The invention discloses a synthetic method of polyarylene
sulfide resin, which comprises: 1, adding a
sulfur source, an alkaline substance and Nmethylpyrrolidone to a reaction kettle, heating to a temperature of 180-210 DEG C, and carrying out a
dehydration reaction to obtain an
intermediate product; 2, continuously adding a dihalogenated aromatic compound and N-methylpyrrolidone into the reactionkettle, adding organic
monobasic acid, carrying out condensation
polymerization at 210-280 DEG C to obtain polyarylene
sulfide slurry, and carrying out post-treatment to obtain polyarylene
sulfide resin, wherein the structural general formula of the organic
monobasic acid is R-COOH, and in the formula, R is selected from
hydrogen or
alkyl with the
carbon number of 1-4. According to the synthesismethod provided by the invention, the loss of the
solvent NMP is fundamentally reduced, and meanwhile, the
alkali metal carboxylate generated in the reaction process can also play a role in promotingpolymerization. The method is simple in process, low in production cost and high in economy.