The invention discloses a
polyaniline type normal-temperature blackening agent as well as a preparation method and application thereof, and relates to the technical field of
metal surface treatment. The
polyaniline type normal-temperature blackening agent is prepared from the following components in parts by weight: 0.1 to 1.5 parts of
copper sulfate pentahydrate, 0.1 to 2.5 parts of
sodium tungstate dihydrate, 0.5 to 12 parts of
polyaniline reaction liquid, 0.05 to 1.2 parts of
nickel sulfate, 0.1 to 1.3 parts of
sodium thiosulfate, 0.05 to 1.2 parts of disodium 1-hydroxyethylidene-1, 1-diphosphonate, 0.01 to 1.0 part of
fatty alcohol-
polyoxyethylene ether and a proper amount of deionized water. In the components,
copper sulfate pentahydrate,
sodium tungstate dihydrate and polyaniline reaction liquid are used as main film-forming substances,
nickel sulfate is used as a secondary film-forming substance,
sodium thiosulfate is used as a film-forming aid, disodium 1-hydroxyethylidene-1, 1-diphosphonate is used as a chelating agent, and
fatty alcohol-
polyoxyethylene ether is used as a dispersion stabilizer. The finally formed blackening film can
cut off the direct connection between
metal and
oxygen, meanwhile, the continuous protection effect can be achieved, and under the combined action of all the components, the
corrosion resistance is obviously improved.