the continuity of the crystallizing process is realized.