A novel graphene anode active compound used for lead-acid storage batteries is disclosed. The graphene anode active compound comprises following components by weight: 0.5-1.2% of colloidal graphite, 0.5-0.8% of humic acid, 0.3-0.8% of lignin, 0.5-1.2% of barium sulfate, 0.07-0.2% of staple fiber, 0.05-0.15% of polytetrafluoroethylene, 0.03-0.2% of poly(vinyl alcohol), 0.1-0.2% of 1,2-propanediol, 0.1-0.3% of graphene, 0.8-1.5% of acetylene black, 75-85% of lead powder and 7-10% of a diluted sulfuric acid solution, with the balance being deionized water. The graphene anode active compound enhances conductivity and low-temperature charge-discharge properties of anode plates and delays sulfation tendency of anode active compounds. Under the premise of not influencing the initial stage capacity of batteries, cyclic service lifetime of batteries is prolonged, high-current charge-discharge capability of batteries is improved, and using performance under extreme conditions is improved to a certain degree.