The invention provides a preparation method of an aqueous
sodium ion battery
cathode composite material. The method comprises the following steps: S1.
manganese sulfate is added into a mixed solutionof
sodium hydroxide and
permanganate and
centrifugation is carried out, deposition after
centrifugation is taken out, and a Na0.44MnO2 precursor is obtained; S2. the Na0.44MnO2 precursor obtained in the S1 is dissolved in a
sodium hydroxide solution and a
hydrothermal reaction is carried out, after the reaction ends,
centrifugation is carried out, and
drying is carried out in order to obtain Na0.44MnO2; S3. Na0.44MnO2 obtained in the S2,
graphene and carbon nanotubes are added into water, after ultrasonic treatment, filtering and
drying,
calcination is carried out, and the aqueous
sodium ion battery cathode composite material is obtained. The preparation method has the advantages of simple operation, low cost and green and
environmental protection, and Na0.44MnO2 has a tunnel structure andis good for embedding and de-intercalation of sodion; reduced
graphene oxide and carbon nanotubes are doped in Na0.44MnO2,
conductivity of Na0.44MnO2 is enhanced, and multiplying power of the batteryis improved.