The invention discloses a silver
nanowire array
electrode, a preparation method and application thereof. The electrodes are
silver nanowires forming an array with a
diameter of 50-70nm and a wire length of 250-350nm. The bottom of the array is a
silver film of 130-170nm and a
copper film of 0.5-1mm; the method is to use a secondary
anode on the aluminum sheet first Oxidation method to obtain a through-hole
alumina template with a
pore diameter of 50-70nm, and then use the
ion sputtering method to vapor-deposit a
silver film on one side of the
alumina template, and then place the
alumina template with a
silver film on one side in a silver
electrolysis solution, use the electrodeposition method to electrodeposit at a
constant voltage of 0.08 to 0.12V for 1 to 5 minutes, then place it in the
copper electrolyte, use the electrodeposition method to electrodeposit 2.5 to 3.5 at a current of 8 to 12mA / cm2 h, after that, put the aluminum
oxide template with
silver nanowires in the hole, one side covered with silver film and
copper film in sequence, in acid solution or strong alkali solution to corrode the aluminum
oxide template, and make silver
nanowire array
electrode. Array electrodes can be used as sensitive elements for trace detection or reduction of halogenated organic compounds.