The invention discloses an explosion experimental device for simulating an underground free field environment. The device comprises a spherical pressure container, an inner wall sprayed layer, an operation sealing head, a detonation line interface, a pressure sensor test interface, an explosive fixing rod, a fixing groove, a water inlet, a water outlet, an installation base, a flange plate, toughened glass and a base support. The explosion experimental device has the beneficial effects that the spherical pressure container is used as a main body, meeting the requirement of certain amount of explosive for many experiments; the device can be pressurized so as to simulate a certain deep water environment; a spherical tank is provided with an observation window which allows an operator to observe shapes of bubbles in the tank in experiment; the interior of the tank is treated by spraying or pasting multiple layers of material better in wave impedance matching, so as to absorb or suppress reflected impulse load to realize an underground free field environment.